Geochemical study on a well in the Western Canada Basin: relation of the aromatic distribution pattern to maturity of organic matter

Thirty-one rock samples from a Western Canada Basin well have been analysed for aromatics, using glass capillary gas chromatography with simultaneous flame ionization and sulfur-selective flame photometric detection. A uniform aromatic distribution pattern with a marked predominance of di- and tricyclic aromatic hydrocarbons was observed throughout a depth interval of 3000 meters comprising Cretaceous and Jurassic sediments. The very high relative abundance of sulfur aromatics at two narrow intervals in the Triassic and Mississippian is attributed to a major change in facies. Gradual changes with increasing depth have been observed for a series of compound ratios, which had been calculated from the isomers of methyl- and dimethylphenanthrene, and their parent compounds. These changes reflect the increasing thermal maturation of the sedimentary organic matter. A Methylphenanthrene Index (MPI) has been introduced, which exhibited a very good correlation with vitrinite reflectance data. The MPI is the first maturity parameter which is based on a series of aromatic hydrocarbons. This hydrocarbon internal maturity parameter permits the recognition and definition of maturity levels in extracts which can be compared to the maturity (e.g. vitrinite reflectance) of source rocks.     

Perception and evaluation of dead wood in streams and rivers by German students

Dead wood is a significant element of natural streams and rivers in temperate climate zones. Established stream management removes wood, whereas some scientists recently promoted the reintroduction of wood in stream rehabilitation and restoration. It is desirable to know if wood in streams and rivers would be accepted. A survey was therefore conducted in order to assess the spontaneous visual perception of 10 stream and 10 river scenes with and without wood in terms of naturalness, risk, aesthetics and need for improvement using visual analog scales. Three hundred and sixty-five German students from five subjects related to water management and from one subject without any professional association to running waters were surveyed before their first contact to teaching of aquatic ecology. They clearly perceived wood in streams and rivers as natural. Scenes with wood were most frequently associated with danger for sport activities while scenes without wood were most frequently associated with danger by flooding. When comparing scenes with and without wood, scenes with wood were clearly considered more positive as significantly more aesthetic, less dangerous and needing less improvement. The disciplinary groups showed variations in the absolute evaluation scores but the relative evaluation of scenes with wood versus scenes without wood was similar among all groups. The results indicate an acceptance for the reintroduction of wood in stream rehabilitation and restoration by young students who are potential future players in water management.     

Geodynamic evolution of the European Variscan fold belt: palaeomagnetic and geological constraints

The Variscan fold belt of Europe resulted from the collision of Africa, Baltica, Laurentia and the intervening microplates in early Paleozoic times. Over the past few years, many geological, palaeobiogeographic and palaeomagnetic studies have led to significant improvements in our understanding of this orogenic belt. Whereas it is now fairly well established that Avalonia drifted from the northern margin of Gondwana in Early Ordovician times and collided with Baltica in the late Ordovician/early Silurian, the nature of the Gondwana derived Armorican microplate is more enigmatic. Geological and new palaeomagnetic data suggest Armorica comprises an assemblage of terranes or microblocks. Palaeobiogeographic data indicate that these terranes had similar drift histories, and the Rheic Ocean separating Avalonia from the Armorican Terrane Assemblage closed in late Silurian/early Devonian times. An early to mid Devonian phase of extensional tectonics along this suture zone resulted in formation of the relatively narrow Rhenohercynian basin which closed progressively between the late Devonian and early Carboniferous. In this contribution, we review the constraints provided by palaeomagnetic data, compare these with geological and palaeobiogeographic evidence, and present a sequence of palaeogeographic reconstructions for these circum-Atlantic plates and microplates from Ordovician through to Devonian times.     

Self-organization of recent rhythmic iron-manganese precipitations in underground mines in the Harz mountains

A recent early diagenetic banded iron-manganese mud has been forming underground in a closed lead-zinc mine for approximately 40 years. The processes leading to the banded structure of the precipitate were studied during a period of 2 years. Therefore, 19 physical and chemical parameters were measured regularly in short intervals. The resulting time series were analysed with respect to the data sets of the monthly chemical analyses of the descendent mine water, the daily rainfall and the mineral content. The results reveal that the precipitated material undergoes internal self-organization due to interaction of redox, colloid-chemical, microbial, electrical and ripening processes, and not exclusively produced by seasonal fluctuations of material input. Thus, the primary banding of the material, caused by externally forced fluctuations of the redox conditions within the mine water, is reorganized after a short time. The finally observed bands are controlled by non-linear coupling of reaction and transport processes within the mud. A genetic model for the banded mineralization was developed and verified by numerical simulation.