Sulfide and iron control on mercury speciation in anoxic estuarine sediment slurries

In order to understand the role of sulfate and Fe(III) reduction processes in the net production of monomethylmercury (MMHg), we amended anoxic sediment slurries collected from the Venice Lagoon, Italy, with inorganic Hg and either potential electron acceptors or metabolic byproducts of sulfate and Fe(III) reduction processes, gradually changing their concentrations. Addition of sulfide (final concentration: 0.2–6.3 mM) resulted in an exponential decrease in the sulfate reduction rate and MMHg concentration with increasing concentrations of sulfide. Based on this result, we argue that the concentration of dissolved sulfide is a critical factor controlling the sulfate reduction rate, and in turn, the net MMHg production at steady state. Addition of either Fe(II) (added concentration: 0–6.1 mM) or Fe(III) (added concentration: 0–3.5 mM) resulted in similar trends in the MMHg concentration, an increase with low levels of Fe additions and a subsequent decrease with high levels of Fe additions. The limited availability of dissolved Hg, associated with sulfide removal by precipitation of FeS, appears to inhibit the net MMHg production in high levels of Fe additions. There was a noticeable reduction in the net MMHg production in Fe(III)-amended slurries as compared to Fe(II)-amended ones, which could be caused by a decrease in the sulfate reduction rate. This agrees with the results of Hg methylation assays using the enrichment cultures of anaerobic bacteria: whereas the enrichment cultures of sulfate reducers showed significant production of MMHg (4.6% of amended Hg), those of Fe(III), Mn(IV), and nitrate reducers showed no production of MMHg. It appears that enhanced Fe(III)-reduction activities suppress the formation of MMHg in high sulfate estuarine sediments.     

Relocation effects of dredged marine sediments on mercury geochemistry: Venice lagoon,Italy

Understanding the biogeochemical process of Hg is critical in the overall evaluation of the ecological impacts resulting from the reuse of Hg-contaminated dredged sediment. Sediment banks (V1 and V2) were constructed with freshly dredged sediments from a navigational channel in Venice Lagoon, Italy, with the goal of clarifying potential differences in the biogeochemistry of Hg between the reused dredged sediments and those from surrounding sites (SS1 and S2). Toward this purpose, Hg and monomethylmercury (MMHg) concentrations, and Hg methylation rates (MMRs) in the surface 2.5 cm sediments were monitored, along with ammonium, iron, sulfate and sulfide concentrations in the pore waters of banks and surrounding sites from November 2005 to February 2007. Pore water analyses indicate that the bank sediments are characterized by lower levels of sulfate and iron, and by higher levels of ammonium and sulfide compared to the surrounding sediments. With respect to Hg speciation, the fractions of MMHg in total Hg (%MMHg/Hg) and the MMRs were significantly lower in the bank V1 compared to those in the reference site SS1, whereas the %MMHg/Hg and the MMRs were similar between V2 and S2. A negative correlation is found between the logarithm of the particle-water partition coefficient of Hg and the MMR, indicating that the reduced MMRs in V1 are caused by the limited concentrations of dissolved Hg. Organic matter appears to play a key role in the control of MMR via the control of Hg solubility.     

Modern swathe sounding and sub-bottom profiling technology for research applications: The Atlas Hydrosweep and Parasound Systems

This chapter describes two separate but complementary research echosounder systems originally developed by Krupp Atlas Elektronik GmbH for the new German oceanographic research vessel Meteor.The Hydrosweep is a Hydrographic wide-swathe sweep survey echosounder for both shallow and deep water applications providing accurate bathymetric surveys and terrain-following navigation capabilities.The Parasound system is a hull-mounted dual channel parametric narrow-beam deep sea survey and sub-bottom profiling echosounder enabling particularly high vertical and horizontal resolution of seabed features.     

Planetary orbital equations in externally-perturbed systems: position and velocity-dependent forces

The increasing number and variety of extrasolar planets illustrates the importance of characterizing planetary perturbations. Planetary orbits are typically described by physically intuitive orbital elements. Here, we explicitly express the equations of motion of the unaveraged perturbed two-body problem in terms of planetary orbital elements by using a generalized form of Gauss’ equations. We consider a varied set of position and velocity-dependent perturbations, and also derive relevant specific cases of the equations: when they are averaged over fast variables (the “adiabatic” approximation), and in the prograde and retrograde planar cases. In each instance, we delineate the properties of the equations. As brief demonstrations of potential applications, we consider the effect of Galactic tides. We measure the effect on the widest-known exoplanet orbit, Sedna-like objects, and distant scattered disk objects, particularly with regard to where the adiabatic approximation breaks down. The Mathematica code which can help derive the equations of motion for a user-defined perturbation is freely available upon request.     

Stream overflow and dwarf nova eruptions

We consider the effects of accretion stream overflow on the viscous dynamics of accretion discs in dwarf novae. If the stream from the secondary star is geometrically thick enough, some fraction of its material can flow over and under the disc. The mass and specific angular momentum of the stream are then deposited not only at the point of collision with the outer disc, but also at those radii in the inner disc with geometric heights that are large enough to intercept the residual stream, or near the radius where the disc has the same specific angular momentum as the stream. The overflowing stream can alter the behaviour of heating fronts and cooling fronts in the disc. If the mass fraction of the overflowing stream is of order tens of per cent, the deposition of mass in the inner parts of the disc is sufficient to change the character of the eruption light curves significantly.     

An instrument for commissioning the active and adaptive optics of modern telescopes: the Infrared Test Camera for the Large Binocular Telescope

We describe the design, integration, and operation of the infrared test cameras for the commissioning of the Large Binocular Telescope. The design and construction phase lasted slightly more than one year from February 2007 to April 2008 and was the result of a joint collaboration among INAF Osservatorio Astronomico di Bologna, Università di Bologna Dipartimento di Astronomia (Italy) and the Max-Planck-Institut für Astronomie (Heidelberg, Germany). Thereafter, the camera was delivered to the LBT Observatory (USA) for commissioning of the telescope active optics and, more recently, for commissioning of the first light adaptive optics.     

Structural properties of pseudo-bulges, classical bulges and elliptical galaxies: a Sloan Digital Sky Survey perspective

We have performed 2D bulge/bar/disc decompositions using g , r and i -band images of a representative sample of nearly 1000 galaxies from the Sloan Digital Sky Survey. We show that the Petrosian concentration index is a better proxy for the bulge-to-total ratio than the global Sérsic index. We show that pseudo-bulges can be distinguished from classical bulges as outliers in the Kormendy relation. We provide the structural parameters and distributions of stellar masses of ellipticals, classical bulges, pseudo-bulges, discs and bars, and find that 32 per cent of the total stellar mass in massive galaxies in the local universe is contained in ellipticals, 36 per cent in discs, 25 per cent in classical bulges, 3 per cent in pseudo-bulges and 4 per cent in bars. Pseudo-bulges are currently undergoing intense star formation activity and populate the blue cloud of the colour–magnitude diagram. Most (though not all) classical bulges are quiescent and populate the red sequence of the diagram. Classical bulges follow a correlation between the bulge Sérsic index and bulge-to-total ratio, while pseudo-bulges do not. In addition, for a fixed bulge-to-total ratio, pseudo-bulges are less concentrated than classical bulges. Pseudo-bulges follow a mass–size relation similar to that followed by bars, and different from that followed by classical bulges. In the fundamental plane, pseudo-bulges occupy the same locus as discs. While these results point out different formation processes for classical and pseudo-bulges, we also find a significant overlap in their properties, indicating that the different processes might happen concomitantly. Finally, classical bulges and ellipticals follow offset mass–size relations, suggesting that high-mass bulges might not be simply high-mass ellipticals surrounded by discs.