Ceres’ spectral link to carbonaceous chondrites—Analysis of the dark background materials

Ceres’ surface has commonly been linked with carbonaceous chondrites (CCs) by ground‐based telescopic observations, because of its low albedo, flat to red‐sloped spectra in the visible and near‐infrared (VIS/NIR) wavelength region, and the absence of distinct absorption bands, though no currently known meteorites provide complete spectral matches to Ceres. Spatially resolved data of the Dawn Framing Camera (FC) reveal a generally dark surface covered with bright spots exhibiting reflectance values several times higher than Ceres’ background. In this work, we investigated FC data from High Altitude Mapping Orbit (HAMO) and Ceres eXtended Juling (CXJ) orbit (~140 m/pixel) for global spectral variations. We found that the cerean surface mainly differs by spectral slope over the whole FC wavelength region (0.4–1.0 μm). Areas exhibiting slopes ?1 constitute only ~3% of the cerean surface and mainly occur in the bright material in and around young craters, whereas slopes ≥?10% μm^?1 occur on more than 90% of the cerean surface; the latter being denoted as Ceres’ background material in this work. FC and Visible and Infrared Spectrometer (VIR) spectra of this background material were compared to the suite of CCs spectrally investigated so far regarding their VIS/NIR region and 2.7 μm absorption, as well as their reflectance at 0.653 μm. This resulted in a good match to heated CI Ivuna (heated to 200–300 °C) and a better match for CM1 meteorites, especially Moapa Valley. This possibly indicates that the alteration of CM2 to CM1 took place on Ceres.     

Gravity studies of Aphrodite Terra on Venus

Aphrodite Terra is the largest highland area on Venus of the size of Africa. It is traversed by the Aphrodite-Beta belt of troughs with a length of 21 000 km. There are two other large belts of troughs on Venus: Themis-Atla, 14 000 km long, and Beta-Phoebe, 8000 km long. In this paper, four gravity profiles across Aphrodite Terra are studied and compared with the morphology.Western Aphrodite and Niobe Planitia to the north seem to be in isostatic equilibrium under the assumption of Airy compensation with a mean crustal thickness of T = 50 km. The graben area in the middle part of Aphrodite Terra shows negative isostatic gravity anomalies indicating deficit masses. The adjacent Atla Regio to the east is regionally Airy compensated with T = 50 km, and the mountains Nokomis, Maat and Ozza Montes are locally undercompensated, i.e. they are associated with surplus masses in the depth. Ulfrun Regio, a hilly terrain just east of Atla Regio is Airy compensated with T = 30 km. These results give a mean crustal thickness around 50 km for Aphrodite Terra. The isostatic disturbed zones in the middle of Aphrodite (grabens) and Atla Regio as well as the undercompensated Beta Regio have been associated with recent volcanism from the observation of the concentrations of electrical discharges in these areas. Atla and Beta Regiones are both located at intersections of the systems of troughs described above.Contribution No. 308, Institut für Geophysik der Universität Kiel, F.R.G.     

Earthquake chemical precursors in groundwater: a review

We review changes in groundwater chemistry as precursory signs for earthquakes. In particular, we discuss pH, total dissolved solids (TDS), electrical conductivity, and dissolved gases in relation to their significance for earthquake prediction or forecasting. These parameters are widely believed to vary in response to seismic and pre-seismic activity. However, the same parameters also vary in response to non-seismic processes. The inability to reliably distinguish between changes caused by seismic or pre-seismic activities from changes caused by non-seismic activities has impeded progress in earthquake science. Short-term earthquake prediction is unlikely to be achieved, however, by pH, TDS, electrical conductivity, and dissolved gas measurements alone. On the other hand, the production of free hydroxyl radicals (?OH), subsequent reactions such as formation of H₂O₂ and oxidation of As(III) to As(V) in groundwater, have distinctive precursory characteristics. This study deviates from the prevailing mechanical mantra. It addresses earthquake-related non-seismic mechanisms, but focused on the stress-induced electrification of rocks, the generation of positive hole charge carriers and their long-distance propagation through the rock column, plus on electrochemical processes at the rock-water interface.     

Micromechanical analysis of non-coaxiality between stress and strain increment in granular materials

Acta Geotechnica - It is known that non-coaxiality between the directions of the principal stresses and the principal plastic strain increments in granular material is physically resulted from the...     

Methane in the southern North Sea: Sources, spatial distribution and budgets

Measurements of methane (CH₄) so far have always shown supersaturation in the entire North Sea relative to the atmospheric partial pressure and the distribution of surface CH₄ reveals a distinct increase towards the shore. Since North Sea sediments presumably are an insignificant source for CH₄ the coastal contribution via rivers and tidal flats gains in importance.In this work, CH₄ data from the River Weser, the back barrier tidal flats of Spiekeroog Island (NW Germany), and the German Bight are presented. Results from the River Weser are compared to other rivers draining into the German Bight. Measurements in the tidal flat area of Spiekeroog Island highlight this ecosystem as an additional contributor to the overall CH₄ budget of the southern North Sea. A tidally driven CH₄ pattern is observed for the water column with maximum values during low tide. Tidal flat sediments turn out to be the dominating source because pore waters discharged during low tide are highly enriched in CH₄. In contrast, the freshwater contribution to the tidal flats by small coastal tributaries has almost no impact on water column CH₄ concentrations. The CH₄ level seems to be disturbed irregularly by wind forcing due to elevated degassing and prevention of advective flow when tidal flats remain covered by water.Based on our data, two model calculations were used to estimate the impact of tidal flats on the CH₄ budget in the German Bight. Our results demonstrate that the back barrier tidal flats of the east Frisian Wadden Sea contribute CH₄ in an order of magnitude between the Wash estuary and River Elbe and thus have to be considered in budget calculations.     

Comment on the Guzmán-Bianchi type-VII h solutions

It is shown that the recently presented Brans-Dicke-Bianchi type-VII _h perfect fluid solutions by Guzmán (1989) are nothing but the solutions given already by us in our previous paper (Lorenz-Petzold, 1984).     

Field experiments yield new insights into gas exchange and excess air formation in natural porous media

Gas exchange between seepage water and soil air within the unsaturated and quasi-saturated zones is fundamentally different from gas exchange between water and gas across a free boundary layer, e.g., in lakes or rivers. In addition to the atmospheric equilibrium fraction, most groundwater samples contain an excess of dissolved atmospheric gases which is called “excess air”. Excess air in groundwater is not only of crucial importance for the interpretation of gaseous environmental tracer data, but also for other aspects of groundwater hydrology, e.g., for oxygen availability in bio-remediation and in connection with changes in transport dynamics caused by the presence of entrapped air bubbles. Whereas atmospheric solubility equilibrium is controlled mainly by local soil temperature, the excess air component is characterized by the (hydrostatic) pressure acting on entrapped air bubbles within the quasi-saturated zone. Here we present the results of preliminary field experiments in which we investigated gas exchange and excess air formation in natural porous media. The experimental data suggest that the formation of excess air depends significantly on soil properties and on infiltration mechanisms. Excess air was produced by the partial dissolution of entrapped air bubbles during a sprinkling experiment in fine-grained sediments, whereas similar experiments conducted in coarse sand and gravel did not lead to the formation of excess air in the infiltrating water. Furthermore, the experiments revealed that the noble gas temperatures determined from noble gases dissolved in seepage water at different depths are identical to the corresponding in situ soil temperatures. This finding is important for all applications of noble gases as a paleotemperature indicator in groundwater since these applications are always based on the assumption that the noble gas temperature is identical to the (past) soil temperature.     

Potential future changes in water limitations of the terrestrial biosphere

This study explores the effects of atmospheric CO₂ enrichment and climate change on soil moisture (W _r ) and biome-level water limitation (L _TA), using a dynamic global vegetation and water balance model forced by five different scenarios of change in temperature, precipitation, radiation, and atmospheric CO₂ concentration, all based on the same IS92a emission scenario. L _TA is defined as an index that quantifies the degree to which transpiration and photosynthesis are co-limited by soil water shortage (high values indicate low water limitation). Soil moisture decreases in many regions by 2071–2100 compared to 1961–1990, though the regional pattern of change differs substantially among the scenarios due primarily to differences in GCM-specific precipitation changes. In terms of L _TA, ecosystems in northern temperate latitudes are at greatest risk of increasing water limitation, while in most other latitudes L _TA tends to increase (but again varies the regional pattern of change among the scenarios). The frequently opposite direction of change in W _r and L _TA suggests that decreases in W _r are not necessarily felt by actual vegetation, which is attributable mainly to the physiological vegetation response to elevated CO₂. Without this beneficial effect, the sign of change in L _TA would be reversed from predominantly positive to predominantly negative.