The comparison of two severe Hwangsa (Asian dust) cases of spring and winter in Seoul, Korea

This study investigated meteorological, physical, and chemical characteristics of 2 severe Hwangsa (Asian dust, maximum average of PM₁₀ above 1000 μg m^?3) observed in Seoul, the capital city of Korea, during 30～31^st May, 2008 (DSS2008) and 25～26^th December, 2009 (DSS2009). DSS2008 and DSS2009 had a same source region and route. However, they have different meteorological conditions. DSS2009 had a shorter travel time from the source region to Korea and shorter duration time in Korea than DSS2008 due to a strong winter Siberian anticyclone. One of DSS2008 sample was affected by not only Asian dust but also a long-range transported haze due to consecutive influx after low pressure passed while DSS2009 sample collected only dust aerosol. For both cases, the mass concentration of coarse particles (PM_10-1) increased by 3～14 times compared to that during non Asian dust period, however, that of fine particles (PM₁) increased only in DSS2008. For DSS2008 water-soluble ion balance between anions and cations in fine mode was close to 1:1 while cations were higher than anions in coarse mode. NH₄ ⁺ and Ca²⁺ were found to be the main contributing factors for the neutralization. Cl^? loss was observed about 60% indicating an active interaction of Na⁺ with pollutants. Reconstruction of chemical compositions showed relatively high concentrations of secondary pollutants (NH₄NO₃ and (NH₄)₂SO₄), CaCO₃, and Ca(NO₃)₂ compared to that during non Asian dust period. DSS2009 exhibited the typical characteristics of Asian dust having a high concentration of Ca²⁺ with higher equivalent concentration of cations than anions in all size bins. Cl^? loss was hardly observed. The secondary pollutants were lower than that of non Asian dust cases. The result of reconstruction of ionic components indicated the CaCO₃ derived from soil particle, CaSO₄, and Ca (NO₃)₂ were dominant in DSS2009.     

The Use of Stable Sulfur, Oxygen and Hydrogen Isotope Ratios as Geochemical Tracers of Sulfates in the Podwiśniówka Acid Drainage Area (South-Central Poland)

The paper presents the results of determinations of stable S and O isotopes of dissolved sulfates and O and H stable isotopes of waters from three ponds, that is, Marczakowe Do?y acid pond, Marczakowe Do?y fish pond and Podwi?niówka acid pit pond, located in the Holy Cross Mountains (south-central Poland). The δ³⁴S_V-CDT and δ¹⁸O_V-SMOW of SO₄ ^2? in waters of three ponds (n = 14) varied from ?16.2 to ?9.5 ‰ (mean of ?13.6 ‰) and from ?8.1 to ?3.2 ‰ (mean of ?4.8 ‰), respectively. The mean δ³⁴S–SO₄ ^2? values were closer to those of pyrite (mean of ?25.4 ‰) and efflorescent sulfate salts (mean of ?25.6 ‰), recorded previously in the Podwi?niówka quarry, than to sulfates derived from other anthropogenic or soil and bedrock sources. The SO₄ ^2? ions formed by bacterially induced pyrite oxidation combined with bacterial (dissimilatory) dissolved sulfate reduction, and presumably with subordinate mineralization of carbon-bonded sulfur compounds, especially in both Marczakowe Do?y ponds. In addition, the comparison of δ¹⁸O–SO₄ ^2? and δ¹⁸O–H₂O values indicated that 75–100 % of sulfate oxygen was derived from water. Due to the largest size, the Podwi?niówka acid pit pond revealed distinct seasonal variations in both δ¹⁸O–H₂O (?9.2 to ?1.6) and δD–H₂O (?29.7 to ?71.3) values. The strong correlation coefficient (r ² = 0.99) was noted between δ¹⁸O–H₂O and δD–H₂O values, which points to atmospheric precipitation as the only source of water. The sediments of both acid ponds display different mineral inventory: the Marczakowe Do?y acid pond sediment consists of schwertmannite and goethite, whereas Podwi?niówka acid pit pond sediment is composed of quartz, illite, chlorite and kaolinite with some admixture of jarosite reflecting a more acidic environment. Geochemical modeling of two acid ponds indicated that the saturation indices of schwertmannite and nanosized ε-Fe₂O₃ (Fe³⁺ oxide polymorph) were closest to thermodynamic equilibrium state with water, varying from ?1.44 to 3.05 and from ?3.42 to 6.04, respectively. This evidence matches well with the obtained mineralogical results.     

A study on carbon dioxide emissions from bituminous coal in Korea

Consumption of primary energy in Korea increased 5.25 % per year over a 10 years span starting in 1990. Korea ranked 8th in primary energy consumption in 2011; coal consumption increased 35 % from 87,827 million tons in 2006–119,321 tons in 2010. Heavy energy-consuming countries consistently conduct research to develop an emission factor of Tier 2 level, reflecting the characteristics of the fuel that they use. To calculate the emission factor of bituminous coal for fuel, this study developed emission factor and calculated emission amount by implementing fuel analysis on bituminous coal consumed in Korea between 2007 and 2009. CO₂ emission factor calculated by fuel analysis method is 95,315 kg/TJ, which is 0.75 % higher than the default value suggested by IPCC. The emission amount calculated by using the CO₂ emission factor in this study is 231.881 million tons, which has a difference of 1.739 million tons compared to the IPCC default value.     

Terrestrial water dynamics in the lower Ganges—estimates from ENVISAT and GRACE

In this study, the hydrodynamics of lower Ganges basin in India has been monitored using radar altimetry data from environmental satellite (ENVISAT) mission and microgravity data from the Gravity Recovery and Climate Experiment (GRACE) mission. River stage time series have been constructed for different virtual stations on the lower Ganges. Time series for the integrated water volume changes from microgravity measurements have also been constructed to characterize the seasonal and interannual fluctuation patterns in water storage and flux. The ENVISAT dataset indicates an average seasonal river stage fluctuation of 8 m in the lower Ganges River. The GRACE dataset reveals a seasonal fluctuation ranging from 0.18 to 0.40 m in the vertically integrated total water storage in the lower Ganges basin. The two independent datasets show broad similarity in the lower Ganges basin and outline the importance of space-based techniques for monitoring continental water resources.     

Period studies of classical Algol-type binaries II: UX Leo,RW Mon,EQ Ori,XZ UMa and AX Vul

This study presents an investigation of the orbital period variations of five Algol type binaries, UX Leo, RW Mon, EQ Ori, XZ UMa and AX Vul based on all available minima times. The O–C diagrams of all systems exhibit a periodic variation superimposed on a downward parabolic segment. The mass loss due to magnetic braking effect in the cooler components is assumed to account for the parabolic variation with a downward shape, while it is suggested that the light-time effect (LITE) due to an unseen component around the eclipsing binaries explains the tilted sinusoidal changes in their O–C diagrams. The orbital period decrease rates for the systems are estimated as approximately between about 0.7 and 2.5 s per century. It is clearly seen that mass loss effect is more dominant than the expected mass transfer for classical Algols in this study. The minimum mass of the probable third bodies around the eclipsing pairs was calculated to be ?0.5 M_⊙ except for UX Leo, in which it was estimated to be approximately 0.9 M_⊙. In order to search for third lights in the light curves of five systems, the V-light curves of the systems were analyzed and their physical and photometric parameters were determined. For UX Leo, a significant third light contribution was determined. We found a very small third light that can be tested using multi-color light curves, for RW Mon, EQ Ori and XZ UMa, while a third light for AX Vul could not be exposed.     

Ion-cyclotron waves in solar coronal hole

We investigate the effect of the plume/interplume lane (PIPL) structure of the solar polar coronal hole (PCH) on the propagation characteristics of ion-cyclotron waves (ICW). The gradients of physical parameters determined by SOHO and TRACE satellites both parallel and perpendicular to the magnetic field are considered with the aim of determining how the efficiency of the ICR process varies along the PIPL structure of PCH. We construct a model based on the kinetic theory by using quasi-linear approximation. We solve the Vlasov equation for O VI ions and obtain the dispersion relation of ICW. The resonance process in the interplume lanes is much more effective than in the plumes, agreeing with the observations which show the source of fast solar wind is interplume lanes. The solution of the Vlasov equation in PIPL structure of PCH, the physical parameters of which display gradients along and perpendicular direction to the external magnetic field, is thus obtained in a more general form than the previous investigations.     

Buoyant boundary layer flows- an analogy to the Ekman spiral

Abstract

Flow details inside the buoyant boundary layer in the heat-up process of a contained, stably stratified, fluid are presented. Numerical solutions were obtained for the heatup problem in a cylinder considered by Sakurai and Matsuda (1972). By plotting the scaled vertical velocity W versus the scaled temperature θ as functions of the normal distance from the sidewall, the precise shape of the buoyant layer spiral is constructed. The analogy between this spiral and the Ekman spiral in rotating fluids is apparent. As the Rayleigh number Ra increases, the magnitude of the scaled vertical velocity increases substantially, but the scaled temperature does not vary appreciably. The buoyant layer thickness is determined by measuring the zero-crossing normal distance for the vertical velocity. The buoyant layer suction increases significantly as Ra increases. The effects of vertical level and of time on the qualitative behavior of buoyant layer flows are found to be small. The buoyant layer flows decay over the heat-up time scale t _n ; t _h characterizes the time span over which the overall adjustment process in the inviscid interior region is accomplished. This work clarifies that the analogy between heat-up and spin-up, which has been known to exist in the main body of inviscid fluid, applies equally well to the boundary layer regions.     

Influence of trace element fluxes from submarine groundwater discharge (SGD) on their inventories in coastal waters off volcanic island,Jeju, Korea

The concentrations of trace elements in groundwater and seawater were measured in a coastal embayment (Bangdu Bay) of a volcanic island (Jeju) off the southernmost coast of Korea in August and December of 2009. The concentrations of trace elements (Al, Mn, Fe, Co, Ni, and Cu) in the groundwater in summer were approximately 20-fold higher than those in winter, with good correlation to each other. Overall, the concentrations of most of the trace elements in the groundwater were 3- to 70-fold higher than those in the seawater of this Bay. Simple budget calculations showed that large fluxes of submarine groundwater discharge (SGD)-driven trace elements were responsible for the unusually enhanced concentrations of trace elements (particularly for Al, Fe and Co) in the summer seawater. The results imply that the temporal changes in SGD-driven trace element fluxes are large and may contribute considerably to the budget of trace elements in the coastal ocean, particularly off a highly permeable volcanic island.