On mean sea-level along the Brazilian coast

Summary. (Part 1) Fourier analyses of mean monthly sea-level data from Belém, Fortaleza, Salvador and Imbituba, ports on the Brazilian coast, are made with simultaneous data of air temperature, sea surface atmospheric pressure, atmospheric precipitation and evaporation. Results show that the mean monthly sea-levels of ports below Recife's latitude show peaks in February-March and April-May which are apparently related to the seasonal temperature changes and the combined action of precipitation, winds and oceanographic large-scale changes. The port of Belém showed a stronger semi-annual seasonal component, which seems to be related to the alternate southern and northern hemispheres' influences of the atmospheric precipitation. (Part 2 of the paper presented at the Symposium concerned the longer term changes of sea-level, including an analysis of principal components. These subjects will be treated in a separate paper.)     

A Comparison between WCS and OPeNDAP for Making Model Results and Data Products Available through the Internet

Numerical models produce output with a large number of variables, grid cells and time steps. The same applies to algorithms that produce gridded datasets from sparse or abundant raw data. Further use of the resulting data products has been challenging, especially for dissemination outside the institute of origin. Due to the gradually increasing size of data products, simply downloading copies of them is becoming impossible. A gradual transition from traditional download methods to web services is therefore observed. Web services allow for on‐the‐fly access to subsets of data that were hitherto considered as indivisible granules. Here we compare the most mature candidates to serve gridded data through the web: the Open‐source Project for a Network Data Access Protocol (OPeNDAP) and Web Coverage Service (WCS) protocols. In the framework of the new Dutch National Model and Data Centre (NMDC.eu) a distributed data storage has been created by coupling OPeNDAP servers. A WCS service layer is provided for the same data. This allows us to compare OPeNDAP and WCS. Using several use cases, we compare the usability, performance and features of the two protocols.     

Middle Proterozoic–early Palaeozoic evolution of central Baltoscandian intracratonic basins: evidence for asthenospheric diapirs

The three intracratonic sedimentary basins located in central Baltoscandinavia, namely the Bothnian Gulf basin, the Bothnian Sea basin and the Baltic basin, developed in response to Middle Proterozoic and Late Proterozoic tectonic events, separated in time by about 800 Ma. Only the Baltic basin was subsequently affected by Caledonian orogenesis and Mesozoic rifting. Crustal extension was minor or did not take place during the Proterozoic basin evolution phases. However, according to the Moho topography, crustal thinning did take place. This was probably a result of subcrustal magmatism. On a craton-wide scale, the ages of granitoids, which intruded during the Middle Proterozoic basin formation, generally decrease from east to west. This fact, combined with the evidence provided by mantle-derived flood basalt magmatism, points to a moving asthenospheric diapir as the cause for basin development. Asthenospheric upwelling was probably also responsible for the second, Late Proterozoic, basin evolution phase, as evidenced by the lack of crustal thinning and extension, and the occurrence of tholeiitic intrusions. In addition, a Late Proterozoic thermally induced palaeo-high, located at about the position of the intracratonic basins, is compatible with indications from glaciations. As the ages of Late Proterozoic intracratonic basins also decrease from east to west across the craton, the location of asthenospheric diapirism during this time interval was also moving. For the Fennoscandian lithosphere, the presence of fundamental lithospheric weakness zones (e.g. terrane boundaries) might be an explanation for the formation of two generations of basins originating from asthenospheric upwelling at about the same location in the Fennoscandian Shield. The spacing and size of the Proterozoic intracratonic basins suggest that the asthenospheric diapirism was not deep seated. Therefore, sublithospheric convective processes might be the cause for the asthenospheric upwellings. Such processes are related to Rayleigh–Taylor instabilities in the sublithospheric mantle. Emplacement of an asthenospheric diapir causes a thermal bulge at the surface of the lithosphere. Modelling results demonstrate that erosion of the surficial high, succeeded by cooling of the lithosphere, can explain the accumulation of early Palaeozoic sediments in the Bothnian Sea basin, taking into account post-Ordovician vertical and lateral erosion of the basin fill.     

Actinian dominated intertidal mudflats: A new case of an extraordinary rare phenomenon from Southern Chile

Generally, estuarine intertidal mudflats constitute important nurseries for fish and foraging grounds for coastal birds by providing a plenitude of mollusks, worms, and crustaceans as prey, which in turn mostly feed on suspended and benthic microalgae, bacteria, and detritus. Despite the high productivity of such habitats, pronounced variability in both salinity and temperature results typically in low diversity. The only sea anemone reported from estuarine mud is the edwardsiid Nematostella vectensis Stephenson, 1935. It occurs widely in the northern hemisphere, and occasionally in extremely high density. Here we document another sea anemone from estuarine mud and muddy sand found in Southern Chile which has similar ecological attributes. Taxonomic confusion has impeded the reporting on this small but prominent member in a macrozoobenthic assemblage, the brooding Anthopleura hermaphroditica (Carlgren, 1899; Anthozoa: Actiniidae). It differs from N. vectensis by the presence of symbiotic algae. Average density under poly- to euhaline conditions in mud and muddy sand at around mid tide level was about 3 actinians per cm². An average abundance of 11,000 m^? 2, a biovolume of 487 cm³ m^? 2, and a biomass of 35.5 g dry organic weight m^? 2 were found in mud and muddy sand in two surveys 20 years apart. The mean fishing area of fully expanded individuals covers 42 ± 25 mm², corresponding to a circular area with a diameter of 7.3 ± 5.7 mm. Preliminary experiments indicate that associated benthos may be relegated to life below surface by the net of tentacles above the sediment. As no predators on A. hermaphroditica could be found on the mudflat, the success of this mixotrophic sea anemone may entail a trophic dead end.     

Effect of wave–bedform feedbacks on the formation of,and grain sorting over shoreface-connected sand ridges

The influence of wave–bedform feedbacks on both the initial formation of shoreface-connected sand ridges (sfcr) and on grain size sorting over these ridges on micro-tidal inner shelves is studied. Also, the effect of sediment sorting on the growth and the migration of sfcr is investigated. This is done by applying a linear stability analysis to an idealized process-based morphodynamic model, which simulates the initial growth of sfcr due to the positive coupling between waves, currents, and an erodible bed. The sediment consists of sand grains with two different sizes. New elements with respect to earlier studies on grain sorting over sfcr are that wave-topography interactions are explicitly accounted for, entrainment of sediment depends on bottom roughness, and transport of suspended sediment involves settling lag effects. The results of the model indicate that sediment sorting causes a reduction of the growth rate and migration speed of sfcr, whereas the wavelength is only slightly affected. In the case where the entrainment of suspended sediment depends on bottom roughness, the coarsest sediment is found in the troughs; otherwise, the finest sediment occurs in the troughs. Compared to previous work, modeled maximum variations in the mean grain size over the topography are in better agreement with field observations. Settling lag effects are important for the damping of high-wavenumber mode instabilities such that a preferred wavelength of the bedforms is obtained.     

Products and Mechanism of the Gas Phase Reaction of Ozone with β-Pinene

Gas phase ozonolysis of -pinene was performedin a 570 l static reactor at 730 Torr and 296 K insynthetic air and the products were analysed by acombination of gas phase FTIR spectroscopy, HPLC andIC analyses of gas phase and aerosol samples,respectively. The reaction mechanism was investigatedby adding HCHO, HCOOH and H₂O as Criegeeintermediate scavenger and cyclohexane as OH radicalscavenger. Main identified products (yields inparentheses) in the presence of cyclohexane as OHradical scavenger were HCHO (0.65 ± 0.04),nopinone (0.16 ± 0.04), 3-hydroxy-nopinone (0.15± 0.05), CO₂ (0.20 ± 0.04), CO (0.030± 0.002), HCOOH (0.020 ± 0.002), the secondaryozonide of -pinene (0.16 ± 0.05), andcis-pinic acid (0.02 ± 0.01). The decompositionof the primary ozonide was found to yieldpredominantly the excited C₉-Criegee intermediateand HCHO (0.84 ± 0.04) and to a minor extent theexcited CH₂OO intermediate and nopinone (0.16± 0.04). Roughly 40% of the excitedC₉-Criegee intermediate becomes stabilised andcould be shown to react with HCHO, HCOOH and H₂O. The atmospherically important reaction of thestabilised C₉-Criegee intermediate with H₂Owas found to result in a nopinone increase of (0.35± 0.05) and in the formation of H₂O₂(0.24 ± 0.03). Based on the observed products,the unimolecular decomposition/isomerisationchannels of the C₉-Criegee intermediate arediscussed in terms of the hydroperoxide and esterchannels. Subsequent reactions of the nopinonylradical, formed in the hydroperoxide channel, lead tomajor products like 3-hydroxy-nopinone but also tominor products like cis-pinic acid. A mechanismfor the formation of this dicarboxylic acid isproposed and its possible role in aerosol formationprocesses discussed.     

The rotation of Italy: Preliminary palaeomagnetic data from the Umbrian sequence,Northern Apennines

A preliminary collection of 43 palaeomagnetic samples (10 sites) from the miogeosynclinal and supposedly autochthonous Umbrian sequence in the Northern Apennines, Italy, was analysed by means of alternating magnetic fields and thermal demagnetization studies. The older group of samples, taken from the upper part of the Calcari Diasprini (Malm), the Fucoid Marls (Albian/Cenomanian) and from the basal part of the Scaglia Bianca (Early Late Cretaceous), all showed normal polarity directions and resulted in a mean site direction:D = 290.5°,I = +51.5°,α₉₅ = 11°,k = 74,N = 4.The younger group of samples, taken throughout the Scaglia Rossa sequence (Latest Cretaceous/Middle Eocene) showed normal and reversed polarity directions. In contrast to the older group, the magnetic analysis of these samples resulted in a considerably less dense grouping of site mean directions. This presumably is due to inaccuracies introduced with the very large bedding tilt corrections that had to be applied to the samples of some sites. A tentative mean site direction for these Scaglia Rossa samples was computed as:D = 351°,I = +52.5°,α₉₅ = 23.5°,k = 11.5,N = 5.Despite the low precision of the Scaglia Rossa result, the significant deviation between this Latest Cretaceous/Early Tertiary direction and the Late Jurassic/Early Late Cretaceous direction indicates a counterclockwise rotation of more than forty degrees. This rotation can be dated as Late Cretaceous.How far these data from the Northern Apennines apply to other parts of the Italian Peninsula has yet to be established. The timing of this rotation is not at variance with the data from other parts of Mediterranean Europe (Southern Alps, Iberian Peninsula) and from Africa. However, taking into account the preliminary nature of the results, the amount of rotation of the Northern Apennines seems to surpass the rotation angle which is deduced from the palaeomagnetic data for Africa.     

Response of littoral chironomid communities and organic matter to late glacial lake—level,vegetation and climate changes at Lago dell’Accesa (Tuscany,Italy)

This study focuses on the response of lacustrine littoral chironomid communities to late glacial changes in limnological, environmental and climate conditions in the Mediterranean context. Late glacial chironomid (Diptera: Chironomidae) assemblages, organic petrography and geochemistry were analysed in a sediment core from the littoral zone of Lago dell’Accesa (Tuscany, Italy), where the lake-level fluctuations and the vegetation history have been previously reconstructed. Comparison of the chironomid stratigraphy to other proxies (pollen assemblages, organic petrography and geochemistry, lake-level) and regional climate reconstruction suggested the predominant influence of lake-level changes on the littoral chironomid fauna. The main lowering events that occurred during the Oldest and the Younger Dryas were followed by higher proportions of taxa typical of littoral habitats. A complementary study of organic matter suggested the indirect impact of lake-level on the chironomids through changes in humic status and habitat characteristics, such as the type of substrate and aquatic macrophyte development. Several chironomid taxa, such as Glyptotendipes, Microtendipes and Cricotopus type patens, were identified as possible indicators of low lake-level in the late glacial records. Nevertheless, this study suggested that parallel analyses of organic matter and chironomid assemblages may be needed to circumvent misinterpretation of littoral chironomid assemblage stratigraphy. There was a weak response of the chironomid assemblages to small lake-level lowerings that corresponded to the Older Dryas and Preboreal oscillations. A higher level of determination, e.g. to the species group level, may be necessary to increase the sensibility of the indicators to lake-level changes.