Track of fluid paleocirculation in dolomite host rock at regional scale by the Anisotropy of Magnetic Susceptibility (AMS): An example from Aptian carbonates of La Florida,Northern Spain

The present study aims to apply the AMS method (Anisotropy of Magnetic Susceptibility) at a regional scale to track the fluid circulation direction that has produced an iron metasomatism within pre-existing dolomite host rock. The Urgonian formations hosting the Zn–Pb mineralizations in La Florida (Cantabria, northern Spain) have been taken as target for this purpose. Sampling was carried out, in addition to ferroan dolomite host rock enclosing the Zn–Pb mineralizations, in dolomite host rock and limestone to make the comparison possible between magnetic signals from mineralized rocks, where fluid circulation occurred, and their surrounding formations. AMS study was coupled with petrofabric analysis carried out by texture goniometry, Scanning Electron Microscopy (SEM) observations and also Shape Preferred Orientation (SPO) statistics. SEM observations of ferroan dolomite host rock illustrate both bright and dark grey ribbons corresponding respectively to Fe enriched and pure dolomites. SPO statistics applied on four images from ferroan dolomite host rock give a well-defined orientation of ribbons related to the intermediate axis of magnetic susceptibility K₂. For AMS data, two magnetic fabrics are observed. The first one is observed in ferroan dolomite host rock and characterized by a prolate ellipsoid of magnetic susceptibility with a vertical magnetic lineation. The magnetic susceptibility carrier is Fe-rich dolomite. These features are probably acquired during metasomatic fluid circulations. In Fe-rich dolomite host rock, ?c? axes are vertical. As a rule, (0001) planes (i.e. planes perpendicular to ?c? axes) are isotropic with respect to crystallographic properties. So, the magnetic anisotropy measured in this plane should reflect crystallographic modification due to fluid circulation. This is confirmed by the texture observed using the SEM. Consequently, AMS results show a dominant NE–SW elongation interpreted as the global circulation direction and a NW–SE secondary elongation that we have considered as sinuosities of the fluid trajectory. The second type of magnetic fabric is essentially observed in the limestone and characterized by an oblate form of the ellipsoid of magnetic susceptibility, a horizontal magnetic foliation and mixed magnetic susceptibility carriers. It is interpreted as a sedimentary fabric.     

Hydro-climatic analysis of mechanical breakups reconstructed from tree-rings, Necopastic watershed, northern Québec, Canada

We used a 54-year (1950–2003) ice scar chronology constructed from damaged trees to investigate relationships between large scale hydro-climatic conditions and mechanical breakup magnitude in the Necopastic River watershed (James Bay, northern Québec). Our objectives were: (1) to identify hydrologic and climatic variables that explain variations in mechanical breakup magnitude at the watershed scale, (2) to organize these variables in terms of importance and (3) to construct a predictive model for ice-floods in the Necopastic watershed. We used parametric correlation analysis to measure the degree of linear association between variables and classification trees (CT) coupled with a cross-validation approach to construct the predictive model and to organize variables according to their importance. In the Necopastic watershed, the type and magnitude of breakups are determined by an interaction between forces that maintain the ice cover in place and forces that tend to dislodge it. In contrast with lakes, early and rapidly rising floods, rather than abnormally high flood discharge, create conditions that favour intense mechanical breakups. Moreover, cold and snowy spring conditions during high positive Arctic Oscillation (AO) indices delay the thermal degradation of the ice cover and preserve its mechanical properties over longer time periods.     

Current state and trends in Canadian Arctic marine ecosystems: I. Primary production

During the International Polar Year (IPY), large international research programs provided a unique opportunity for assessing the current state and trends in major components of arctic marine ecosystems at an exceptionally wide spatio-temporal scale: sampling covered most regions of the Canadian Arctic (IPY-Canada??s Three Oceans project), and the coastal and offshore areas of the southeastern Beaufort Sea were monitored over almost a full year (IPY-Circumpolar Flaw Lead project). The general goal of these projects was to improve our understanding of how the response of arctic marine ecosystems to climate warming will alter the productivity and structure of the food web and the ecosystem services it provides to Northerners. The present paper summarizes and discusses six key findings related to primary production (PP), which determines the amount of food available to consumers. (1) Offshore, the warming and freshening of the surface layer is leading to the displacement of large nanophytoplankton species by small picophytoplankton cells, with potentially profound bottom-up effects within the marine food web. (2) In coastal areas, PP increases as favourable winds and the deeper seaward retreat of ice promote upwelling. (3) Multiple upwelling events repeatedly provide food to herbivores throughout the growth season. (4) A substantial amount of pelagic PP occurs under thinning ice and cannot be detected by orbiting sensors. (5) Early PP in the spring does not imply a trophic mismatch with key herbivores. (6) The epipelagic ecosystem is very efficient at retaining carbon in surface waters and preventing its sedimentation to the benthos. While enhanced PP could result in increased fish and marine mammal harvests for Northerners, it will most likely be insufficient for sustainable large-scale commercial fisheries in the Canadian Arctic.     

A New Interlaboratory Characterisation of Silicon,Rare Earth Elements and Twenty‐Two Other Trace Element Concentrations in the Natural River Water Certified Reference Material SLRS‐6 (NRC‐CNRC)

The natural river water reference material SLRS‐6 (NRC‐CNRC) is the newest batch of a quality control material routinely used in many international environmental laboratories. This work presents a nine‐laboratory compilation of measurements of major and trace element concentrations and their related uncertainties, unavailable in the NRC‐CNRC certificate (B, Cs, Li, Ga, Ge, Hf, Nb, P, Rb, Rh, Re, S, Sc, Se, Si, Sn, Th, Ti, Tl, W, Y, Y, Zr and REEs). Measurements were mostly made using inductively coupled plasma‐mass spectrometry. The results are compared with equivalent data for the last batch of the material, SLRS‐5, measured simultaneously with SLRS‐6 in this study. In general, very low concentrations, close to the quantification limits, were found in the new batch. The Sr isotopic ratio is also reported.     

Paleoeskimo site taphonomy: An assessment of the integrity of the Tayara site,Qikirtaq Island,Nunavik, Canada

A detailed taphonomic study was undertaken at the Tayara site in order to determine the impact of natural processes such as surface water flow on spatial patterning and site formation. The study focused on Paleoeskimo level II, which contains many lithics and significant faunal remains. Level II integrity was assessed through spatial analysis and by examining the size distribution of lithic artifacts and bone orientation. Experimental knapping aimed at replicating Paleoeskimo lithic technology was used to assess the possible size sorting of lithics. The study indicates that artifact burial by water‐laid sediments did not result in a selective impoverishment in small‐sized lithics. Statistically significant lithic concentrations and associations suggest that spatial distribution was not significantly modified by site formation processes. However, slight post‐depositional changes were presumably induced by water flows in the form of statistically significant horizontal bone reorientations. These occurred when gently flowing water inundated bone accumulations without inducing significant washing or sorting of smaller lithic debris. The spatial integrity evaluation of the level II assemblage reveals a low degree of spatial disturbance and disorganization of the material (i.e., limited entropy), which is likely related to low‐energy hydraulic forces and rapid burial soon after Paleoeskimo occupation. The grouping and deposition of much of the occupation debris is likely the result of Paleoeskimo activities (e.g., knapping and butchering), and the lithics and fauna specimens are probably at or very near their original location. These results show the behavioral significance of the grouping and deposition of debris in Tayara's level II. © 2009 Wiley Periodicals, Inc.     

Flow of ultra-hot orogens: A view from the Precambrian, clues for the Phanerozoic

This contribution emphasizes first-order structural and metamorphic characters of Precambrian accretionary orogens to understand the kinematics and thermomechanical state of the continental lithosphere in convergent settings involving massive juvenile magmatism. We define a new class of orogens, called ultra-hot orogens (UHO), in which the weakest type of lithosphere on Earth is deformed. UHO are characterized by (1) distributed shortening and orogen-scale flow combining vertical and horizontal longitudinal advection, under long-lasting convergence, (2) homogeneous thickening by combined downward movements of supracrustal units and three-dimensional mass redistribution in the viscous lower crust, and (3) steady-state, negligible topography and relief leveled by syn-shortening erosion and near-field sedimentation. The flow analysis of UHO provides clues to understanding crustal kinematics beneath high plateaus and suggests that the seismic reflectivity pattern of hot orogens is an image of the layering produced by lateral flow of the lower crust and associated syn-kinematic plutonism.In between the UHO and the modern cold orogens (CO), developed by shortening of lithosphere bearing a stiff upper mantle, two classes of orogens are defined. Hot orogens (HO, representative of Cordilleran and wide mature collisional belts) share flow pattern characteristics with UHO, but involve a less intense magmatic activity and develop high topographies driving their collapse. Mixed-hot orogens (MHO, representative of magmatic arcs and Proterozoic collisional belts) are orogens made of UHO-type juvenile crust and display CO-like structure and kinematics. This classification points to the fundamental link between the presence of a stiff lithospheric mantle and strain localization along major thrusts in convergent settings. A high Moho temperature (> 900 °C), implying thinning of the lithospheric mantle, enhances three-dimensional flow of the lithosphere in response to convergence. Overall, this classification of orogens emphasizes the space and time variability of uppermost mantle temperature in controlling plate interactions and continental growth.     

Thermal anomalies and paleoclimatic diffusive and advective phenomena: example of the Anglo-Paris Basin,northern France

This study is the first quantification of the combined impact of diffusive and advective paleoclimatic phenomena to explain the weak vertical thermal flux anomaly in the upper part of the Anglo-Paris intracratonic sedimentary basin in northern France. The aim of the research is to understand the mechanisms at the origin of the thermal flux anomaly at the level of the Meso-Cenozoic sediment pile. Based on a temperature profile representative of the basin, transient thermo-hydraulic simulations were performed along a representative vertical cross-section of about 400 km within the Lower Cretaceous multi-layer aquifer. Four paleoclimatic scenarios are the combination of two paleotemperature climatic forcings and two hydrodynamic regimes, one of them taking into account the interruption of the recharge linked to permafrost development. The simulation results clearly show the transient nature of the basin’s thermal regime. Then, for the reference well, the majority of the thermal flux anomaly can be explained by advective and paleoclimatic mechanisms with a decrease in geothermal flux simulated up to a little over 30 mW/m², depending on the scenarios. Decrease in heat flux because of basin-scale subsurface flows in the Lower Cretaceous is around 15 mW/m². There are several ways forward from this first simple model, including simulation of development of permafrost and also the integration of vertical flows in the basin by use of a three-dimensional model to better explain the data.