River basin management and food crisis in Nigeria

River Basin Development is one of the key agricultural programmes embarked upon by Nigeria to meet the challenges of escalating import bills on food. This paper takes a critical look at the various efforts made by the management of the River Basin Authorities in responding to the current food crisis. The rationale for the huge financial allocation made to the Authorities is questioned, and the management lapses in their key areas of operation, such as irrigation, mechanization and extension services, are discussed. It is found that despite the huge financial investments made in the river basins, their impact is hardly felt, not only in terms of food production capacity but also in the production performance of the peasant farmers. The paper argues that the problem of food crisis in Nigeria could be solved by strengthening the ability of the peasant farmers and farmers co-operatives through financial aid and extension services, and not by huge financial investments on high technology agricultural projects, characterized by centralized administration and expatriáte management.     

High-resolution historical records from Pettaquamscutt River basin sediments: 2. Pb isotopes reveal a potential new stratigraphic marker

A high-resolution record of Pb deposition in Rhode Island over the past 250 yr was constructed using a sediment core from the anoxic Pettaquamscutt River basin. The sedimentary Pb concentration record shows the well-described maximum associated with leaded gasoline usage in the United States. Diminished Pb variability during recorded periods of local industrial activity (1735 to 1847) supports the greater importance of regional atmospheric lead transport vs. local inputs. The Pb isotopic composition at this site shows a clear maximum in anthropogenic ²⁰⁶Pb/²⁰⁷Pb in the mid-1800s. Similar peaks have also been observed in sediments from Chesapeake Bay and the Great Lakes, suggesting a common source. Possible causes for this event include mining and smelting of Pb ores in the Upper Mississippi Valley district, which accounted for almost all Pb production in the United States in that period. The timing of this event can provide an important stratigraphic marker for sediments deposited in the past 200 yr in the Northeastern United States. The downcore profile of anthropogenic ²⁰⁶Pb/²⁰⁷Pb provides a classic example of how changes in the mixture of ores for production of tetraethyl lead caused a regional-scale shift in the sedimentary record, and suggests that coal could have played a secondary role in Pb emissions after 1920.     

Application of petrographic and geochemical methods to sourcing felsitic archaeological materials in Southeastern New England

At least four volcanic complexes of different age and petrologic character occur in southeastern New England. Each complex contains a variety of fine-grained felsitic rocks, and three of these are known to have been quarried by prehistoric people for material used in the production of stone tools. These volcanics include a Late Proterozoic calcalkaline suite (Lynn-Mattapan) and several alkaline suites of Ordovician to Carboniferous age (Blue Hill, Spencer Hill, and Wamsutta suites). Each suite exhibits unique petrographic and geochemical features that help to constrain sources of felsitic archaeological materials. Distinctive petrographic features are: (1) Lynn/Mattapan: mostly pyroclastic rocks that typically contain broken crystals, volcanic clasts, and relict pumice and glass shards; phenocrysts of plagioclase, quartz, and perthite, commonly in glomeroporphyritic clusters; accessory sphene and prominent late-stage epidote; some varieties exhibit distinct flow-banding. (2) Blue Hill and Spencer Hill rocks: mainly lava flows; abundant perthite and quartz phenocrysts, with minor or no plagioclase; accessory minerals may include fluorite, aegerine, riebeckite, zircon, and allanite. (3) Wamsutta rhyolite: phenocrysts solely of anorthoclase; quartz restricted to late-stage filling of vesicles, and to planar, subparallel fractures in-filled as lithophysae; lava flows with devitrified glass matrix. Major element geochemistry is of limited use in distinguishing the volcanic groups, but trace element signatures are distinct and provide excellent criteria to discriminate rocks from each suite. Compared to the Lynn/Mattapan suite, the Blue Hill and Spencer Hill rocks exhibit higher concentrations of Rb, Y, Zr, Nb, La, Ce and Zn, and lower concentrations of Sr and Ba. Wamsutta rhyolite is intermediate in composition, but distinct. Examination of material from six prehistoric quarries, and debitage collected at seven archaeological sites, demonstrates that most samples can be assigned to one of the above volcanic suites based on combined petrographic and geochemical attributes. These geologic attributes add a significant element of quantification to archaeological sourcing problems that lead to improved identification of materials compared to hand sample characterization alone. The volcanics from source areas proximal to the Boston basin were important to Early and Middle Archaic period populations across most of southeastern Massachusetts. During the Late/Terminal Archaic period, these materials were being transported extensively throughout eastern and southeastern Massachusetts, the Narragansett Bay area, and parts of Rhode Island. Thus, routinely applied geological methods can provide useful approaches to constrain the sources of felsites from southeastern New England found in archaeological contexts. © 1997 John Wiley & Sons, Inc.     

Evidence for centennial-scale Lateglacial and early Holocene climatic complexity from Quoyloo Meadow,Orkney, Scotland

The influence of the North Atlantic on the margins of Europe means the region is particularly sensitive to changes in the ocean–atmospheric system. During the Last Glacial–Interglacial Transition (16–8 cal ka bp ) this system was repeatedly disrupted, leading to a series of abrupt and short-lived shifts in climate. Despite much research, the number and magnitude of these ‘centennial-scale’ events is not well understood. To address this, we expand upon investigations at Quoyloo Meadow, Orkney, Scotland, one of the best chronologically constrained palaeoclimate records in northern Britain. By coupling stable isotope and chironomid fossil analyses with existing data, this study identifies multiple phases of centennial-scale disturbance at: c. 14.0, 11.1, 10.8, 10.5, 10.45 and 10.3 cal ka bp , with the events at 14.0 and 10.3 exhibiting a particularly pronounced cold-climate signature. During the Holocene, the strongest response to climate forcing was at c. 10.3–10.0 cal ka bp , expressed as a two-stage drop in mean July temperatures, a shift in pollen spectra indicative of ‘less-stable’ climatic regimes, and a depletion in δ¹⁸O values. We interpret this as the first reliably dated incidence of the ‘10.3-ka event’ in the British Isles and consider the wider impact of this climatic reversal in other Holocene records.     

Characterization of uranium-contaminated sediments from beneath a nuclear waste storage tank from Hanford, Washington: Implications for contaminant transport and fate

The concentration and distribution of uranium (U) in sediment samples from three boreholes recovered near radioactive waste storage tanks at Hanford, Washington, USA, were determined in detail using bulk and micro-analytical techniques. The source of contamination was a plume that contained an estimated 7000 kg of dissolved U that seeped into the subsurface as a result of an accident that occurred during filling of tank BX-102. The desorption character and kinetics of U were also determined by experiment in order to assess the mobility of U in the vadose zone. Most samples contained too little moisture to obtain quantitative information on pore water compositions. Concentrations of U (and contaminant phosphate—P) in pore waters were therefore estimated by performing 1:1 sediment-to-water extractions and the data indicated concentrations of these elements were above that of uncontaminated “background” sediments. Further extraction of U by 8 N nitric acid indicated that a significant fraction of the total U is relatively immobile and may be sequestered in mobilization-resistant phases. Fine- and coarse-grained samples in sharp contact with one another were sub-sampled for further scrutiny and identification of U reservoirs. Segregation of the samples into their constituent size fractions coupled with microwave-assisted digestion of bulk samples showed that most of the U contamination was sequestered within the fine-grained fraction. Isotope exchange (²³³U) tests revealed that ∼51% to 63% of the U is labile, indicating that the remaining fund of U is locked up in mobilization-resistant phases. Analysis by Micro-X-ray Fluorescence and Micro-X-ray Absorption Near-Edge Spectroscopy (μ-XRF and μ-XANES) showed that U is primarily associated with Ca and is predominately U(VI). The spectra obtained on U-enriched “hot spots” using Time-Resolved Laser-Induced Fluorescence Spectroscopy (TRLIFS) provide strong evidence for uranophane-type [Ca(UO₂)₂(SiO₃OH)₂(H₂O)₅] and uranyl phosphate [Ca(UO₂)₂(PO₄)₂(H₂O)_10-12] phases. These data show that disseminated micro-precipitates can form in narrow pore spaces within the finer-grained matrix and that these objects are likely not restricted to lithic fragment environments. Uranium mobility may therefore be curtailed by precipitation of uranyl silicate and phosphate phases, with additional possible influence exerted by capillary barriers. Consequently, equilibrium-based desorption models that predict the concentrations and mobility of U in the subsurface matrix at Hanford are unnecessarily conservative.     

The removal kinetics of dissolved organic matter and the optical clarity of groundwater

Concentrations of dissolved organic matter (DOM) and ultraviolet/visible light absorbance decrease systematically as groundwater moves through the unsaturated zones overlying aquifers and along flowpaths within aquifers. These changes occur over distances of tens of meters (m) implying rapid removal kinetics of the chromophoric DOM that imparts color to groundwater. A one-compartment input-output model was used to derive a differential equation describing the removal of DOM from the dissolved phase due to the combined effects of biodegradation and sorption. The general solution to the equation was parameterized using a 2-year record of dissolved organic carbon (DOC) concentration changes in groundwater at a long-term observation well. Estimated rates of DOC loss were rapid and ranged from 0.093 to 0.21 micromoles per liter per day (μM d^?1), and rate constants for DOC removal ranged from 0.0021 to 0.011 per day (d^?1). Applying these removal rate constants to an advective-dispersion model illustrates substantial depletion of DOC over flow-path distances of 200 m or less and in timeframes of 2 years or less. These results explain the low to moderate DOC concentrations (20–75 μM; 0.26–1 mg L^?1) and ultraviolet absorption coefficient values (a ₂₅₄?<?5 m^?1) observed in groundwater produced from 59 wells tapping eight different aquifer systems of the United States. The nearly uniform optical clarity of groundwater, therefore, results from similarly rapid DOM-removal kinetics exhibited by geologically and hydrologically dissimilar aquifers.     

Capture-zone design in an aquifer influenced by cyclic fluctuations in hydraulic gradients

Design of a groundwater pumping and treatment system for a wood-treatment facility adjacent to the tidally influenced Fraser River estuary required the development of methodologies to account for cyclic variations in hydraulic gradients. Design of such systems must consider the effects of these cyclic fluctuations on the capture of dissolved-phase contaminants. When the period of the cyclic fluctuation is much less than the travel time of the dissolved contaminant from the source to the discharge point, the hydraulic-gradient variations resulting from these cycles can be ignored. Capture zones are then designed based on the average hydraulic gradient determined using filter techniques on continuous groundwater-level measurements. When the period of cyclic fluctuation in hydraulic gradient is near to or greater than the contaminant travel time, the resulting hydraulic-gradient variations cannot be ignored. In these instances, procedures are developed to account for these fluctuations in the capture-zone design. These include proper characterization of the groundwater regime, assessment of the average travel time and period of the cyclic fluctuations, and numerical techniques which allow accounting for the cyclic fluctuations in the design of the capture zone. Electronic Publication     

Land degradation impacts on tropical agricultural basins and their management: the Nigerian example

This study uses the fault-tree technique to identify the major effects of land degradation caused by the adoption of a malfunctioning shifting cultivation technology for food production in tropical basins. Through reference to existing empirical research, the sequence of events in the process of degradation of the Nigerian agricultural basins and the adjoining river systems was identified and related to the appropriate causal agent. A complete picture of the cost of land degradation goes beyond the degraded terrain and includes damage in areas where there is an unloading of large quantities of run-off and sediments. The causal pathway showed that existing land degradation management policies have focused on the symptoms rather than on the cause of the degradation process. Through a thorough examination of those malfunctioning components of the traditional farming technology, appropriate management strategies are proferred. An institutional organization for land degradation management in Nigeria which includes the federal, state and local governments is strongly recommended.     

Estimation of uranium endowment by subjective geological analysis—a comparison of methods and estimates for the San Juan Basin,New Mexico

This study investigates how estimates of uranium endowment made by a geologist using an appraisal system that is based upon a formalization of geoscience and decision rules compare with estimates made by informal and unconstrained intuitive processes. The motivation for this study derives from the premise that formalization of decisions would mitigate the heuristic biases and hedging that may result from the use of unconstrained intuitive processes. Estimates of the uranium endowment of the San Juan Basin of New Mexico by four methodologies are compared in this study. These methods, ranked from top to bottom by degree of decomposition (mitigating of heuristic bias)and control on hedging, are as follows Implicit 2 1.5 × 10⁶ s.t. of U₃O₈ Implicit 1 1.6 × 10⁶ s.t. of U₃O₈ NURE (1980) 2.4 × 10⁶ s.t. of U₃O₈ Appraisal system 3.9 × 10⁶ s.t. of U₃O₈ The magnitude of expected uranium endowment estimated by these methods, ranked from smallest to largest, is in this same order. With the exception of the NURE estimates, the magnitude of the variance (uncertainty)of uranium endowment, ranked from smallest to largest, also is in this same order. These results prompt the suggestion that the more decomposed and formalized the estimation procedure, the greater the expected value and the variance of uranium endowment. Equivalently, predicating U ₃ O ₈ endowment estimation strictly upon that part of the geologist's geoscience that is useful in making U ₃ O ₈ endowment estimates and upon his understanding of the region's history produced larger estimates than have previously been reported. However, this method of estimation also shows that uncertainty about the actual state of U ₃ O ₈ endowment is much greater than previously described.