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371.
We compare several statistical routines that may be used to calculate δ18Osw and SSS from paired coral Sr/Ca and δ18O measurements. Typically, the δ18Ocoral-SST relationship is estimated by linear regression of coral δ18O vs. SST. If this method is applied, evidence should be given that at a particular site SST and SSS do not co-vary. In the tropical oceans, SST and δ18Osw (SSS) often co-vary, and this will bias the estimate of the regression slope of δ18Ocoral-SST. Using a stochastic model, we show that covariance leads to a bias in the coefficients of the univariate regression equations. As the slope of the δ18Ocoral-SST relationship has known, we propose to insert this value for γ1 in the regression models. This requires that the constants of the regression equations are removed. To omit the constants, we propose to center the regression equations (i.e., to remove the mean values from the variables). The statistical error propagation is calculated to assess our ability to resolve past variations in δ18Osw (SSS). At Tahiti, we find that the combined analytical uncertainties of coral δ18O and Sr/Ca equal the amplitude of the seasonal cycle of δ18Osw (SSS). Therefore, we cannot resolve the seasonal cycle of SSS at Tahiti. At Timor, the error of reconstructed δ18Osw (SSS) is lower than the magnitude of seasonal variations of δ18Osw (SSS), and the seasonal cycle of δ18Osw (SSS) can be resolved.  相似文献   
372.
We have undertaken a study of the common green or orange-brown spots at the surface of rough diamond specimens, which are caused by alpha particles emanating from radioactive sources outside the diamond. Richly coloured haloes represent elevated levels of structural damage, indicated by strong broadening of the main Raman band of diamond, intense strain birefringence, and up-doming of spots due to their extensive volume expansion. Green radio-colouration was analogously generated through the irradiation of diamond with 8.8 MeV helium ions. The generation of readily visible radio-colouration was observed after irradiating diamond with ≥1015 He ions per cm2. The accumulation of such a high number of alpha particles requires irradiation of the diamond from a radioactive source over long periods of time, presumably hundreds of millions of years in many cases. In the samples irradiated with He ions, amorphisation was observed in volume areas where the defect density exceeded 5 × 10?3 Å?3 (or 0.03 dpa; displacements per target atom). In contrast, graphitisation as a direct result of the ion irradiation was not observed. The green colouration transformed to brown at moderate annealing temperatures (here 450 °C). The colour transformation is associated with only partial recovery of the radiation damage. The colour change is mainly due to the destruction of the GR1 centre, explained by trapping of vacancies at A defects to form the H3 centre. An activation energy of ~2.4 ± 0.2 eV was determined for the GR1 reduction. The H3 centre, in turn, causes intense yellowish-green photoluminescence under ultraviolet illumination. Radio-colouration and associated H3 photoluminescence are due to point defects created by the ions irradiated, whereas lattice ionisation is of minor importance. This is concluded from the depth distribution of the colouration and the photoluminescence intensity (which corresponds to the defect density but not the ionisation distribution pattern). The effect of the implanted He ions themselves on the colour and photoluminescence seems to be negligible, as radio-colouration and H3 emission were analogously produced through irradiation of diamond with C ions. The photoluminescence emission becomes observable at extremely low defect densities on the order of 10?6 Å?3 (or 0.000006 dpa) and is suppressed at moderate defect densities of ~5 × 10?4 Å?3 (or ~0.003 dpa). Intensely brown-coloured diamond hence does not show the H3 emission anymore. Anneals up to 1,600 °C has reduced considerably irradiation damage and radio-colouration, but the structural reconstitution of the diamond (and its de-colouration) was still incomplete.  相似文献   
373.
Urban form and function have been studied extensively in urban planning and geographical information science. However, gaining a greater understanding of how they merge to define the urban morphology remains a substantial scientific challenge. Toward this goal, this paper addresses the opportunities presented by the emergence of crowdsourced data to gain novel insights into form and function in urban spaces. We are focusing in particular on information harvested from social media and other open-source and volunteered datasets (e.g. trajectory and OpenStreetMap data). These data provide a first-hand account of form and function from the people who define urban space through their activities. This novel bottom-up approach to study these concepts complements traditional urban studies to provide a new lens for studying urban activity. By synthesizing recent advancements in the analysis of open-source data, we provide a new typology for characterizing the role of crowdsourcing in the study of urban morphology. We illustrate this new perspective by showing how social media, trajectory, and traffic data can be analyzed to capture the evolving nature of a city’s form and function. While these crowd contributions may be explicit or implicit in nature, they are giving rise to an emerging research agenda for monitoring, analyzing, and modeling form and function for urban design and analysis.  相似文献   
374.
We identify an important set of key areas where an advanced observational Ultraviolet capability would have major impact on studies of cosmology and Galaxy formation in the young Universe. Most of these are associated with the Universe at z < 3–4. We address the issues associated with Dark matter evidence in the local Universe and the impact of the Warm-Hot Intergalactic Medium WHIM on the local Baryon count. The motivations to make ultraviolet (UV) studies of supernovae (SNe) are reviewed and discussed in the light of the results obtained so far by means of IUE and HST observations. It appears that UV studies of SNe can, and do lead to fundamental results not only for our understanding of the SN phenomenon, such as the kinematics and the metallicity of the ejecta, but also for exciting new findings in Cosmology, such as the tantalizing evidence for “dark energy” that seems to pervade the Universe and to dominate its energetics. The need for additional and more detailed UV observations is also considered and discussed.Finally we show the enormous importance of the UV for abundance evolution in the Intergalactic Medium (IGM), and the importance of the He II studies to identify re-ionization epochs, which can only be done in the UV.  相似文献   
375.
A simulation study of the energy released in air due to the development of an extensive air shower has been carried out using the CORSIKA code. The contributions to the energy release from different particle species and energies as well as the typical particle densities are investigated. Special care is taken of particles falling below the energy threshold of the simulation which contribute about 10% to the total energy deposition. The dominant contribution to the total deposition stems from electrons and positrons from sub-MeV up to a few hundred MeV, with typical transverse distances between particles exceeding 1 mm for 10 EeV showers.  相似文献   
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377.
Abstract Petrographical and chemical analysis of melt particles and alteration minerals of the about 100 m‐thick suevitic sequence at the Chicxulub Yax‐1 drill core was performed. The aim of this study is to determine the composition of the impact melt, the variation between different types of melt particles, and the effects of post‐impact hydrothermal alteration. We demonstrate that the compositional variation between melt particles of the suevitic rocks is the result of both incomplete homogenization of the target lithologies during impact and subsequent post‐impact hydrothermal alteration. Most melt particles are andesitic in composition. Clinopyroxene‐rich melt particles possess lower SiO2 and higher CaO contents. These are interpreted by mixing of melts from the silicate basement with overlying carbonate rocks. Multi‐stage post‐impact hydrothermal alteration involved significant mass transfer of most major elements and caused further compositional heterogeneity between melt particles. Following backwash of seawater into the crater, palagonitization of glassy melt particles likely caused depletion of SiO2, Al2O3, CaO, Na2O, and enrichment of K2O and FeOtot during an early alteration stage. Since glass is very susceptible to fluid‐rock interaction, the state of primary crystallization of the melt particles had a significant influence on the intensity of the post‐impact hydrothermal mass transfer and was more pronounced in glassy melt particles than in well‐crystallized particles. In contrast to other occurrences of Chicxulub impactites, the Yax‐1 suevitic rocks show strong potassium metasomatism with hydrothermal K‐feldspar formation and whole rock K20 enrichment, especially in the lower unit of the suevitic sequence. A late stage of hydrothermal alteration is characterized by precipitation of silica, analcime, and Na‐bearing Mg‐rich smectite, among other minerals. This indicates a general evolution from a silica‐undersaturated fluid at relatively high potassium activities at an early stage toward a silica‐oversaturated fluid at relatively high sodium activities at later stages in the course of fluid rock interaction.  相似文献   
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The variation of the equilibrium line altitude can be used as an indicator for glacier mass balance variability. Snow lines at the end of the ablation period are suitable proxies for the annual equilibrium line altitude on glaciers. We investigate snow lines at Purogangri ice cap on the central Plateau in order to study the interannual variability of glacier mass balance. Datasets of the daily Moderate Resolution Imaging Spectroradiometer snow product MOD10A1 were used to infer transient snow line variability during 2001–2012 and to derive regional‐scale, annual equilibrium line altitude. The Moderate Resolution Imaging Spectroradiometer snow albedo embedded within the snow product was compared with high‐resolution Landsat imagery. An albedo threshold was established to differentiate between ice and snow and the 13th percentile of the altitudes of snow‐covered pixels was chosen to represent the snow line altitude. The second maximum of the snow line altitudes in the ablation period was taken as a proxy for the annual equilibrium line altitude. A linear correlation analysis was carried out (1) between interannual variability of the equilibrium line altitude at Purogangri ice cap and various climate elements derived from the High Asia Reanalysis, and (2) between interannual variability of the equilibrium line altitude and the circulation indices North Atlantic Oscillation and Indian Summer Monsoon. Results suggest that air temperature and meridional wind speed above ground in July, as well as the lower tropospheric zonal wind in June and August play a crucial role in the development of the annual equilibrium line altitude.  相似文献   
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