Assessment of the topsoil heavy metals pollution in the Sarno River basin,south Italy

The Sarno River basin area is one of the most polluted in Europe and it is due to the waste products of the tomato industry, the leather tanneries and the pharmaceutical industry. This area also has been densely populated and urbanized since the Middle Bronze Age, as testified by the presence of numerous archeological sites, including the ancient Pompeii town, and environmental degradation that characterizes the area is absolutely unacceptable. This paper represents a detailed study to assess the potentially harmful element content of topsoils. In total, 283 soil samples were collected and analyzed, after an aqua regia extraction, by a combination of inductively coupled plasma atomic emission and inductively coupled plasma mass spectrometry for 53 elements. Univariate and multivariate analyses were carried out to show the single-element geochemical distribution and the distribution of factor scores of the elemental associations resulting from R-mode factor analysis. Maps showing elements and the association factor score distributions have been obtained using GeoDAS and ArcGIS software. The assessment of the soil contamination was also carried out using the contamination factor and degree of contamination. The results obtained indicate that soil pollution has different anthropogenic sources. Specifically, Cr pollution derives from tanneries discharging wastewaters in the main water bodies of the basin while Cu contamination seems to depend on widespread agricultural practices. Tin, Pb, Hg, Zn, Cd, Sb anomalies are found mainly in urban and industrial areas, sometimes close to roads with high traffic levels while there is a substantial coincidence with background values for other elements (Co, Ni, Se, Tl and V).     

Compressional reworking of the East African Orogen in the Uluguru Mountains of eastern Tanzania at c. 550 Ma: implications for the final assembly of Gondwana

The Uluguru Mountains of eastern Tanzania represent a key area to unravel the tectonic history of Gondwana assembly along the Neoproterozoic East African Orogen. On the basis of combined structural and ⁴⁰Ar/³⁹Ar geochronological investigations, we have re‐interpreted the structural architecture of the region. Texturally‐late, ductile to cataclastic low‐angle tectonic contacts are recognized, which delimit the contacts between the main lithological units that form a post‐metamorphic, NW‐verging nappe stack. ⁴⁰Ar/³⁹Ar geochronology places this nappe‐forming event at c. 550 Ma, post‐dating tonalitic dyke emplacement at c. 580 Ma. Results from this study (i) demonstrate that a distinct and later episode of convergence occurred in the region at c. 550 Ma, when previous structural elements of the East African Orogen were finally juxtaposed; and (ii) extends models involving the polyphase assembly of Gondwana to East Africa.     

Infrared transmission spectroscopy of carbonate samples of biotic origin relevant to Mars exobiological studies

Because it is possible that Mars experienced an ancient climate warmer and wetter than the present one, it is reasonable to suppose that simple forms of life developed there, in the underground or at the surface, as in the terrestrial primitive biosphere. In this work we have performed infrared (IR) transmission spectroscopic analyses directed to examine the reaction to heat treatments of biotic (fresh and fossil materials) and abiotic particulate samples composed of calcium carbonate (aragonite or calcite). The aim is to check if IR spectroscopy can be a useful tool for discriminating between abiotic and biotic (fossil) carbonate samples collected on the martian surface, during in situ or sample-return missions. An important result we found is that, after thermal processing, it is possible to distinguish, by means of IR spectroscopy, abiotic aragonite from aragonite of recent biological origin. In addition we have found that the spectral behaviour of all the analysed fossil samples after heat treatment is the same as that of fresh biotic material irrespective of the original structure (whether aragonite or calcite).     

Explicit stress integration with error control for the Barcelona Basic Model.: Part II: Algorithms efficiency and accuracy

The paper compares the accuracy and efficiency of explicit stress integration schemes for elasto-plastic unsaturated soil models with automatic error control. Numerical tests are performed with reference to the Barcelona Basic Model (BBM), one of the most popular elasto-plastic models for unsaturated soils, by using eight explicit Runge–Kutta algorithms of various order as well as a novel application of the extrapolation method described in the companion paper. Initially, the results obtained from the lowest order Runge–Kutta scheme (i.e. Modified Euler) as well as the extrapolation method are checked against accurate solutions of a number of BBM paths involving changes of strains and suction. Subsequently, the efficiency and accuracy of all algorithms are assessed for generic increments of strains and suction, while the difference between two alternative error control methods is also analysed. The results presented, although strictly valid for the Barcelona Basic Model, are expected to be general and relevant to other similar unsaturated elasto-plastic models formulated in terms of two independent stress variables such as net stress and suction.     

Lava stones from Neapolitan volcanic districts in the architecture of Campania region,Italy

Results of a research carried out on the lavas from Campi Flegrei and Somma-Vesuvius volcanic districts are reported here. The lavas have been widely employed, since Roman age, in several important monumental buildings of the Campania region, mainly in the town of Naples and in its province. They are classified as trachytes (Campi Flegrei products), tephri-phonolites and phono-tephrites (Somma-Vesuvius complex) from a petrographical point of view. Sampling was carried out from well-known exploitation districts. A substantial chemical difference between the products of the two sectors was confirmed, while petrophysical characterization evidenced similarity among the two different materials, although some differences were recorded even in samples coming from the same exploitation site.     

Active foreland deformation evidenced by shallow folds and faults affecting late Quaternary shelf–slope deposits (Adriatic Sea, Italy)

A succession of depositional sequences, recording middle-late Pleistocene and Holocene glacial–interglacial cycles, documents the impact of short-term tectonic deformation on the western Adriatic margin. The western Adriatic margin is part of the Apennine foreland which was intensely, though variably, deformed during the Meso-Cenozoic evolution of the Adriatic region from a passive margin to a foreland basin. The study area extends offshore Gargano Promontory, an uplifted sector of the Adriatic foreland, and includes three major deformation belts located along or cross-strike to the margin: (1) the NW-SE Gallignani-Pelagosa ridge, (2) the WSW-ENE Tremiti-Pianosa high (both located north of Gargano) and (3) the W-E to NW-SE Gondola fault deformation belt (in the south Adriatic). Long-term deformation along these tectonic lineaments is documented on conventional low-frequency seismic profiles by regional folds and faults affecting Eocene–Miocene units overlain by dominantly draping Plio-Quaternary deposits. At this scale of observation, only north of Gargano Promontory there is some evidence of Plio-Quaternary units thinning against structural highs, thus suggesting that tectonic deformation was protracted through this interval. Based on new high-resolution seismic data, we show that deformation along these pre-existing tectonic structures continued during the Quaternary, affecting middle-late Pleistocene and even Holocene units on the shelf and upper slope north and south of Gargano Promontory. These recent deformations consist of gentle folds and high-angle faults, locally producing topographic relief that affects the stratigraphy and thickness of syn-tectonic deposits. We interpret the small-scale, shallow faults and gentle folds affecting middle-late Pleistocene and Holocene deposits, north and south Gargano Promontory, as the evidence of ongoing foreland deformation along inherited regional fold and fault systems.     

Lithological control on thrust-related deformation in the Sassa-Guardistallo Basin (Northern Apennines hinterland, Italy)

The Sassa‐Guardistallo Basin (SGB) is located close to the Tyrrhenian Sea and represents one of the most internal Neogene–Quaternary hinterland basins of the Northern Apennines fold‐and‐thrust belt. Its sedimentary succession consists of ca. 400‐m‐thick Late Tortonian–Messinian continental – largely conglomeratic – units overstepping a mainly shaly substratum (Palombini Shales) and overlain by Late Messinian evaporites and marine to continental Pliocene–Pleistocene sediments. This stratigraphic succession can be approximated to a composite rheological multilayer that dictated the style of basin deformation. Detailed geological mapping and structural analysis revealed that basin deposits were affected by compressional deformations that can be found both at map and outcrop scales. Decametric splay thrusts emanating from the substratum–conglomerate interface locally double the continental succession and are bounded by a roof thrust along the Late Messinian evaporite décollement, defining a deformation pattern consistent with a duplex‐like structure. The time–space structural evolution of the basin inferred from the fieldwork was addressed and tested by analogue modelling that approximated the rheological stratification of the study area to a layered brittle–ductile system. The model results support the hypothesis that the evolution of the thrust system affecting the SGB started as an early floor imbricate fan thrust system that successively evolved to a duplex structure as the link thrusts propagated into the upper décollement layer that resulted from the deposition of the Late Messinian evaporites. Models display many structural features that may be compared with the natural prototype, and highlight the importance of syntectonic sedimentation in the development and evolution of tectonic structures. The results of this study retain relevant implications for the Neogene evolution of the Tyrrhenian Basin–Northern Apennines system. This study also supports that combining between field structural analyses and analogue modelling can give useful hints into the evolutionary history of tectonically complex areas.     

Estimation of the Lagrangian Velocity Structure Function Constant C0 by Large-Eddy Simulation

The inertial subrange Kolmogorov constant C ₀, which determines the effective turbulent diffusion in velocity space, plays an important role in the Lagrangian modelling of pollutants. A wide range of values of the constant are found in the literature, most of them determined at low Reynolds number and/or under different assumptions. Here we estimate the constant C ₀ by tracking an ensemble of Lagrangian particles in a planetary boundary layer simulated with a large-eddy simulation model and analysing the Lagrangian velocity structure function in the inertial subrange. The advantage of this technique is that it easily allows Reynolds numbers to be achieved typical of convective turbulent flows. Our estimates of C ₀ is C ₀=4.3±0.3 consistent with values found in the literature