Boron isotopes as pH proxy: A new look at boron speciation in deep-sea corals using B MAS NMR and EELS

Dissolved boron in modern seawater occurs in the form of two species, trigonal boric acid B(OH)₃ and tetrahedral borate ion . One of the key assumption in the use of boron isotopic compositions of carbonates as pH proxy is that only borate ions, , are incorporated into the carbonate. Here, we investigate the speciation of boron in deep-sea coral microstructures (Lophelia pertusa specimen) by using high field magic angle spinning nuclear magnetic resonance (¹¹B MAS NMR) and electron energy-loss spectroscopy (EELS). We observe both boron coordination species, but in different proportions depending on the coral microstructure, i.e. centres of calcification versus fibres. These results suggest that careful sampling is necessary before performing boron isotopic measurements in deep-sea corals. By combining the proportions of B(OH)₃ and determined by NMR and our previous ion microprobe boron isotope measurements, we propose a new equation for the relation between seawater pH and boron isotopic composition in deep-sea corals.     

Sun-as-a-Star Observation of Flares in Lyman α by the PROBA2/LYRA Radiometer

There are very few reports of flare signatures in the solar irradiance at H i Lyman α at 121.5 nm, i.e. the strongest line of the solar spectrum. The LYRA radiometer onboard PROBA2 has observed several flares for which unambiguous signatures have been found in its Lyman-α channel. Here we present a brief overview of these observations followed by a detailed study of one of them: the M2 flare that occurred on 8 February 2010. For this flare, the flux in the LYRA Lyman-α channel increased by 0.6 %, which represents about twice the energy radiated in the GOES soft X-ray channel and is comparable with the energy radiated in the He ii line at 30.4 nm. The Lyman-α emission represents only a minor part of the total radiated energy of this flare, for which a white-light continuum was detected. Additionally, we found that the Lyman-α flare profile follows the gradual phase but peaks before other wavelengths. This M2 flare was very localized and had a very brief impulsive phase, but more statistics are needed to determine if these factors influence the presence of a Lyman-α flare signal strong enough to appear in the solar irradiance.     

Detection of Solar Rotational Variability in the Large Yield RAdiometer (LYRA) 190 – 222 nm Spectral Band

We analyze the variability of the spectral solar irradiance during the period from 7 January 2010 until 20 January 2010 as measured by the Herzberg channel (190?–?222 nm) of the Large Yield RAdiometer (LYRA) onboard PROBA2. In this period of time, observations by the LYRA nominal unit experienced degradation and the signal produced by the Herzberg channel frequently jumped from one level to another. Both factors significantly complicate the analysis. We present the algorithm that allowed us to extract the solar variability from the LYRA data and compare the results with SORCE/SOLSTICE measurements and with modeling based on the Code for the Solar Irradiance (COSI).     

Fluvial response to climatic and anthropogenic forcing in the Moselle drainage basin (NE France) during historical periods: evidence from OSL dating

The aim of this paper is to study a low energy fluvial system response to natural and anthropogenic forcing during the last two millennia. In contrast with longer timescales (Holocene to Quaternary), historical sedimentary archives are sparse in such systems which are typically characterized by the predominance of erosion compared with aggradation. We studied three main sections in the Moselle valley (northeastern France) by a multi‐proxy approach combining morphology, sedimentology, archaeological evidence, historical archives, and dating. The geochronological framework was based on Optically Stimulated Luminescence (OSL) and validated by independent age control. The exposed sediments were allocated to different historical periods from Roman period to present. The first results show that, in contrast with many other fluvial systems, the Moselle and its tributaries did not experience major changes during historical periods. Climatic changes such as the Little Ice Age had a minor influence on floodplain aggradation (e.g. in grain size or sedimentation rates) in the Moselle valley and were only able to affect the fluvial style. This provides evidence that the reworking of sediments is the main fluvial process at short timescales in the valley floors of the Moselle catchment. In contrast, anthropogenic forcing seems important not only during recent centuries but also since Roman times. This is suggested by the case‐study of the Metz‐Mazelle section where significant headward erosion and sedimentation were recognized, and may be related to human occupation. The results therefore point to a need for increasing geoarchaeological and geochronological research in the Moselle catchment and similar low energy fluvial systems. Such research is actually essential to improve the knowledge of the fluvial response to environmental changes during the historical periods and to recognize the respective influence of natural variability and human forcing. Copyright © 2012 John Wiley & Sons, Ltd.     

Eutrophication and drought disturbance shape functional diversity and life-history traits of aquatic plants in shallow lakes

Theories that link plant strategies and abiotic filters discriminate between three strategies: competitive, ruderal or stress-tolerant species, and suggest that functional diversity is higher at intermediate values along the gradients of productivity and disturbance. The mechanism by which abiotic filters screen plant traits in aquatic plant communities has been poorly tested and has led to contrasting results. The present study aimed to test whether functional diversity and abundance of life-history traits corresponding to morphology, fecundity and longevity of aquatic plants were linked to disturbance and productivity. Fifty-nine shallow lakes that were arranged along a gradient of productivity (estimated through total phosphorus concentration) and drought-disturbance frequency were sampled for aquatic plants. Species traits were documented and functional diversity was calculated (richness, dispersion and evenness) for each lake. Increasing total phosphorus concentration was associated with decreased functional richness and dispersion but not functional evenness. Functional diversity did not differ according to disturbance frequency, regardless of the index that was measured. High productivity favoured floating species with storage organs and vegetative reproduction, especially at low disturbance frequency. For all disturbance frequencies, low productivity favoured small species without storage organs and sexual reproduction. The present study partly supports the theoretical model. At high productivity levels, because phytoplankton is a better competitor for light than aquatic plants, plant traits are screened stringently, and species with traits that allow them to reach the photic zone are selected.     

The sodium exosphere of Mercury: Comparison between observations during Mercury's transit and model results

In this study we compare the sodium exosphere observations made by Schleicher et al. [Schleicher, H., and 4 colleagues, 2004. Astron. Astrophys. 425, 1119-1124] with the result of a detailed numerical simulation. The observations, made during the transit of Mercury across the solar disk on 7 May 2003, show a maximum of sodium emission near the polar regions, with north prevalence, and the presence of a dawn-dusk asymmetry. We interpret this distribution as the resulting effect of two combined processes: the solar wind proton precipitation causing chemical alteration of the surface, freeing the sodium atoms from their bounds in the crystalline structure on the surface, and the subsequent photon-stimulated and thermal desorption of the sodium atoms. While we find that the velocity distribution of photon desorbed sodium can explain the observed exosphere population, thermal desorption seems to play a minor role only causing a smearing at the locations where Na atoms are released on the dayside. The observed and simulated distributions agree very well with this hypothesis and indicate that the combination of the proposed processes is able to explain the observed features.     

Quantification of initial steps of nucleation and growth of silica nanoparticles: An in-situ SAXS and DLS study

The initial steps of silica polymerization and silica nanoparticle formation have been studied in-situ and in real-time. The experiments were carried out in near neutral pH (7–8) solutions with initial silica concentrations of 640 and 1600 ppm ([SiO₂]) and ionic strengths (IS) of 0.02, 0.05, 0.11 and 0.22 M. The polymerization reactions were induced by neutralizing a high pH silica solution (from pH 12 to 7) and monitored by the time-dependent depletion in monosilicic acid concentration over time. The accompanied nucleation and growth of silica nanoparticles (i.e., change in particle size over time) was followed in-situ using time-resolved synchrotron-based Small Angle X-ray Scattering (SAXS) and conventional Dynamic Light Scattering (DLS) combined with scanning and (cryo)-transmission electron microscopy (SEM/cryo-TEM).The critical nucleus diameter was quantified (1.4–2 nm) and results from SAXS and DLS showed that over 3 h the particle diameter increased to a final size of 8 nm. SEM and TEM photomicrographs verified the SAXS and DLS data and confirmed the spherical and hydrous structure of the forming silica nanoparticles. Furthermore, fractal analysis (i.e., fractal dimension, D_m  2.2) indicated that the formed particles consisted of open, polymeric, low-density structures.For the nucleation and growth of silica nanoparticles a 3-stage growth process is proposed: (1) homogeneous and instantaneous nucleation of silica nanoparticles, (2) 3-D, surface-controlled particle growth following 1st order reaction kinetics and (3) Ostwald ripening and particle aggregation.