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91.
High pressure polymorphs of olivine (Mg, Fe)2SiO4 have been observed by transmission electron microscopy in the shocked Tenham and Catherwood meteorites. Planar defects are characterized in β and γ polymorphs and their possible role in polymorphic transitions is assessed and discussed in relation with the published literature. The stacking fault observed in the β-phase can produce a shear transformation to the γ-phase if it occurs on every other (010) plane. Conversely, the stacking fault observed in the γ-phase can be transformed to the β-phase if it is repeated on every other (110) plane and to an intermediate, yet unobserved, ε1-phase if it is repeated on every (110) plane. Shear transformation between olivine and γ-spinel could involve the ε1-phase as an intermediate stage. 相似文献
92.
93.
Characterization of water in synthetic rhyolitic glasses and natural melt inclusions by Raman spectroscopy 总被引:3,自引:1,他引:2
Aliouka?Chabiron Jacques?PirononEmail author Dominique?Massare 《Contributions to Mineralogy and Petrology》2004,146(4):485-492
Raman spectroscopy was used to analyze quantitatively water in silicate glasses and melt inclusions and to monitor H2O–OH speciation. Calibration is based on synthetic glasses with various water contents (0.02–7.67% H2O); water determination and OH–H2O differentiation on the area of the Si–O broad band at 468 cm–1 and the asymmetric O–H band at 3,550 cm–1. Each Raman spectrum has been decomposed into four Gaussian + Lorentzian components centered at 3,330, 3,458, 3,560, and 3,626 cm–1 using the Levenberg–Marquardt algorithm. These components are interpreted to be two different types of H2O molecule sites. The influence of the temperature on the loss of water is more important for molecular water than for the hydroxyl groups. The H2O–OH partition confirms the typical evolution of water speciation in rhyolitic glasses as a function of the bulk water content. Method limitations have been studied for the application to natural melt inclusions.Editorial responsibility: T.L Grove 相似文献
94.
Georg?M.?PartzschEmail author Dominique?Lattard Catherine?McCammon 《Contributions to Mineralogy and Petrology》2004,147(5):565-580
One of the most widely used methods to estimate magmatic oxygen fugacity involves the use of empirical equations relating fO2 to the iron redox state in quenched silicate liquids; however none of the equations have been calibrated experimentally under subliquidus conditions at temperatures and oxygen fugacities that are relevant to natural magmas. To address this problem, we tested two empirical relationships [Eq. (1) in Kress and Carmichael 1991; Eq. (6) in Nikolaev et al. 1996] on synthetic glasses synthesized from a ferrobasaltic and a transitional alkali-basaltic composition at sub- to superliquidus temperatures (1,132–1,222°C) and controlled oxygen fugacities (FMQ=–2 to +1.4). Fe3+/Fe was determined using conventional and milliprobe Mössbauer spectroscopy, and verified using wet chemical analysis on selected samples. For the ferrobasaltic bulk composition SC1-P, both empirical models reproduce the Fe3+/Fe ratio of the quenched liquids generally within 0.03 for sub- as well as superliquidus temperatures, although agreement is worse at higher oxygen fugacities (FMQ>+1) at subliquidus temperatures. For the transitional alkali-basaltic composition 7159V-P, both models reproduce the Fe3+/Fe ratio of the quenched liquids generally within 0.04, although agreement is worse for both models at high oxygen fugacities (FMQ>+1). Such behaviour may be related to a change in melt structure, where a progressive change in Fe3+ coordination is inferred to occur as a function of Fe3+/Fe based on Mössbauer center shifts. Recasting the data in terms of oxygen fugacity shows that calculated oxygen fugacities deviate from those actually maintained during the equilibration of the sample material by generally no more than 0.5 log-bar unit, with maximum deviations that only rarely exceed one log-bar unit.Editorial responsibility: J. Hoefs 相似文献
95.
A. Benmoussa J.-F. Hochedez W. K. Schmutz U. SchÜhle M. NeslÁdek Y. Stockman U. Kroth M. Richter A. Theissen Z. Remes K. Haenen V. Mortet S. Koller J. P. Halain R. Petersen M. Dominique M. D’Olieslaeger 《Experimental Astronomy》2003,16(3):141-148
Fabrication, packaging and experimental results on the calibration of metal-semiconductor-metal (MSM) photodetectors made on diamond are reported. LYRA (Lyman- RAdiometer onboard PROBA-2) will use diamond detectors for the first time in space for a solar physics instrument. A set of measurement campaigns was designed to obtain the XUV-to-VIS responsivity of the devices and other characterizations. The measurements of responsivity in EUV and VUV spectral ranges (40–240 nm) have been carried out by the Physkalisch-Technische Bundesanstalt (PTB) in Germany at the electron storage ring BESSY II. The longer wavelength range from 210 to 1127 nm was measured with monochromatic light by using a Xe-lamp at IMO-IMOMEC. The diamond detectors exhibit a photoresponse which lie in the 35–65 mA/W range at 200 nm (corresponding to an external quantum efficiency of 20–40%) and indicate a visible rejection ratio (200–500 nm) higher than four orders of magnitude. 相似文献
96.
97.
Laurent Pfister Gilles Drogue Abdelkhalak El Idrissi Jean-François Iffly Christelle Poirier Lucien Hoffmann 《Climatic change》2004,66(1-2):67-87
The spatial variability of observed trends in rainfall structure over the last 5 decades and its effects on the spatial variability of maximum daily water levels in the Grand-Duchy of Luxembourg (Europe) were investigated in 9 sub-basins of the Mosel river. Over the past 25 years, an increase in westerly atmospheric circulation types during winter months has caused an increase in winter rainfall totals, duration and intensity. More specifically, the spatial variability of trends having affected winter rainfall totals, duration and intensity have led to spatially varying positive trends in maximum daily water levels. Observed trends in rainfall characteristics and maximum daily water levels during winter show closely linked spatial patterns that are strongly related to the topography of the study area. 相似文献
98.
Pascal Bertran Dominique Bonnissent Daniel Imbert Pierre Lozouet Nathalie Serrand Christian Stouvenot 《Comptes Rendus Geoscience》2004,336(16):14
A 2.5-m-thick sequence of lake sediments at the Étang de Grand-Case, Saint Martin (French West Indies) is studied here. Significant hydrological budget fluctuations allows distinction of three main climatic periods: (1) an overall dry period (4200 BP–2300 BP), characterised by carbonated mud, gypsum and storm sand layers; (2) a wet phase (2300 BP–1150 BP) dominated by organic mud; and (3) a more complex phase (1150 BP to present), with detrital inputs due to human activities. Comparison with other regional high-resolution records shows that similar climate modifications typify the whole Mesoamerican and Caribbean area. The climatic phenomena that are implicated in the variations of both precipitation and hurricane frequency over the Lesser Antilles are due to the latitudinal displacement of the inter-tropical convergence zone. These data give new support to the hypothesis of the existence of a correlation between peopling phases and climate variations in the Caribbean as previously proposed by some archaeologists. To cite this article: P. Bertran et al., C. R. Geoscience 336 (2004). 相似文献
99.
100.
This paper describes the activity of a small meandering stream and the development of its floodplain during the last 4600 years (calendar years BP) in the northern boreal zone of Québec. Three trenches were excavated across the floodplain's full width and permitted the interpretation of morphosedimentary units in relation to modern analogs. Chronological controls within trenches was provided by the dendrochronological and radiocarbon dating of buried tree trunks. From 4600 to 2900 cal. BP and from 1000 to 120 cal. BP, the channel migrated and constructed its floodplain at very slow rates, mostly because of low flow velocities, vegetated streambanks and the cohesive texture of marine sediments reworked by the channel. Vertical accretion rates were extremely variable on the floodplain, with high rates proximal to the modern channel and low rates over distal (also older) portions of the floodplain. Following a major channel shift (meander cut-off or avulsion) around 2900 cal. BP, channel migration appears to have been constrained to a narrow zone adjacent to the modern channel. Within this constrained zone, the migrating channel has reworked its own sediments leading to a marked unconformity between 2900–1000 cal. BP. It is thought that underlying marine sediments protrusions, and perhaps the forested banks, protected older alluvial sediments from being eroded during the last three millenniums. Our study shows that small boreal floodplains may contain, in a very small area, abundant and diversified archives of their evolution. 相似文献