The Aguablanca Ni–(Cu) sulfide deposit, SW Spain: geologic and geochemical controls and the relationship with a midcrustal layered mafic complex

The Aguablanca Ni–(Cu) sulfide deposit is hosted by a breccia pipe within a gabbro–diorite pluton. The deposit probably formed due to the disruption of a partially crystallized layered mafic complex at about 12–19 km depth and the subsequent emplacement of melts and breccias at shallow levels (<2 km). The ore-hosting breccias are interpreted as fragments of an ultramafic cumulate, which were transported to the near surface along with a molten sulfide melt. Phlogopite Ar–Ar ages are 341–332 Ma in the breccia pipe, and 338–334 Ma in the layered mafic complex, and are similar to recently reported U–Pb ages of the host Aguablanca Stock and other nearby calc-alkaline metaluminous intrusions (ca. 350–330 Ma). Ore deposition resulted from the combination of two critical factors, the emplacement of a layered mafic complex deep in the continental crust and the development of small dilational structures along transcrustal strike-slip faults that triggered the forceful intrusion of magmas to shallow levels. The emplacement of basaltic magmas in the lower middle crust was accompanied by major interaction with the host rocks, immiscibility of a sulfide melt, and the formation of a magma chamber with ultramafic cumulates and sulfide melt at the bottom and a vertically zoned mafic to intermediate magmas above. Dismembered bodies of mafic/ultramafic rocks thought to be parts of the complex crop out about 50 km southwest of the deposit in a tectonically uplifted block (Cortegana Igneous Complex, Aracena Massif). Reactivation of Variscan structures that merged at the depth of the mafic complex led to sequential extraction of melts, cumulates, and sulfide magma. Lithogeochemistry and Sr and Nd isotope data of the Aguablanca Stock reflect the mixing from two distinct reservoirs, i.e., an evolved siliciclastic middle-upper continental crust and a primitive tholeiitic melt. Crustal contamination in the deep magma chamber was so intense that orthopyroxene replaced olivine as the main mineral phase controlling the early fractional crystallization of the melt. Geochemical evidence includes enrichment in SiO₂ and incompatible elements, and Sr and Nd isotope compositions (⁸⁷Sr/⁸⁶Sr_i 0.708–0.710; ¹⁴³Nd/¹⁴⁴Nd_i 0.512–0.513). However, rocks of the Cortegana Igneous Complex have low initial ⁸⁷Sr/⁸⁶Sr and high initial ¹⁴³Nd/¹⁴⁴Nd values suggesting contamination by lower crustal rocks. Comparison of the geochemical and geological features of igneous rocks in the Aguablanca deposit and the Cortegana Igneous Complex indicates that, although probably part of the same magmatic system, they are rather different and the rocks of the Cortegana Igneous Complex were not the direct source of the Aguablanca deposit. Crust–magma interaction was a complex process, and the generation of orebodies was controlled by local but highly variable factors. The model for the formation of the Aguablanca deposit presented in this study implies that dense sulfide melts can effectively travel long distances through the continental crust and that dilational zones within compressional belts can effectively focus such melt transport into shallow environments.Electronic supplementary material Supplementary material is available in the online version of this article at and is accessible for authorized users.     

Ancient oxide- and sulphide-mineralization in the islands of Tenerife and La Gomera (Canary Archipelago, Spain)

The alkaline intrusive complexes of Tenerife and La Gomera (Canary Archipelago, Spain) are formed by nepheline syenites and alkali gabbroids, and represent part of the oldest magmatic episodes in both islands. This work presents new studies of the petrographic and geochemical features of these rocks, and offers the first data about their respective ore minerals (iron oxides and sulphides). Mineralization is represented in both complexes by iron-rich patches and veins displaying a simple paragenesis of magnetite, ilmenite, pyrite and pyrrhotite, in association with widespread chloritic alteration of the intrusive host rocks. The comparative study of the mineralogical, textural and chemical characteristics of the ore minerals allows a metallogenetic model to be proposed which comprises two stages (magmatic and hydrothermal) in La Gomera and only one (magmatic) in Tenerife. The migration of the sulphide-bearing hydrothermal fluids far from the intrusive complex in Tenerife, and/or possible re-melting process could explain the apparent absence of the later hydrothermal stage in Tenerife. Received: 29 January 1998 / Accepted: 1 April 1998     

Regional and species specific sexual reproductive patterns of three zooxanthellate scleractinian corals across the Eastern Tropical Pacific

Sexual reproduction of zooxanthellate scleractinian corals in the Eastern Tropical Pacific (ETP) is influenced by the interactive effects of regional and local oceanographic conditions, as well as a variety of other environmental factors. Differences in spatial and temporal gamete development and reproductive patterns of three widespread scleractinian corals of this region—Pocillopora damicornis (branching colony morphology, characterized as hermaphrodite broadcaster), Pavona gigantea (massive colonies, characterized as gonochoric broadcaster/sequential co‐sexually hermaphroditic) and Porites panamensis (encrusting colonies, characterized as gonochoric brooder)—were evaluated at local and regional scales across the ETP. This area extended from the Gulf of California (24°N) to the southern coast of Ecuador (–1°S), including offshore islands, using existing data pooled from prior studies. Predictive models were employed based on environmental variables: sea surface temperature, daylight hours, diffuse attenuation co‐efficient at 490 nm and photosynthetically active radiation. Datasets were extracted from satellite images ( https://oceancolor.gsfc.nasa.gov ) and analysed using WAM_STATIST ver. 6.33® software to obtain monthly average data from each site. The spatial (region, sub‐region and site) and seasonal (wet, dry) variation in reproductive activity (% colonies with gametes) differed among the three species; significant interactions were season × sub‐region for P. damicornis, season × site (sub‐region) for P. gigantea, and season × site for P. panamensis, for which sub‐region was not considered as a factor. The predictive models also suggest that gamete production/maturation of P. damicornis and P. gigantea is influenced by local differences in sea surface temperature and daylight hours. Porites panamensis was not correlated with any environmental variable examined. Variations in local and regional reproductive developmental patterns are likely an acclimatization response by each species imposed by the timing and duration of local stressor events. This analysis has provided insights into the diverse local and regional physical drivers that affect species responses and acclimatization in sexual reproduction across the ETP.     

Deadly oasis:Recurrent annihilation of Cretaceous desert bryophyte colonies;the role of solar,climate and lithospheric forcing

Many oases(wet interdunes)are sedimentary systems characterized by high-frequency water-level oscillations,marked changes in salinity and intense biological activity at their margins.They are considered to be one of the most challenging environments on Earth for ecosystem development.These dynamic,depositional settings are usually unfavourable for fossilization and subsequent preservation of vegetal remains.This paper describes bryophyte(liverwort)assemblages occurring in three successive horizons interpreted to represent(i)recurrent early successional phases of biological soil crust colonization of wet interdune margins or(ii)exceptional preservation of floating or riparian liverworts in oasis pond waters associated with a progressive fall of the interdune water level.The record of in situ colonization surfaces characterized by delicate(e.g.lignin-free)three-dimensional structures represents an exceptional type of preservation herein associated with a rapid variation in phreatic interdune water level and the subsequent establishment of anoxic and reducing conditions.The occurrence of exceptionally preserved liverwort colonies coincides with the sedimentary record of,at least,three seismite levels in the oasis.Data gathered from the site suggests that the water table of the oasis was controlled by a combination of(i)a positive creation of accommodation space due to subsidence associated with movement on syn-sedimentary extensional faults,and(ii)the rise and fall of the oasis water table controlled by the oscillations of the groundwater system due to orbital changes which appear to drive the variability of the climate system.Rising groundwater levels flooded the oasis soil crusts and lead to the exceptional recurrent preservation of liverwort colonies at the oasis margins.Alternatively,considering the hypothesis of floating or riparian liverworts in the oasis pond waters,the fall in the level of the oasis water table placed the floating liverworts in contact with the oasis bottom sediments.This fall in the level of the oasis water table could indicate a cessation of accommodation space by syn-sedimentary extensional faults and/or a regional lowering of the groundwater system level associated with drought periods.Preliminary results indicate that oasis lamination between liverwort colonies records decadal and sub-decadal cyclicity,related with 11-year Schwabe sunspot and sub-decadal NAO cyclicities,conferring for every sedimentary cycle between liverwort colonies a duration of approximately 200 years,that otherwise matches the expected recurrence period for the De Vries cycle of solar activity.     

Hydro-morphological characteristics and hydrogeological functioning of a wetland system: a case study in southern Spain

The analysis and interpretation of physical and limnological parameters combined with hydrochemical (major ions and stable isotopes) analyses enabled us to evaluate the hydrogeological functioning and the hydrogeochemical evolution of groundwater in two adjacent lakes related to a karstic aquifer (Archidona, southern Spain). Lake water, groundwater and the outflow from a spring, were monitored periodically from 1998 to 1999 and sporadically from 2000 to 2006. The evolution of groundwater chemistry from recharge (dolines) to discharge areas (spring) showed an increment of 20% in magnesium and 15% in sulphate, and such higher increments were recorded for the water from the lakes, suggesting the existence of different hydrogeological paths. A simple water budget model, together with morphological interpretation, suggests that groundwater discharge into the lakes is of relative importance to the input into these systems. Finally, we believe that the development of a new typology for hydro-morphological elements, by means of several hydrological factors and the assessment of pressures and impacts will be useful for the correct management of these lakes and other semi-arid aquatic ecosystems.     

Mountain Front Development by Folding and Crustal Thickening in the Internal Zone of the Betic Cordillera-Alboran Sea Boundary

The boundary between the Alboran Sea and Betic Cordillera is a good example of a fold related mountain front in the Internal Zone of an alpine mountain range. Since the late Miocene, NNW-SSE convergence between the Eurasian and African plates has produced shortening and related orthogonal extension. To improve the characterisation of the geometry of the deep structure in the region and to establish the recent tectonic evolution of the mountain front, well logs and newly acquired geophysical data (multichannel reflection seismic and gravimetric surveys) have been interpreted and integrated with available surface data. The most marked tectonic structure corresponds to large antiforms and synforms of ENE-WSW trend which are related to mountain ranges and basins, respectively. The fold belt continues toward the northern continental shelf of the Alboran Sea. The fold vergence is generally northwards and its amplitude decreases progressively towards SSE, until disappearring in a sharp boundary where the reflectors are undeformed. The deep geometry suggests that fold growth started during upper Tortonian times and continued its activity up to Pliocene or even Quaternary times. The NNW-SSE compression produces crustal thickening and a regional and progressive southwards emersion. The location of main present-day deformation fronts in the Internal Zones contrasts with classical models where the deformation progresses towards the frontal part of External Zones of cordilleras. In addition, this fold-related deformation mountain front has features different from fault related fronts, as it does not show a sharp boundary, and folds that determine rectilinear mountain boundaries decrease progressively in amplitude or in wavelength up to undeformed areas.     

Radiating Fluid Spheres in the Effective Variables Approximation

We study the evolution of spherically symmetric radiating fluid distributions using the effective variables method, implemented ab initio in Schwarzschild coordinates. To illustrate the procedure and to establish some comparison with the original method, we integrate numerically the set of equations at the surface for two different models. The first model is derived from the Schwarzschild interior solution. The second model is inspired in the Tolman VI solution.     

Changes in Climate and Crop Production During the 20th Century in Argentina

This work was focused on the assessment of changes occurring in crop production and climate during the 20th century in Argentina. The study was carried out for nine sites located in the Pampas region that are representative of contrasting environments. We have considered the four main crops cultivated in this area (wheat, maize, sunflower and soybean). Historical climatic data and crop production related variables (yield, planted area, harvested area) were analyzed and, by means of crop simulation models, we quantified the impact of climate on crop yields. Changes occurring in climate during the three last decades of the 20th century were characterized by important increases in precipitation especially between October and March, decreases in maximum temperature and solar radiation in particular during spring and summer and increases in minimum temperature during almost all of the year. These changes contributed to increases in yields, especially in summer crops and in the semiarid zone, mostly due to increases in precipitation, although changes in temperature and radiation also affected crop yields but to a lesser extent. Comparing the period 1950–1970 with 1971–1999, yields increases attributable to changes in climate were 38% in soybean, 18% in maize, 13% in wheat, and 12% in sunflower while mean observed yield increases were 110% for maize, 56% for wheat and 102% for sunflower.     

The role of hydrological processes in ecosystem conservation: Comprehensive water management for a wetland in an arid climate

Water agreements between Mexico and the United States have been crucial to preserving and restoring the Colorado River Delta's wetlands. Nowadays, increased water demand and climate change in the Colorado River Basin could threaten the conservation of the Ciénega de Santa Clara, a 4709 ha coastal wetland at the Sonoran Desert's edge. The international Ramsar convention recognizes the Ciénega de Santa Clara ecosystem for providing vital ecological services, including habitat for endemic, endangered, and migratory species. The hydrology of this wetland has not been completely understood since the 2010–2011 trial run of the Yuma Desalting Plant. Therefore, this study was conducted to identify and quantify the hydrological elements essential for the conservation of this wetland, under three scenarios: (a) normal inflow conditions of the water source – the Wellton-Mohawk canal; (b) inflow reductions, and; (c) an increase of temperature due to global warming. Water and mass balances estimates were conducted every month during 2014–2015; in situ measurements of inflows were carried out on Southern International Boundary in Wellton-Mohawk canal, the Riíto Drain, groundwater, and precipitation: evapotranspiration outputs were estimated using local weather stations and Penman-Monteith formulations. Temperature increases were based on the Intergovernmental Panel on Climate Change projections for the next 100 years. Results showed disconnection in the surface flow of water from the wetland to the adjacent Gulf of California. This behaviour was observed mainly in the summer months in the three scenarios. The disconnections reduced the wetland area and water storage. The hydrological functionality of the Ciénega de Santa Clara wetland depends on the water supply from the Wellton-Mohawk canal, with a minimum continuous discharge of 5.10 m³ s⁻¹ during the summer months.