Geophysical investigation using resistivity and GPR methods: a case study of a lubricant oil waste disposal area in the city of Ribeirão Preto,São Paulo,Brazil

Geophysics has been shown to be effective in identifying areas contaminated by waste disposal, contributing to the greater efficiency of soundings programs and the installation of monitoring wells. In the study area, four trenches were constructed with a total volume of about 25,000 m³. They were almost totally filled with re-refined lubricating oil waste for approximately 25 years. No protection liners were used in the bottoms and laterals of the disposal trenches. The purpose of this work is to evaluate the potential of the resistivity and ground penetrating radar (GPR) methods in characterizing the contamination of this lubricant oil waste disposal area in Ribeirão Preto, SP, situated on the geological domain of the basalt spills of the Serra Geral Formation and the sandstones of the Botucatu Formation. Geophysical results were shown in 2D profiles. The geophysical methods used enabled the identification of geophysical anomalies, which characterized the contamination produced by the trenches filled with lubricant oil waste. Conductive anomalies (smaller than 185 Ωm) immediately below the trenches suggest the action of bacteria in the hydrocarbons, as has been observed in several sites contaminated by hydrocarbons in previously reported cases in the literature. It was also possible to define the geometry of the trenches, as evidenced by the GPR method. Direct sampling (chemical analysis of the soil and the water in the monitoring well) confirmed the contamination. In the soil analysis, low concentrations of several polycyclic aromatic hydrocarbons (PAHs) were found, mainly naphthalene and phenanthrene. In the water samples, an analysis verified contamination of the groundwater by lead (Pb). The geophysical methods used in the investigation provided an excellent tool for environmental characterization in this study of a lubricant oil waste disposal area, and could be applied in the study of similar areas.     

Hydraulic Conductivity Tests for Evaluating Compatibility of Lateritic Soil—Fly Ash Mixtures with Municipal Waste Leachate

Long term competent performance of liner systems is a critical issue in the design and construction of waste repositories due to adverse interactions associated with leachate generated by wastes. This study was conducted to verify the efficacy of fly ash stabilization in enhancing compatibility between lateritic soil and municipal waste leachate. Applications investigated include soil mixtures containing 0, 5, 10, 15, and 20% fly ash compacted at approximately 2% wet of optimum moisture content with modified proctor energy. Baseline hydraulic conductivity was first established at every level of fly ash content by permeating soil mixtures with tap water before permeation with leachate in a compaction mould permeameter using the falling head test method. Results show that the trend in hydraulic conductivity of specimen containing 0% fly ash was characterized by a gradual but erratic decrease which may suggests partial entry of the leachate cations into the double layer. Conversely, specimens containing fly ash showed a general trend consisting of an initial drop in k (up to an order of magnitude) that was followed by slight decrease sustained until k stabilized and later terminated. Above 10% fly ash content, the relatively high values of k observed was not connected with the reactivity of the soil mixtures with leachate, rather it may be attributed to excessive fly ash content that altered their textural and hydraulic properties. The result of this study is potentially significant in the assessment of fly ash as a compatibility enhancing agent which can be admixed in barrier materials that are susceptible to adverse reactions with the liquid to be contained.     

Deccan volcanism linked to the Cretaceous-Tertiary boundary mass extinction: New evidence from ONGC wells in the Krishna-Godavari Basin

A scientific challenge is to assess the role of Deccan volcanism in the Cretaceous-Tertiary boundary (KTB) mass extinction. Here we report on the stratigraphy and biologic effects of Deccan volcanism in eleven deep wells from the Krishna-Godavari (K-G) Basin, Andhra Pradesh, India. In these wells, two phases of Deccan volcanism record the world’s largest and longest lava mega-flows interbedded in marine sediments in the K-G Basin about 1500 km from the main Deccan volcanic province. The main phase-2 eruptions (∼80% of total Deccan Traps) began in C29r and ended at or near the KTB, an interval that spans planktic foraminiferal zones CF1–CF2 and most of the nannofossil Micula prinsii zone, and is correlative with the rapid global warming and subsequent cooling near the end of the Maastrichtian. The mass extinction began in phase-2 preceding the first of four mega-flows. Planktic foraminifera suffered a 50% drop in species richness. Survivors suffered another 50% drop after the first mega-flow, leaving just 7 to 8 survivor species. No recovery occurred between the next three mega-flows and the mass extinction was complete with the last phase-2 mega-flow at the KTB. The mass extinction was likely the consequence of rapid and massive volcanic CO₂ and SO₂ gas emissions, leading to high continental weathering rates, global warming, cooling, acid rains, ocean acidification and a carbon crisis in the marine environment.     

Insights on the events surrounding the final drainage of Lake Ojibway based on James Bay stratigraphic sequences

Deglaciation of the James Bay region was highly dynamic, with the occurrence of ice (Cochrane) readvances into glacial Lake Ojibway around final deglaciation time, which culminated with the drainage of Ojibway waters into Hudson Bay and subsequent incursion of the Tyrrell Sea at ～8 ka. Renewed interest on these events comes from the possible link between the drainage of the ice-dammed Lake Agassiz-Ojibway and a major climate deterioration known as the 8.2-ka cooling event. Recent glaciological modeling suggests that this drainage may have occurred subglacially, a mechanism that can accommodate more than one lake discharge, as suggested by marine records. The exact number and timing of drainage events, as well as location of the lake discharge pathway(s) remain, however, largely unconstrained. Here we focus on the events that led to the drainage of Lake Ojibway by documenting late-glacial sedimentary sequences located east of James Bay. Our investigations indicate that the deglacial sequence consists of a readvance till, extensive Ojibway rhythmites, and thick marine sediments. The glaciolacustrine and marine units are separated by a 60 cm-thick horizon composed of laminated silt beds containing rounded clay balls and disseminated clasts resulting from the abrupt drainage of the lake. Radiocarbon dating of marine fossils lying above the drainage horizon indicates that the glaciolacustrine episode ended around 8128–8282 cal yr BP. Micropaleontological analyses reveal that freshwater ostracods (Candona sp.) and marine microfossils (foraminifers, dinocysts) occur together in the upper part of the Ojibway sediments. Analysis of oxygen isotopes (δ¹⁸O) of ostracods and foraminifers originating from the same stratigraphic position show highly contrasting values that suggest possible subglacial exchanges between Lake Ojibway and Tyrrell Sea waters prior to the final drainage event. The complexity of the deglacial events is further indicated by radiocarbon dating of marine shells retrieved from a Cochrane till that suggests that the last ice readvance occurred almost simultaneously with the final lake discharge. These results bring additional constraints on the drainage mechanism of the coalesced Lake Agassiz-Ojibway and indicate that the James Bay region formed an important drainage pathway for meltwaters at the end of the last deglaciation.     

Virtual reality and its application to slide annimation of landslide

A few researches adopt virtual reality in landslide. So it is significant to combine the physicsbased deformable method with the process simulation of a sliding landslide, this way the dynamic process of a going landslide can be simulated. The analysis of the dynamic law of landslide provides a foundation to forecast and make it realiable to foretell disasters. After recounting the condition of VR and landsliding body simulation, this paper puts forward simulating landslide by the physics-based deformable method. The method divides landsliding into deformable body and rigid one. The deformation of deformable body can be compute by DDA and FEM, and DDA fits the great deformation and FEM is good for the tiny deformation. This paper shows it is feasible to simulate the landslide animation by this method.     

On characteristics of wind direction fluctuations in the surface layer

It is shown that the ratio of standard deviation of lateral velocity to the friction velocity, /u _*, and therefore wind direction fluctuations, are sensitive to mesoscale terrain properties. Under neutral conditions, /u _* is almost 40% larger in rolling terrain than over a horizontal surface. In the lee of a low mountain, the fluctuations may be 2.5 times as strong as over horizontal terrain. In contrast, vertical velocity fluctuations are little influenced by mesoscale terrain features.Now with Air Weather Service, Offutt AFB, Omaha, Nebraska.     

On the criteria to create a susceptibility map to debris flow at a regional scale using Flow-R

Studies on susceptibility to debris flows at regional scale(100-1000 km~2) are important for the protection and management of mountain areas. To reach this objective, routing models, mainly based on land topography, can be used to predict susceptible areas rapidly while necessitating few input data. In this research, Flow-R model is implemented to create the susceptibility map for the debris flow of the Vizze Valley(BZ, North-Eastern Italy; 134 km~2). The analysis considers the model application at local scale for three sub-catchments and then it explores the model upscaling at the regional scale by verifying two methods to generate the source areas of debris-flow initiation. Using data of an extreme event occurred in the Vizze Valley(4 August 2012) and historical information, the modeling verification highlights that the propagation parameters are relatively simple to set in order to obtain correct runout distances. A double DTM filtering-using a threshold for the upslope contributing area(0.1 km~2) and a threshold for the terrain-slope angle(15°)-provides a satisfactory prediction of source areas and susceptibility map within the geological conditions of the Vizze Valley.     

Compositions and microstructures of CB sulfides: Implications for the thermal history of the CB chondrite parent body

We studied textures and compositions of sulfide inclusions in unzoned Fe,Ni metal particles within CBa Gujba, CBa Weatherford, CBb HH 237, and CBb QUE 94411 in order to constrain formation conditions and secondary thermal histories on the CB parent body. Unzoned metal particles in all four chondrites have very similar metal and sulfide compositions. Metal particles contain different types of sulfides, which we categorize as: homogeneous low‐Cr sulfides composed of troilite, troilite‐containing exsolved daubreelite lamellae, arcuate sulfides that occur along metal grain boundaries, and shock‐melted sulfides composed of a mixture of troilite and Fe, Ni metal. Our model for formation proposes that the unzoned metal particles were initially metal droplets that formed from splashing by a partially molten impacting body. Sulfide inclusions later formed as a result of precipitation of excess S from solid metal at low temperatures, either during single stage cooling or during a reheating event by impacts. Sulfides containing exsolution lamellae record temperatures of ?600 °C, and irregular Fe‐FeS intergrowth textures suggest localized shock melting, both of which are indicative of heterogeneous heating by impact processes on the CB parent body. Our study shows that CBa and CBb chondrites formed in a similar environment, and also experienced similar secondary impact processing.     

Identification of temporal and spatial variations of water quality in Sanya Bay,China by three-way principal component analysis

A large data set obtained by a 1-year monthly determination of water quality from Sanya Bay, South China Sea, was treated by three-way principal component analysis aimed at exploring the spatial and temporal patterns of water quality in Sanya Bay. Tucker3 model of optimum complexity (2, 2, 1) explaining 33.18% of the data variance, allowed interpretation of the data information in three modes. The model explained spatial and temporal variation trends in terms of water quality variables during the study period. Water quality in sampling station (S2) Sanya River was mainly influenced by Sanya River, and water quality in other stations (S1, S3–S10) were mainly influenced by the waters in South China Sea. The results delineated the mouth of Sanya River as critical from pollution point of view. The dry season from October to the next April and rainy season from May to September have different influences on water quality in Sanya Bay. The information extracted by the three-way models would be very useful to regional agencies in developing a strategy to carry out scientific plans for resource use based on marine system functions.