Low-degree partial melting trends recorded in upper mantle minerals

The study of glass inclusions inside mantle minerals provides direct information about the chemistry of naturally occurring mantle-derived melts and the fine-scale complexity of the melting process responsible for their genesis. Minerals in a spinel lherzolite nodule from Grande Comore island contain glass inclusions which, after homogenization by heating, exhibit a continuous suite of chemical compositions clearly distinct from that of the host basanitic lava. The compositions range from silicic, with nepheline–olivine normative, 64 wt% SiO₂ and 11 wt% alkali oxides, to almost basaltic, with quartz normative, 50 wt% SiO₂ and 1–2 wt% alkali oxides. Within a single mineral phase, olivine, the inferred primary melt composition varies from 54 to 64 wt% SiO₂ for MgO content ranging from 8 to 0.8 wt%. An experimental study of the glass and fluid inclusions indicates that trapped melts represent liquids that are in equilibrium with their host phases at moderate temperature and pressure (T≈1230°C and P≈1.0 Gpa for melts trapped in olivine). Quantitative modelling of the compositional trends defined in the suite shows that all of the glasses are part of a cogenetic set of melts formed by fractional melting of spinel lherzolite, with F varying between 0.2 and 5%. The initial highly silicic, alkali-rich melts preserved in Mg-rich olivine become richer in FeO, MgO, CaO and Cr₂O₃ and poorer in SiO₂, K₂O, Na₂O, Al₂O₃ and Cl with increasing melt fractions, evolving toward the basaltic melts found in clinopyroxene. These results confirm the connection between glass inclusions inside mantle minerals and partial mantle melts, and indicate that primary melts with SiO₂ >60 wt%, alkali oxides >11%, FeO <1 wt% and MgO <1 wt% are generated during incipient melting of spinel peridotite. The composition of the primary melts is inferred to be dependent on pressure, and to reflect both the speciation of dissolved CO₂ and the effect of alkali oxides on the silica activity coefficient in the melt. At pressures around 1 GPa, low-degree melts are characterized by alkali and silica-rich compositions, with a limited effect of dissolved CO₂ and a decreased silica activity coefficient caused by the presence of alkali oxides, whereas at higher pressures alkali oxides form complexes with carbonates and, consequently, alkali-rich silica-poor melts will be generated.     

A mass mortality of subtropical intertidal populations of the sea urchin Paracentrotus lividus: analysis of potential links with environmental conditions

An outbreak of bald sea urchin disease was detected affecting intertidal populations of the edible temperate species Paracentrotus lividus at its southernmost geographical limit. The mortality event was detected in three sites (Güímar, Palmar and Alcalá) off Tenerife, Canary Islands (Northeastern Atlantic), in October 2003, coinciding with the highest sea surface temperatures (SST) and the lowest wave heights of the year. The prevalence of infection reached 100% but did not affect equally all studied sites or the different size classes. The disease was more prevalent in large sea urchins (>40 mm). The prevalence appeared to be positively correlated with the environmental variable SST and negatively correlated with wave height. In October 2004, only two infected urchins were found (prevalence 1%) at one of the studied sites. However, during 2004 no such extreme values of temperature and wave height were observed. We conclude that high SSTs and low wave heights such as those observed during 2003 are conditions that may trigger outbreaks of urchin disease.     

Impact of climate change on the hydrogeology of two basins in northern France

This study presents an analysis of climate-change impacts on the water resources of two basins located in northern France, by integrating four sources of uncertainty: climate modelling, hydrological modelling, downscaling methods, and emission scenarios. The analysis focused on the evolution of the water budget, the river discharges and piezometric heads. Seven hydrological models were used, from lumped rainfall-discharge to distributed hydrogeological models, and led to quite different estimates of the water-balance components. One of the hydrological models, CLSM, was found to be unable to simulate the increased water stress and was, thus, considered as an outlier even though it gave fair results for the present day compared to observations. Although there were large differences in the results between the models, there was a marked tendency towards a decrease of the water resource in the rivers and aquifers (on average in 2050 about ?14 % and ?2.5 m, respectively), associated with global warming and a reduction in annual precipitation (on average in 2050 +2.1 K and ?3 %, respectively). The uncertainty associated to climate models was shown to clearly dominate, while the three others were about the same order of magnitude and 3–4 times lower. In terms of impact, the results found in this work are rather different from those obtained in a previous study, even though two of the hydrological models and one of the climate models were used in both studies. This emphasizes the need for a survey of the climatic-change impact on the water resource.     

Delineation of Microscale Regimes of Fully-Developed Drainage and Implications for Continuum Models

Despite significant progress made in recent years, a fundamental understanding of immiscible displacements at the macroscale is lacking. In this paper we use a version of percolation theory, based on invasion percolation in a gradient, to connect drainage processes at the pore-network scale with the displacement at the macroscale. When the mobility ratio M is sufficiently small, the displacement is stabilized and can be described by invasion percolation in a stabilizing gradient. In the opposite case, it has common features with invasion percolation in a destabilizing gradient. A diagram delineating the regimes of fully developed drainage is developed. The transition between stabilized displacement and fingering is controlled by the change of the sign of the gradient of the percolation probability, and the transition boundary is described by a scaling law involving the capillary number and the viscosity ratio. We review recent work for random networks and extend the method to correlated pore networks. As the regimes of stabilized displacement are also those for which conventional theories (such as the Buckley–Leverett equation) are expected to apply, the phase diagram helps to delineate their validity.     

Geodynamic evolution of Korea: A view

Abstract Evidence for South Korean Palaeozoic geodynamic evolution is restricted to the Ogcheon Belt, which is a complex polycyclic domain forming the boundary between the Precambrian Gyeonggi Block to the northwest and the Ryeongnam Block to the southeast. Two independent sub-zones can be distinguished: the Taebaeksan Zone to the northeast and the Ogcheon Zone sensu stricto. The Taebaeksan Zone and Ryeongnam Block display characteristic features of the North China palaeocontinent. This domain remained relatively stable during the Palaeozoic. In contrast, the Ogcheon Belt s. s. is a highly mobile zone that belongs to the South China palaeocontinent and corresponds to a rift that opened during the Early Palaeozoic. In lowermost Devonian times, the rift basin was closed and the Ogcheon Belt was structured in a pile of nappes. From the lack of suture in the Ogcheon Belt it can be inferred that the Gyeonggi Block belongs to the South China palaeocontinent. Thus, the boundary between the North China and South China blocks should be located to the north of Gyeonggi Block, that is, in the Palaeozoic Imjingang Belt. From the Middle Carboniferous, sedimentation started again on a weakly subsiding paralic platform located in the hinterland of the Late Palaeozoic orogen of southwest Japan. In the Late Carboniferous, increasing subsidence recorded extensional tectonics related to the opening of the Yakuno Oceanic Basin (southwest Japan). In the Middle Permian, the end of marine influences in the platform and emplacement of terrestrial coal measures, may be correlated with the closure of the oceanic area and subsequent ophiolite obduction. In Late Permian to Early Triassic times, the Honshu Block (the eastern palaeomargin of the Yakuno Basin) collided with Sino-Korea. Post-collisional intracontinental tectonics reached the Ogcheon Belt in the Middle Triassic (Songnim tectonism). Ductile dextral shear zones associated with synkinematic granitoids were emplaced in the southwest of the belt. In the Upper Triassic, the late stages of the intracontinental transcurrent tectonics generated narrow intramontane troughs (Daedong Supergroup). The Daedong basins were deformed during two tectonic events, in the Middle (?) and Late Jurassic. The Upper Jurassic to Lower Cretaceous basins (Gyeongsang Supergroup), that are controlled by left-lateral faults, may have resulted from the same tectonic event.     

Avoiding deforestation in Panamanian protected areas: An analysis of protection effectiveness and implications for reducing emissions from deforestation and forest degradation

Reducing greenhouse gas emissions from deforestation and forest degradation (REDD) is likely to be central to a post-Kyoto climate change mitigation agreement. As such, identifying conditions and factors that will shape the success or failure of a reduced deforestation scheme will provide important insights for policy planning. Given that protected areas (PAs) are a cornerstone in forest conservation, we draw on interviews and secondary data to analyze the effects of available PA resources, governance ability, the level of community involvement, and provincial deforestation rates on land-cover change in nine PAs in Panama. Our results illustrate that coupling surveillance measures with greater funding and strong governance are paramount to reducing deforestation. Alone, however, these factors are insufficient for forest protection. We argue that conservation approaches that complement effective surveillance with community participation and equitable benefit sharing will address the wider issues of leakage and permanence.     

Alimentation et origine de la salinité de la source sous-marine de Port-Miou (Marseille–Cassis). Principale émergence d'un réseau karstique hérité du Messinien

(Marseille–Cassis–Bouches–du-Rhône). The salinity of the karstic submarine spring of Port-Miou has sometimes been attributed to the leaching of continental evaporites. Our recent chemical and isotopic analyses indicate a simple mixing between fresh karstic water and seawater. In the main gallery, the contamination by seawater, still present up to 2.2 km from the entrance at a depth of 147 m below the sea level, forces us to think about a general geometry that allows mixing of waters, at a great depth, in the karstic system. The measurements of the discharge of the spring indicate an excess of water compared with its supposed watershed, whereas a succinct evaluation of the aquifers of the Lower Provence indicates a deficit of discharge. Consequently, it seems possible that parts of the calcareous areas of the Lower Provence feed the springs of Port-Miou with a total catchment area of 1200 km². This deep and large karstic system was probably installed during the Messinian period, when the important lowering of the level of the Mediterranean Sea provoked an important gradient between Provence and the seashore. To cite this article: B. Blavoux et al., C. R. Geoscience 336 (2004).     

Pulsed export of carbon in the north-western Mediterranean Sea

The short term (hourly scale) variability of heterotrophic prokaryote (HP) vertical distribution and respiratory activity, was investigated in the north-western (NW) Mediterranean Sea. HP vertical distribution was determined on board by flow cytometry analysis of seawater samples collected by series of CTD casts. Cell counts and viability were determined for all samples. HP respiratory rates were determined later in the laboratory from filtered seawater samples (23 dm³) from 300–1 150-m depth. The average cell viability was 94.8%±2.2% (n=240). There was no accumulation of dead cells, due to quick decay of damaged cells. In the epipelagic layer, three HP groups were distinguished, two (HNA1, HNA2) whose cells exhibited a high nucleic acid content and one (LNA) with low nucleic acid content cells. HNA2 was most populated at 50 m but not detected at 90 m and below, presumably aerobic anoxygenic photoheterotrophic bacteria (AAPs). The variability in HP abundance was mainly confined in the upper 80 m. A few secondary peaks of HP abundance were observed (80–150 m) in connection with abundance troughs in the surface layer. HP cells were continuously present in a wide layer around 500 m (mean 191×10³ cells/cm³). Below this layer, HP abundance randomly exhibited peaks, coupled to respiratory rate peaks. The HP abundance and variability in the water column was suppressed during a strong wind event. The observed sporadic variability was tentatively interpreted through a pulsed carbon-export mechanism induced by the microorganism production of dissolved polysaccharides, followed by flocculation and rapid sinking. This mechanism would thus contribute to (i) preventing organic matter accumulation in the epipelagic layer, (ii) seeding the water column with live HP cells, and (iii) supplying the aphotic water column with fresh and labile organic matter. This important vertical flux mechanism needs further observations and modelling.

     

Multi‐Element Determination of Trace Elements in Natural Water Reference Materials by ICP‐SFMS after Tm Addition and Iron Co‐precipitation

We report on an improved method for determining trace element abundances in seawater and other natural waters. The analytical procedure involves co‐precipitation on iron hydroxides after addition of a Tm spike, and measurement by inductively coupled plasma‐sector field mass spectrometry (ICP‐SFMS). The validity of the method was assessed through a series of co‐precipitation experiments, using ultra‐diluted solutions of a certified rock reference material (BIR‐1). Results obtained for four natural water reference materials (NASS‐5, CASS‐4, SLEW‐3, SLRS‐4) are in agreement with published working values for rare earth elements, yttrium, vanadium and, when available, for hafnium, zirconium, thorium and scandium. A set of proposed values with uncertainties typically better than 8% RSD is proposed for Hf, Zr and Th.     

Lowland rainforest response to hydrological changes during the last 1500 years in Gabon, Western Equatorial Africa

Pollen and δ¹³C_TOM data obtained from two contrasting lake sequences (Lakes Kamalété and Nguène), located 200 km apart in the lowland rainforest of Gabon, provide complementary local and regional 1500-yr records of high resolution (15–30 yr) vegetation change. A combination of aquatic, semi-aquatic and terrestrial pollen showed in both records that the tropical rainforest increased during periods of high rainfall and decreased during drought intervals. The strong fluctuations of water balance at decadal scale during the “Medieval Warm Period” ( 1100–800 cal yr BP) coincided with a noticeable increase in shade-intolerant taxa, indicating recurring rainforest canopy disturbance. The δ¹³C_TOM signal showed high-amplitude variations in both records, which positively correlates with the rainforest dynamics and local vegetation changes. The similar trends in both the pollen and the δ¹³C_TOM signals between these sites demonstrate the regional broadly synchronous timing of shifting hydrological conditions. The largely positive co-variation between strong fluctuations of hydrological conditions and changes in rainforest structure and composition indicate that regional climatic change is probably the driving force for major rainforest dynamics in Gabon. Any significant anthropogenic impact on vegetation has not been clearly identified, and this issue still needs to be resolved independently by obtaining detailed archeological records across the interval 1400–800 BP, which currently seem to be extremely rare or not easily available.