长江水氢、氧同位素组成的时空变化及其环境意义

在2003～2007年间,在长江干流的25个水文站及主要支流的13个水文站系统采样,进行了氢氧同位素研究。观测到的D变化范围为-30‰～-112‰,变化范围为-3.8‰～-15.4‰。从长江源头到河口,不同时期的样品均显示相同的氢氧同位素沿程变化特征。从源头到攀枝花,长江干流的D与逐步下降;而由攀枝花到入海口,D与值逐渐升高。 研究发现,控制长江水的氢氧同位素组成的主要因素是大气降水。长江干流D与值所展现的从攀枝花至河口逐渐升高的趋势就是对流域大气降水的D与变化趋势的响应。长江各支流在氢氧同位素组成上的差别及其对干流的影响也反映大气降水对长江水的制约。 蒸发作用对长江水的氢氧同位素组成也有重要影响。长江源头地处青藏高原,高原湖泊和沼泽星罗棋布。由于气候干燥、日照强烈,湖沼水经过长期的蒸发,盐度逐渐加大,D和18O值也逐渐升高。这些湖水的加入对长江水的氢氧同位素组成也造成一定影响。蒸发作用在枯水期也使洞庭湖与鄱阳湖的D和18O值升高,进而提高长江相关河段的D和18O值。 冰雪融化是影响长江水的氢氧同位素组成的另一重要因素。在长江源头和所有左岸支流的源头,冰川融雪都是重要的水源之一。由于冰川水在氢氧同位素组成上的特殊性,其对河水贡献的大小将影响河水的氢氧同位素组成。 三峡大坝对于长江的水动力体系影响巨大,三峡水库对长江水资源的调控作用有待长期观测研究。从本次的研究资料来看,三峡大坝在丰水期对相应河段的氢氧同位素变化趋势影响不大。但在枯水季节,三峡水库蓄水使下游的宜昌和沙市的水源发生明显变化,导致D和18O值的显著降低。 长江水资源状况及其演变趋势是受到各方面高度关注的重要研究课题。为深入探讨这一问题,需要了解长江水资源的变化与各种气象与水文要素之间的关系,查明大气降水、地下水、冰川水、湖水与河水之间的交互作用。而氢氧同位素示踪技术在这方面可以发挥关键性的作用。由于现有资料有限,目前还无法利用氢氧同位素组成来追溯其气候条件的详细演化过程。但若能在进行系统水文测量的同时,适当开展氢氧同位素测定,将对研究长江水资源状况及其演变趋势大有脾益。     

特提斯喜马拉雅带江孜地区古近纪地层源区分析——对造山带早期地壳加厚的制约

特提斯喜马拉雅北亚带江孜地区上古新统-下始新统甲查拉组记录了喜马拉雅碰撞造山带的早期地壳加厚和沉积历史。本文我们报道了甲查拉组详细的碎屑锆石U-Pb年龄和全岩Sm-Nd同位素数据。甲查拉组由青灰色厚层的岩屑砂岩夹泥岩组成,不整合覆盖在宗卓组之上,碎屑锆石主要的峰值介于350～80 Ma, 900～470 Ma以及1 300～950 Ma,次要的峰值介于2 800～1 500 Ma。全岩⁸⁷Sr/⁸⁶Sr介于0.707 505～0.713 174,¹⁴³Nd/¹⁴⁴Nd介于0.512 206～0.512 355,ε_Nd(0)介于-5.52～-8.43。甲查拉组物源区以再循环的日喀则弧前盆地和上三叠统郎杰学群为主,少量物质来自雅鲁藏布江缝合带。上述研究表明,甲查拉组沉积在周缘前陆盆地的背景下,且特提斯喜马拉雅北亚带在始新世期间经历了明显的地壳加厚。     

印度与欧亚板块碰撞以来东喜马拉雅构造结的演化

在野外填图,构造观察及前人研究的基础上,本文识别并描述了东喜马拉雅构造结中的推覆断裂、正断裂及走滑断裂、背斜(形)和向斜(形)等构造类型,讨论了这些构造位置及与印度板块挤入,印支地块旋转的关系,还探讨了东喜马拉雅构造结对印度板块持续向北推挤下的特殊应变调节方式。在印度大陆部分,东喜马拉雅构造结由3个向外逐渐变新的构造结组成,即北东向的南迦巴瓦峰复式背斜、北西向的桑复式向斜及北东向的阿萨母复式向斜。上述3个构造结是协调印度板块的挤入、喜马拉雅弧的扩展及印支地块的旋转的构造。在欧亚大陆内部的冈底斯岛弧,在派区及阿尼桥走滑断裂协调下,高喜马拉雅结晶岩的基底挤入冈底斯岛弧内部,在大拐弯顶端形成向上的挤出构造。在南迦巴瓦峰构造结的北西侧,由于掀斜式抬升及重力滑动,使得冈底斯盖层与结晶基底脱耦,上盘盖层沿东久向北西方向滑动。在南迦巴瓦峰构造结北东侧,由于印支地块的挤出和旋转,形成一系列的北西向走滑断裂,如实皆断裂、嘉黎-高黎贡断裂、澜沧江断裂及红河断裂等。     

西北黄土地区地铁深基坑工程监测的关键技术

根据西北黄土地区第一条地铁——西安地铁近四年地铁基坑工程的监测经验,提出了基坑工程监测的主要内容、作用及其常用监测手段,介绍了轴力监测关键技术;测斜仪量测墙体位移关键技术;地裂缝段地表监测点布设的关键技术;盾构地表监测作用、监测项目、地层移动特征;监测报警注意事项。其中着重分析了黄土地区常用的内支撑形式——钢支撑监测的注意事项及常见异常测量数据的出现原因,提出温度对其测量结果的影响不可忽略。     

Rapid Eocene erosion,sedimentation and burial in the eastern Himalayan syntaxis and its geodynamic significance

The lower Bomi Group of the eastern Himalayan syntaxis comprises a lithological package of sedimentary and igneous rocks that have been metamorphosed to upper amphibolite-facies conditions. The lower Bomi Group is bounded to the south by the Indus–Yarlung Suture and to the north by unmetamorphosed Paleozoic sediments of the Lhasa terrane. We report U–Pb zircon dating, geochemistry and petrography of gneiss, migmatite, mica schist and marble from the lower Bomi Group and explore their geological implications for the tectonic evolution of the eastern Himalaya. Zircons from the lower Bomi Group are composite. The inherited magmatic zircon cores display ²⁰⁶Pb/²³⁸U ages from ~ 74 Ma to ~ 41.5 Ma, indicating a probable source from the Gangdese magmatic arc. The metamorphic overgrowth zircons yielded ²⁰⁶Pb/²³⁸U ages ranging from ~ 38 Ma to ~ 23 Ma, that overlap the anatexis time (~ 37 Ma) recorded in the leucosome of the migmatites. Our data indicate that the lower Bomi Group do not represent Precambrian basement of the Lhasa terrane. Instead, the lower Bomi Group may represent sedimentary and igneous rocks of the residual forearc basin, similar to the Tsojiangding Group in the Xigaze area, derived from denudation of the hanging wall rocks during the India–Asia continental collision. We propose that following the Indian–Asian collision, the forearc basin was subducted, together with Himalayan lithologies from the Indian continental slab. The minimum age of detrital magmatic zircons from the supracrustal rocks is ~ 41.5 Ma and their metamorphism had happened at ~ 37 Ma. The short time interval (< 5 Ma) suggests that the tectonic processes associated with the eastern Himalayan syntaxis, encompassing uplift and erosion of the Gangdese terrane, followed by deposition, imbrication and subduction of the forearc basin, were extremely rapid during the Late Eocene.     

川中东北部中-下侏罗统湖相碳酸盐岩碳氧同位素特征及其古环境意义

在钻井岩心观察和岩石学分析的基础上,对川中东北部龙岗地区中-下侏罗统自流井组和凉高山组典型钻井取心段碳酸盐岩样品进行了碳氧同位素分析。40余件样品的测试结果表明,δ¹³C_PDB值在-1.24‰～4.59‰之间,除了1个负值外,都为正值。δ¹⁸O_PDB值在-15.7‰～-9.83‰之间,都为负值。与海相和陆相碳酸盐岩同位素值对比显示,自流井期和凉高山期古湖泊均表现出内陆开放性淡水湖泊的特点,没有经过明显的海水入侵。在中-下侏罗统广泛存在的碳同位素正偏移是由湖泊初级生产力提高所导致的。岩相和同位素变化显示了古湖平面经历了2次主旋回和6次次级旋回变化,湖平面变化总体表现为东岳庙段沉积期＞大一三亚段沉积期＞大一亚段沉积期＞凉高山期＞马鞍山段沉积期。古湖泊初级生产力的变化表现为大一三亚段沉积期＞东岳庙段沉积期＞大一亚段沉积期＞凉高山期＞马鞍山段沉积期。     

Observation of CO2 degassing in Tianshuihai Lake Basin of the Qinghai-Tibetan Plateau

A large volume of underground gas in the permafrost region of the Qinghai-Tibetan Plateau has been identified. Although many studies were performed to investigate the soil organic carbon dynamics and Earth degassing in volcanic areas, this is the first report of a large amount of non-volcanic CO₂ contained in permafrost. The gas was mostly CO₂ (81.76 vol. %) and nitrogen (14.59 vol. %). The gas composition and the evidence from carbon stable isotope values (?23.9 ‰, PDB) suggested that the gases possibly had a deep origin. The gas emissions may be triggered by permafrost degradation, which means mitigation of the barrier effect of permafrost for the gas. In addition, plate tectonic processes may also lead to gas emissions, as the tectonic activity is strong in the area. Therefore, particular attention should be paid to the underground gases in the study of global change and permafrost degradation.     

Hydrogeochemical and isotopic evidences of the groundwater regime in Datong Basin, Northern China

Datong Basin is one of the Cenozoic faulted basins in Northern China’s Shanxi province, where groundwater is the major source of water supply. The results of hydrochemical investigation show that along the groundwater flow path, from the margins to the lower-lying central parts of the basin, groundwater generally shows increases in concentrations of TDS, HCO₃ ^?, SO₄ ^2?, Cl^?, Na⁺ and Mg²⁺ (except for Ca²⁺ content). Along the basin margin, groundwater is dominantly of Ca–HCO₃ type; however, in the central parts of the basin it becomes more saline with Na–HCO₃-dominant or mixed-ion type. The medium-deep groundwater has chemical compositions similar to those of shallow groundwater, except for the local area affected by human activity. From the mountain front to the basin area, shallow groundwater concentrations of major ions increase and are commonly higher than those in medium-deep aquifers, due to intense evapotranspiration and anthropogenic contamination. Hydrolysis of aluminosilicate and silicate minerals, cation exchange and evaporation are prevailing geochemical processes occurring in the aquifers at Datong Basin. The isotopic compositions indicate that meteoric water is the main source of groundwater recharge. Evaporation is the major way of discharge of shallow groundwater. The groundwater in medium-deep aquifers may be related to regional recharges of rainwater by infiltrating along the mountain front faults, and of groundwater permeating laterally from bedrocks of the mountain range. However, in areas of groundwater depression cones, groundwater in the deep confined aquifers may be recharged by groundwater from the upper unconfined aquifer through aquitards.     

Investigation of manganese tolerance and accumulation of two Mn hyperaccumulators Phytolacca americana L. and Polygonum hydropiper L. in the real Mn-contaminated soils near a manganese mine

Up to date, very few studies have examined the phytoextraction ability of hyperaccumulators in the real soils contaminated with heavy metals following the identification of the hyperaccumulators using hydroponics tests. In the present study, amended with a chemical-mobilizing agent of ethylene diamine triacetic acid (EDTA), the manganese accumulation, tolerance and the hyperaccumulating ability of two hyperaccumulators Phytolacca americana L. (Phytolaccaceae) and Polygonum hydropiper L. (Polygonaceae) proved by previous hydroponics tests were examined using pot experiments with paddy soils contaminated with Mn (1,047 ± 53 mg kg^?1) collected from one site in the vicinity of one manganese mine in Xiushan county of Chongqing, China. Results showed that the root and shoot biomass of P. americana and the chlorophyll production of P. hydropiper were significantly inhibited by EDTA treatments while the chlorophyll production of P. americana was oppositely obviously promoted by EDTA. It is noteworthy that, with or without EDTA treatment, the shoot Mn concentrations of both plant species were significantly below the hyperaccumulator threshold, indicating these two plants concealed their hyperaccumulating ability in the studied soils. Thus, further detailed studies need to be conducted to promote the metal hyperaccumulating capacity of these two plant species under comparably low Mn-contaminated soil conditions as shown in this study before the successful application of these Mn hyperaccumulators identified in laboratories to the phytoextraction of lightly or moderately Mn-contaminated agricultural soils.     

滇西南芦子园超大型铅锌多金属矿床成矿模式与综合找矿模型

滇西南芦子园铅锌多金属矿床是近年来在三江成矿省保山一镇康铅-锌-铜-铁-锡-金成矿带发现并评价的第一个超大型矿床。在前人研究成果的基础上,结合本区多年的工作成果,总结了芦子园超大型铅锌多金属矿床的找矿标志．并初步建立了矿床的成矿模式和找矿模型。研究表明,芦子园铅锌多金属矿床是以寒武系上统为容矿地层并提供初始矿源,印支期中基性岩浆岩提供部分成矿物质,并受燕山期和喜马拉雅期隐伏酸性侵入体控制的叠加改造型矿床。区域物化探异常特征表明．该多金属矿床具有超大型矿床的典型矿化特征与找矿标志。