Chondritic ingredients: II. Reconstructing early solar system history via refractory lithophile trace elements in individual objects of the Leoville CV3 chondrite

We performed a LA-ICP-MS study of refractory lithophile trace elements in 32 individual objects selected from a single section of the reduced CV3 chondrite Leoville. Ingredients sampled include ferromagnesian type I and II chondrules, Al-rich chondrules (ARCs), calcium-aluminum-rich inclusions (CAIs), a single amoeboid olivine aggregate (AOA), and matrix. The majority of rare earth element (REE) signatures identified are either of the category “group II” or they are relatively flat, i.e., more or less unfractionated. Data derived for bulk Leoville exhibit characteristics of the group II pattern. The bulk REE inventory is essentially governed by those of CAIs (group II), ARCs (flat or group II), type I chondrules (about 90% flat, 10% group II), and matrix (group II). Leoville matrix also shows a superimposed positive Eu anomaly. The excess in Eu is possibly due to terrestrial weathering. The group II pattern, however, testifies to volatility-controlled fractional condensation from a residual gas of solar composition at still relatively high temperature. In principle, this signature (group II) is omnipresent in all types of constituents, suggesting that the original REE carrier of all components was CAI-like dust. In addition, single-element anomalies occasionally superimposing the group II signature reveal specific changes in redox conditions. We also determined the bulk chemical composition of all objects studied. For Mg/Si, Mg/Fe, and Al/Ca, Leoville's main ingredients—type I chondrules and matrix—display a complementary relationship. Both components probably formed successively in the same source region.     

53Mn and 60Fe in iron meteorites—New data,model calculations

We measured specific activities of the long‐lived cosmogenic radionuclides ⁶⁰Fe in 28 iron meteorites and ⁵³Mn in 41 iron meteorites. Accelerator mass spectrometry was applied at the 14 MV Heavy Ion Accelerator Facility at ANU Canberra for all samples except for two which were measured at the Maier‐Leibnitz Laboratory, Munich. For the large iron meteorite Twannberg (IIG), we measured six samples for ⁵³Mn. This work doubles the number of existing individual ⁶⁰Fe data and quadruples the number of iron meteorites studied for ⁶⁰Fe. We also significantly extended the entire ⁵³Mn database for iron meteorites. The ⁵³Mn data for the iron meteorite Twannberg vary by more than a factor of 30, indicating a significant shielding dependency. In addition, we performed new model calculations for the production of ⁶⁰Fe and ⁵³Mn in iron meteorites. While the new model is based on the same particle spectra as the earlier model, we no longer use experimental cross sections but instead use cross sections that were calculated using the latest version of the nuclear model code INCL. The new model predictions differ substantially from results obtained with the previous model. Predictions for the ⁶⁰Fe activity concentrations are about a factor of 2 higher, for ⁵³Mn, they are ~30% lower, compared to the earlier model, which gives now a better agreement with the experimental data.     

Realisation of a fully‐deterministic microlensing observing strategy for inferring planet populations

Within less than 15 years, the count of known planets orbiting stars other than the Sun has risen from none to more than 400 with detections arising from four successfully applied techniques: Doppler‐wobbles, planetary transits, gravitational microlensing, and direct imaging. While the hunt for twin Earths is on, a statistically well‐defined sample of the population of planets in all their variety is required for probing models of planet formation and orbital evolution so that the origin of planets that harbour life, like and including ours, can be understood. Given the different characteristics of the detection techniques, a complete picture can only arise from a combination of their respective results. Microlensing observations are well‐suited to reveal statistical properties of the population of planets orbiting stars in either the Galactic disk or bulge from microlensing observations, but a mandatory requirement is the adoption of strictly‐deterministic criteria for selecting targets and identifying signals. Here, we describe a fully‐deterministic strategy realised by means of the ARTEMiS (Automated Robotic Terrestrial Exoplanet Microlensing Search) system at the Danish 1.54‐m telescope at ESO La Silla between June and August 2008 as part of the MiNDSTEp (Microlensing Network for the Detection of Small Terrestrial Exoplanets) campaign, making use of immediate feedback on suspected anomalies recognized by the SIGNALMEN anomaly detector. We demonstrate for the first time the feasibility of such an approach, and thereby the readiness for studying planet populations down to Earth mass and even below, with ground‐based observations. While the quality of the real‐time photometry is a crucial factor on the efficiency of the campaign, an impairment of the target selection by data of bad quality can be successfully avoided. With a smaller slew time, smaller dead time, and higher through‐put, modern robotic telescopes could significantly outperform the 1.54‐m Danish, whereas lucky‐imaging cameras could set new standards for high‐precision follow‐up monitoring of microlensing events (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

The speleothem record of climate variability in Southern Arabia

Uranium-series dated stalagmites from Oman indicate that pluvial conditions prevailed from 6.3 to 10.5, 78 to 82, 120 to 130, 180 to 200 and 300 to 330 kyr B.P.; all of these periods coincide with peak interglacials. Oxygen (δ¹⁸O) and hydrogen (δD) isotope ratios of speleothem calcite and fluid inclusions reveal the source of moisture and provide information on the amount of precipitation, respectively. δ¹⁸O and δD values of stalagmites deposited during peak interglacials vary between ?8 and ?4 ‰ (VPDB) and ?53 and ?20‰ (Vienna Standard Mean Ocean Water [VSMOW]) respectively, whereas modern stalagmites range from ?2.6 to ?1.1‰ in δ¹⁸O (VPDB) and ?7.6 and ?3.3‰ in δD (VSMOW), respectively. The growth and isotopic records indicate that during peak interglacial periods, the limit of the monsoon rainfall was shifted far north of its present location and each pluvial period was coinciding with an interglacial stage of the marine oxygen isotope record.     

A GIS based approach to back trajectory analysis for the source apportionment of aerosol constituents and its first application

A new method has been developed to combine back trajectory statistics with a detailed land cover analysis. It provides numeric proxies for the residence times of sampled air masses above certain land cover classes (marine, natural vegetation, agricultural lands, urban areas, and bare areas), as well as further meteorological parameters (mean trajectory length, solar radiation along trajectory, and local height of the boundary mixing layer). The method has been implemented into a GIS-enabled database system to allow for an efficient processing of large datasets with low computational demands. A principal component analysis was performed on a dataset including the modelled residence times, the modelled meteorological parameters, some measured meteorological parameters (wind speed and temperature), and the concentrations of 10 particle constituents (inorganic ions and organic and elemental carbon) in 5 particle size ranges for 29 winter- and summertime samples at an urban background site in Leipzig, Germany. Six principal components could be extracted which together explained about 80% of the total variance in the dataset. The factors could be attributed to the influence of meteorology to continental background pollution, secondary formation processes in polluted air masses, wood burning, aged sea-salt, local traffic, and long-range transported crustal material. The modelled residence times and the meteorological parameters were generally consistent with the existing knowledge of specific particle sources and thereby facilitated and strengthened the interpretation of the factors. Moreover, they allowed for a clear distinction between continental background pollution and secondary formation processes, which has not been possible in previous source apportionment studies. The results demonstrate that the combined usage of back trajectory, land cover, and meteorological data by the presented method yields valuable additional information on the history of sampled air masses, which can improve the quality of source apportionment of atmospheric aerosol constituents.     

How to improve the representation of hydrological processes in SWAT for a lowland catchment – temporal analysis of parameter sensitivity and model performance

Model diagnostic analyses help to improve the understanding of hydrological processes and their representation in hydrological models. A detailed temporal analysis detects periods of poor model performance and model components with potential for model improvements, which cannot be found by analysing the whole discharge time series. In this study, we aim to improve the understanding of hydrological processes by investigating the temporal dynamics of parameter sensitivity and of model performance for the Soil and Water Assessment Tool model applied to the Treene lowland catchment in Northern Germany. The temporal analysis shows that the parameter sensitivity varies temporally with high sensitivity for three groundwater parameters (groundwater time delay, baseflow recession constant and aquifer fraction coefficient) and one evaporation parameter (soil evaporation compensation factor). Whereas the soil evaporation compensation factor dominates in baseflow and resaturation periods, groundwater time delay, baseflow recession constant and aquifer fraction coefficient are dominant in the peak and recession phases. The temporal analysis of model performance identifies three clusters with different model performances, which can be related to different phases of the hydrograph. The lowest performance, when comparing six performance measures, is detected for the baseflow cluster. A spatially distributed analysis for six hydrological stations within the Treene catchment shows similar results for all stations. The linkage of periods with poor model performance to the dominant model components in these phases and with the related hydrological processes shows that the groundwater module has the highest potential for improvement. This temporal diagnostic analysis enhances the understanding of the Soil and Water Assessment Tool model and of the dominant hydrological processes in the lowland catchment. Copyright © 2013 John Wiley & Sons, Ltd.     

The Fate of Chernobyl137Cs in Lake Lugano

A rapid removal of Chernobyl¹³⁷Cs from a number of large lakes has been previously reported. Our measurements of¹³⁷Cs in water, sediments and pore water in the mono- and meromictic basins of Lake Lugano (Lago di Lugano) reveal generally slower half-removal times of 1.2 and 6.7 yrs, respectively. In the seasonally anoxic southern basin, this is most probably related to an intensive recycling of¹³⁷Cs between water and sediments. In the permanently stratified northern basin the removal rate is much slower due to an important inventory build up in the deep anoxic part of the basin.     

Changes in the biota and sediments of glacial Lake Koźmin, Poland, during the late Saalian (Illinoian)

Upper Saalian (Illinoian) glaciolacustrine deposits in central Poland, preserved in a tectonic graben, were exposed in an opencast lignite mine and investigated using sedimentological and micro-paleontological methods. The extraglacial lake sediments provide the first records of late Saalian cladoceran communities in central Europe, recovered from glaciolacustrine deposits. Sedimentation was dominated by a supply of clastics that fluctuated with the seasons, forming rhythmites. In addition to seasonal cyclicity, sedimentary and environmental conditions changed every several years to decades, with periods of increased inflow to the lake delivering sandy material, and periods of almost stagnant water dominated by suspension settling. The sediments contain Cladocera assemblages that indicate the lake was initially deep, oligotrophic, and filled with moderately cold water. Changes in Cladocera community composition and abundance were perhaps responses to climate seasonality. Zones without Cladocera were associated with seasons of higher inflow and sediment supply, and directly or indirectly, with tectonic activity in the graben. Earthquakes, documented by the presence of seismites, caused not only deformation of unconsolidated lake-bottom sediments, but possibly also changes in habitat characteristics. Combined sedimentological and biological data were used to infer the lake’s history and show that deposits of glaciolacustrine lakes can be used as indicators of past ecological and climate changes.     

The composition and size distribution of the dust in the coma of Comet Hale-Bopp

We discuss the composition and size distribution of the dust in the coma of Comet Hale-Bopp. We do this using a model fit for the infrared emission measured by the Infrared Space Observatory (ISO) and the measured degree of linear polarization of scattered light at various phase angles and wavelengths. The effects of particle shape on the modeled optical properties of the dust grains are taken into account. Both the short wavelength (7-44 μm) and the long wavelength (44-120 μm) infrared spectrum are fitted using the same dust parameters, as well as the degree of linear polarization at twelve different wavelengths in the optical to near-infrared domains. We constrain our fit by forcing the abundances of the major rock forming chemical elements to be equal to those observed in meteorites. The infrared spectrum at long wavelengths reveals that large grains are needed in order to fit the spectral slope. The size and shape distribution we employ allows us to estimate the sizes of the crystalline silicates. The ratios of the strength of various forsterite features show that the crystalline silicate grains in Hale-Bopp must be submicrometer-sized. On the basis of our analysis the presence of large crystalline silicate grains in the coma can be excluded. Because of this lack of large crystalline grains combined with the fact that we do need large amorphous grains to fit the emission spectrum at long wavelengths, we need only approximately 4% of crystalline silicates by mass (forsterite and enstatite) to reproduce the observed spectral features. After correcting for possible hidden crystalline material included in large amorphous grains, our best estimate of the total mass fraction of crystalline material is ∼7.5%, which is significantly lower than deduced in previous studies in which the typical derived crystallinity is ∼20-30%. The implications of this low abundance of crystalline material on the possible origin and evolution of the comet are discussed. We conclude that the crystallinity we observe in Hale-Bopp is consistent with the production of crystalline silicates in the inner Solar System by thermal annealing and subsequent radial mixing to the comet forming region (∼30 AU).