Chemistry of metal–humic complexes contained in Megalopolis lignite and potential application in modern organomineral fertilization

Lignite samples from two deposits located in the Megalopolis Basin, Southern Greece, were evaluated for their potential applicability as raw materials for the production of organomineral fertilizers. Fundamental chemical analyses were carried out to demonstrate high humic substances and metal contents. To determine their relative distribution in the Megalopolis lignite extract, eight elements, namely Na, K, Cd, Mn, Mg, Pb, Zn, and Cu, were studied both in H₂O and in Na₄P₂O₇/NaOH solutions. The behavior of these metals showed significant variations; Zn, Pb, Cd, and Cu associate mostly to the humic substances and proved scarce in the water extract. Contrarily, K and Mg gave a significantly low total yield in the Na₄P₂O₇/NaOH solution, while Mn was classified among the least extracted elements. Further enrichment of Megalopolis humic substances in these metals was achieved; Pb and Mg proved the most and least retained metal, respectively. Decomplexation titration curves of humic matter saturated with these metal ions demonstrated that novel organomineral fertilizing materials may develop based on optimized metal ion and humate contents, which can retain metals in a soluble form within a wide pH range. Formation of complexes between humic substances and Zn, Cd, and Mg was clearly indicated.     

Assessment of the Water and Habitat Quality of a Mediterranean River (Kalamas,Epirus, Hellas), in Accordance with the EU Water Framework Directive

In the present study, the water quality of Kalamas river (NW Greece) was evaluated using physicochemical and hydromorphological parameters and benthic macroinvertebrates. Statistical analyses (Cluster and FUZZY analyses) were performed and two biotic scores (BMWP' and HS) were used in order to classify the sites according to water quality. Kalamas river appeared to have excellent tomoderate water quality at all sampling sites except one (close to the delta area) which was ”fairly or significantly polluted”. During the low flow season water quality appeared poorer than during the high flow season. The ecological parameters (hydromorphological, chemical, and biological) used for this integrated approach are the ones proposed by the New Water Directive 2000/60 EC for an efficient surveying monitoring of running waters.     

A process oriented characterization of tropical oceanic clouds for climate model evaluation, based on a statistical analysis of daytime A-train observations

This paper aims at characterizing how different key cloud properties (cloud fraction, cloud vertical distribution, cloud reflectance, a surrogate of the cloud optical depth) vary as a function of the others over the tropical oceans. The correlations between the different cloud properties are built from 2?years of collocated A-train observations (CALIPSO-GOCCP and MODIS) at a scale close to cloud processes; it results in a characterization of the physical processes in tropical clouds, that can be used to better understand cloud behaviors, and constitute a powerful tool to develop and evaluate cloud parameterizations in climate models. First, we examine a case study of shallow cumulus cloud observed simultaneously by the two sensors (CALIPSO, MODIS), and develop a methodology that allows to build global scale statistics by keeping the separation between clear and cloudy areas at the pixel level (250, 330?m). Then we build statistical instantaneous relationships between the cloud cover, the cloud vertical distribution and the cloud reflectance. The vertical cloud distribution indicates that the optically thin clouds (optical thickness <1.5) dominate the boundary layer over the trade wind regions. Optically thick clouds (optical thickness >3.4) are composed of high and mid-level clouds associated with deep convection along the ITCZ and SPCZ and over the warm pool, and by stratocumulus low level clouds located along the East coast of tropical oceans. The cloud properties are analyzed as a function of the large scale circulation regime. Optically thick high clouds are dominant in convective regions (CF?>?80?%), while low level clouds with low optical thickness (<3.5) are present in regimes of subsidence but in convective regimes as well, associated principally to low cloud fractions (CF?<?50?%). A focus on low-level clouds allows us to quantify how the cloud optical depth increases with cloud top altitude and with cloud fraction.     

DXL: a sounding rocket mission for the study of solar wind charge exchange and local hot bubble X-ray emission

The Diffuse X-rays from the Local galaxy (DXL) mission is an approved sounding rocket project with a first launch scheduled around December 2012. Its goal is to identify and separate the X-ray emission generated by solar wind charge exchange from that of the local hot bubble to improve our understanding of both. With 1,000 cm² proportional counters and grasp of about 10 cm² sr both in the 1/4 and 3/4 keV bands, DXL will achieve in a 5-min flight what cannot be achieved by current and future X-ray satellites.