Mechanism of the water and carbon dioxide solubility in oxides and silicates and the role of O−

The dissolution of water does not stop at the OH^– stage but may proceed further towards H₂ plus O^– formation. The discovery of atomic carbon dissolved in minerals suggests that, if CO₂ enters oxides and silicates at high pressures and temperatures, not only [CO₃]^2– ions but also [CO ₄ ^. ]^4– complexes are formed via a charge transfer which produces O^– and essentially zero-valent, atomic carbon. Under P —T-conditions of the mantle, where the solubility for water and CO₂ is high, the silicate phases formed may therefore consist to a large volume fraction of O^– ions which are much smaller than O^2–ions and strongly cova-lently bonding. The implications for the crystal chemistry of high pressure phases, for the petrology of mantle rocks are outlined.     

Carbon in solid solution in forsterite—a key to the untractable nature of reduced carbon in terrestrial and cosmogenic rocks

Carbon is an incompatible element in oxide and silicate lattices. Until now it has been believed to exist only in the form of CO^2?₃ ions, molecularily dissolved CO₂ or graphitic inclusions. Recently it has been shown that carbon can dissolve in refractory oxides, like MgO and CaO, in the form of carbon atoms.The experimental results obtained with carbonaceous MgO are reviewed and new results are presented which demonstrate that synthetic forsterite and natural olivines can also take up atomic carbon in solid solution. The incorporation of the carbon atoms is treated thermodynamically. Near the melting point they probably occupy cation vacancies, but with decreasing temperature they are progressively transferred on interstitial sites. On these sites they are very mobile and tend to segregate into the elastically relaxed subsurface zone, but exsolution to graphite is prevented by the strain fields surrounding each carbon atom.Upon heating, however, the atomic carbon may react with lattice oxygen to give CO₂ and with co-dissolved hydrogen to give a wide variety of hydrocarbons. The underlying reaction mechanisms, involving the formation and decay of O^? ions, are discussed in view of the so-called ‘carbonatic carbon’ and ‘reduced carbon’ in magmatic minerals and meteorites, in view of the diamond genesis and also in view of the reversible CO₂ solubility in silicate magmas at high pressures and temperatures.     

Über die Feldspäte im Germanischen Buntsandstein,ihre Korngrößenabhängigkeit Verbreitung und paläogeographische Bedeutung

The feldspars of the Buntsandstein, their postdepositional alterations, dependance of grain size, their regional distribution and palaeogeographic significance were investigated. The work was based on X-Ray, optical and chemical investigations of about 1100 samples from the Buntsandstein areas in Western Germany and the Vosges. By statistical means feldspar portions independent from grain size were calculated and four different sedimentstreams were identified. The relation of these streams to stratigraphic units is discussed. One stream originated from the south-western margins of the basin, it is very poor in plagioklase and it reached most likely northern Hessen during Lower and Upper Buntsandstein time. During the Middle Buntsandstein it reached the centre of the Weser Basin in southern Niedersachsen. It was ?oppressed“ at its southeastern and eastern flankes by sediment streams originating from the Bohemian Massif. They are characterised by a different granulation, by different feldspar content, and by increasing plagioklase content. In northern Hessen and southern Niedersachsen they reached the western flank of the Weser Basin. During the Middle Buntsandstein this basin had partly been an interference area of S-N and SE-NW sediment flows.     

Reliability of K-Ar Dating of Clays and Silicifications Associated with vein Mineralizations in Western Europe

K-Ar ages were determined on fine fractions and one massive silicification associated with vein mineralizations in uranium, barium, fluorine and related base metals in Western Europe. The reliability of the potassic materials analysed, once the mineralogical and geochemical relationships to the low-temperature mineralization have been established, is demonstrated. The isotopic ages are concentrated between nearly 190 and 170 MA. This epoch corresponds to that of the rifting of the future Atlantic and Tethys oceans. This type of low-temperature mineralization thus seems to be better explained by extensional phenomena.     

Stratigraphy of the tectonically imbricated lithological succession of the Neves Corvo mine area,Iberian Pyrite Belt,Portugal

Biostratigraphic research, based on palynomorphs and ammonoids, of the tectonically imbricated lithological succession of the Neves Corvo mine, in the Portuguese part of the Iberian Pyrite Belt, has yielded ages for all formerly recognised lithostratigraphic units. These can be assembled in three main lithological sequences: (1) detrital sandy/shale substrate (Phyllite-Quartzite Formation) of late Famennian age; (2) Volcano-Sedimentary Complex, divided into a lower and an upper suite, in which one basic, three dolerite sills and four felsic volcanic units and a mineralised package of massive sulphides are identified with ages which range from the late Famennian to the late Visean; (3) flysch succession (Mértola Formation) composed of shale and greywacke dated as late Visean to early Serpukhovian. Precise biostratigraphic dating of the sedimentrary host rocks of massive sulphide mineralisation constrains the age of the latter to the late Strunian (354.8–354.0 Ma). Three stratigraphic hiatuses, corresponding to early/middle Strunian, Tournaisian and early Visean respectively and a south-westward progressive unconformity were also recognised. Sequences 1 and 2 are related to extensional episodes while sequence 3 marks the beginning of compressive tectonic inversion which gave rise to south-westward flysch progradation in close relation to a foreland basin development. Our results lead to the reinterpretation of the tectonic structure of the Neves Corvo mine, with implications for the interpretation of the regional basin dynamics and metal exploration.Editorial handling: F. Tornos     

Trace element incorporation into quartz: A combined study by ICP-MS, electron spin resonance, cathodoluminescence, capillary ion analysis, and gas chromatography

Pegmatite quartz from different occurrences in Norway and Namibia was investigated by a combination of ICP-MS, Electron Spin Resonance (ESR), Capillary Ion Analysis (CIA) and Gas Chromatography (GC) to quantify trace elements in very low concentrations and to determine their position in the quartz structure.The studied quartz samples show similar geochemical characteristics with low contents of most trace elements. Remarkable are the elevated concentrations of Al (36-636 ppm), Ti (1.6-25.2 ppm), Ge (1.0-7.1 ppm), Na (5.2 to >50 ppm), K (1.6 to >100 ppm) and Li (2.1-165.6 ppm). These elements are preferentially incorporated into the quartz lattice on substitutional (Al, Ti, Ge) and interstitial (Li, Na, K) positions. Li⁺ was found to be the main charge compensating ion for Al, Ge and Ti, whereas some ppm of Na and K may also be hosted by fluid inclusions. Ti may be incorporated as substitutional ion for Si or bound on mineral microinclusions (rutile). The results of the ESR measurements show that there may be a redistribution of alkali ions during irradiation. The diamagnetic [AlO₄/M⁺]⁰ center transforms into the paramagnetic [AlO₄]⁰ center, whilst the compensating ions diffuse away and may be captured by the diamagnetic precursor centers of [GeO₄]⁰ and [TiO₄]⁰ to form paramagnetic centers ([TiO₄/Li⁺]⁰, [GeO₄/Li⁺]⁰).In general, fluid inclusions in pegmatite quartz can be classified as H₂O-CO₂-NaCl type inclusions with water as the predominant volatile. Among the main elements hosted by fluid inclusions in quartz are Na, K, NH₄, Ca, Mg and the anionic complexes Cl⁻, NO₃⁻, HCO₃⁻ and SO₄²⁻. Gas analysis of trapped fluids shows volatile components in the following order of abundance: H₂O > CO₂ > N₂(+) ≥ CH₄ > COS > C₂ and C₃ hydrocarbons. Additionally, traces of Co, Ni, Zn, Pb, and Cu were detected by CIA in fluid inclusions of some samples. There are indications that the REE and Rb are also bound in fluid inclusions, however, the concentrations of these elements are too low to be measured by CIA. Assuming that the REE preferentially occur in fluid inclusions, the typical chondrite normalized REE distribution patterns with tetrad effects and a distinct negative Eu anomaly would reflect the composition of the mineralizing fluid.For a number of elements, especially those with extremely low concentrations, the “type” of incorporation in quartz could not directly be determined. We conclude that these ions either are too large to substitute for the small Si⁴⁺ ion or they are not soluble in the mineralizing fluids to be hosted by fluid inclusions. Some of these elements, which are concentrated in the specific mineralization of certain pegmatites, are not present in elevated concentrations in the paragenetic pegmatite quartz itself. This was observed, for instance, for Be, Cs and Rb in the Li (Be-Cs-Rb) pegmatites of Rubicon or for Nb and Ta for Nb-Ta bearing pegmatites from Norway. It may be concluded that the concentrations of these trace elements in quartz do not reflect the mineralization and that these elements thus, cannot be used as petrogenetic indicator.     

Environmental Copper and Manganese in the Pathophysiology of Neurologic Diseases (Alzheimer's Disease and Manganism)

Alzheimer's disease (AD) is the most common form of dementia. Populations migrating from developing to industrialized countries seem to elicit a higher incidence and prevalence rate of AD, suggesting lifestyle and environmental factors to have a role in the pathophysiology of AD. One of its major neuropathological hallmarks is the deposition of Aβ peptides as amyloid plaques in the brain of AD patients. Aβ is proteolytically cleaved out of the larger amyloid precursor protein (APP). Cu and Mn are often found in drinking water and may have a neurotoxic potential. APP is involved in Cu homeostasis in mouse and man. In vitro observations and in vivo data obtained from APP mouse models provide strong evidence that APP overexpression enables intracellular Cu to be transported out of the cell. Disturbed metal‐ion homeostasis with elevated serum Cu levels occurs in Alzheimer and Down's patients and lowered levels in post‐mortem AD brain. We observed that bioavailable Cu has specific beneficial effects in an Alzheimer's disease mouse model. This should be regarded as a proof‐of‐concept for a prophylactic approach to overcome the observed CNS Cu deficiency in the brain of Alzheimer's disease patients. Manganism is a disorder with symptoms similar to that of Parkinson's disease. The precise mechanism how manganese can damage the nervous system is unknown. There is some evidence that iron and manganese may utilize similar transport systems. Epidemi ologic data strongly suggests that manganese enters the body primarily via inhalation and through the ingestion of manganese in drinking water.     

Reef development on a deepening platform: two Early Cretaceous coralgal patch reefs (Catí, Llàcova Formation, eastern Spain) compared

Two coralgal patch reefs of the Hauterivian Llàcova Formation (Maestrat Basin, eastern Spain), exposed at two consecutive stratigraphic levels within a single section, have been studied to document taxonomic implications of a changing environment. These two reefal palaeocommunities differ substantially in coral taxonomic composition, microbialite formation pattern and in abundance and composition of encrusters and bioeroders. Of a total of 14 coral species, just one (Stylina parvistella) occurs in both reefs, yet is abundant in the (lower) reef A and rare, occurring near the reef base, in the reef B assemblage. Reef A is dominated by a phototrophic fauna and coral species with small corallites and imperforate septa (a stylinid-thamnasteriid-heterocoeniid-actinastreid association), along with an encruster association dominated by Bacinella and Lithocodium. Reef B is characterised by a balanced phototrophic-heterotrophic fauna that gradually passes into a heterotrophic-dominated assemblage. During this latest growth stage, microsolenid corals dominated the assemblage. The encruster fauna is characterised by sponges, polychaetes and bryozoans. Moderate deepening during a transgressive systems tract (TST) depositional sequence and elevated nutrient supply are interpreted to represent the driving environmental parameters that caused faunal compositions to differ between these two reefal palaeocommunities. Nine coral taxa, previously known only from younger (Barremian–Cenomanian) strata, have been identified, namely Dimorphocoenia? rudis, Eocomoseris raueni, Eocomoseris sp., Holocoenia jaccardi, Latusastrea irregularis, Mesomorpha sp., Microsolena kugleri, Polyphylloseris mammillata and Polyphylloseris sp. This observation emphasises the importance of the Hauterivian Stage as a period of evolutionary transition in Late Jurassic–Cretaceous coral faunas.     

CO2 Mitigation by Agriculture: An Overview

Agriculture currently contributes significantly to the increase of CO2 in the atmosphere, primarily through the conversion of native ecosystems to agricultural uses in the tropics. Yet there are major opportunities for mitigation of CO2 and other greenhouse gas emissions through changes in the use and management of agricultural lands. Agricultural mitigation options can be broadly divided into two categories: (I) strategies to maintain and increase stocks of organic C in soils (and biomass), and (ii) reductions in fossil C consumption, including reduced emissions by the agricultural sector itself and through agricultural production of biofuels to substitute for fossil fuels.Reducing the conversion of new land to agriculture in the tropics could substantially reduce CO2 emissions, but this option faces several difficult issues including population increase, land tenure and other socio-political factors in developing countries. The most significant opportunities for reducing tropical land conversions are in the humid tropics and in tropical wetlands. An important linkage is to improve the productivity and sustainability of existing agricultural lands in these regions.Globally, we estimate potential agricultural CO2 mitigation through soil C sequestration to be 0.4-0.9 Pg C y-1, through better management of existing agricultural soils, restoration of degraded lands, permanent "set-asides" of surplus agricultural lands in temperate developed countries and restoration of 10-20% of former wetlands now being used for agriculture. However, soils have a finite capacity to store additional C and therefore any increases in C stocks following changes in management would be largely realized within 50-100 years.Mitigation potential through reducing direct agricultural emissions is modest, 0.01-0.05 Pg C y-1. However, the potential to offset fossil C consumption through the use of biofuels produced by agriculture is substantial, 0.5-1.6 Pg C y-1, mainly through the production of dedicated biofuel crops with a smaller contribution (0.2-0.3 Pg C y-1) from crop residues.Many agricultural mitigation options represent "win-win" situations, in that there are important side benefits, in addition to CO2 mitigation, that could be achieved, e.g. improved soil fertility with higher soil organic matter, protection of lands poorly suited for permanent agriculture, cost saving for fossil fuel inputs and diversification of agricultural production (e.g. biofuels). However, the needs for global food production and farmer/societal acceptability suggest that mitigation technologies should conform to: (I) the enhancement of agricultural production levels in parts of the world where food production and population demand are in delicate balance and (ii) the accrual of additional benefits to the farmer (e.g., reduced labor, reduced or more efficient use of inputs) and society at large.