Assessment of the acid drainage neutralization capacity and the toxic metals lixiviation of tailing from Guanajuato mining district,Mexico

In Mexico, many environmental problems are generated by large mining activities taking place in several mining districts. These mining activities produce great quantities of residues; large majorities of these have high sulfur content, which could generate acid drainage due to their interaction with the oxygen in the environment. The study area was located in the Mining District of Guanajuato, Mexico with abandoned tailings generated mainly by the gold and silver production. Two areas, called as Monte de San Nicolás (SN) and Peregrina (P) were selected for this study. The results study shows that there was no risk of production of acid drainage, since these tailings contained high amount of carbonates, which neutralized the generation of acidity and consequently decreased the possibility of leaching of some elements. However, not all elements leach in acid pH, as arsenic bound to oxyhydroxides, which is in a basic environment and its increased release by increasing the pH.     

Late Miocene evaporite geochemistry of Lorca and Fortuna basins (Eastern Betics,SE Spain): Evidence of restriction and continentalization

The Lorca and Fortuna basins are two intramontane Neogene basins located in the eastern Betic Cordillera (SE Spain). During the Late Tortonian—Early Messinian, marine and continental evaporites precipitated in these basins as a consequence of increased marine restriction and isolation. Here we show a stratigraphic correlation between the evaporite records of these basins based on geochemical indicators. We use SO₄ isotope compositions and Sr isotopic ratios in gypsum, and halite Br contents to characterize these units and to identify the marine or continental source of the waters feeding the evaporite basins. In addition, we review the available chronological information used to date these evaporites in Lorca (La Serrata Fm), including a thick saline deposit, that we correlate with the First Evaporitic Group in Fortuna (Los Baños Fm). This correlation is also supported by micropalaeontological data, giving a Late Tortonian age for this sequence. The Second Evaporitic Group, (Chicamo Fm), and the Third Evaporitic Group (Rambla Salada Fm) developed only in Fortuna during the Messinian. According to the palaeogeographical scheme presented here, the evaporites of the Lorca and Fortuna basins were formed during the Late Tortonian—Early Messinian, close to the Betic Seaway closure. Sulphate isotope compositions and Sr isotopic ratios of the Ribera Gypsum Mb, at the base of the Rambla Salada Fm (Fortuna basin), match those of the Late Messinian selenite gypsum beds in San Miguel de Salinas, in the near Bajo Segura basin (40 km to the East), and other Messinian Salinity Crisis gypsum deposits in the Mediterranean. According to these geochemical indicators and the uncertainty of the chronology of this unit, the assignment of the Rambla Salada Fm to the MSC cannot be ruled out.     

The ionosphere: effects,GPS modeling and the benefits for space geodetic techniques

The main goal of this paper is to provide a summary of our current knowledge of the ionosphere as it relates to space geodetic techniques, especially the most informative technology, global navigation satellite systems (GNSS), specifically the fully deployed and operational global positioning system (GPS). As such, the main relevant modeling points are discussed, and the corresponding results of ionospheric monitoring are related, which were mostly computed using GPS data and based on the direct experience of the authors. We address various phenomena such as horizontal and vertical ionospheric morphology in quiet conditions, traveling ionospheric disturbances, solar flares, ionospheric storms and scintillation. Finally, we also tackle the question of how improved knowledge of ionospheric conditions, especially in terms of an accurate understanding of the distribution of free electrons, can improve space geodetic techniques at different levels, such as higher-order ionospheric effects, precise GNSS navigation, single-antenna GNSS orientation and real-time GNSS meteorology.     

Documenting hurricane impacts on coral reefs using two-dimensional video-mosaic technology

Four hurricanes impacted the reefs of Florida in 2005. In this study, we evaluate the combined impacts of hurricanes Dennis, Katrina, Rita, and Wilma on a population of Acropora palmata using a newly developed video‐mosaic methodology that provides a high‐resolution, spatially accurate landscape view of the reef benthos. Storm damage to A. palmata was surprisingly limited; only 2 out of 19 colonies were removed from the study plot at Molasses Reef. The net tissue losses for those colonies that remained were only 10% and mean diameter of colonies decreased slightly from 88.4 to 79.6 cm. In contrast, the damage to the reef framework was more severe, and a large section (6 m in diameter) was dislodged, overturned, and transported to the bottom of the reef spur. The data presented here show that two‐dimensional video‐mosaic technology is well‐suited to assess the impacts of physical disturbance on coral reefs and can be used to complement existing survey methodologies.     

Extreme temperature scenarios in Mexicali,Mexico under climate change conditions

Extreme weather events can have severe consequences for the population and the environment. Therefore, in this study a temporal trend of annual temperatures was built with a time series from 1950 to 2010 for Mexicali, Mexico, and estimates of 5- to 100-year return periods are provided by modeling of summer maximum and winter minimum temperatures. A non-parametric Kendall’s tau test and the Sen’s slope estimator were used to compute trends. The generalized extreme value (GEV) distribution was applied to the approximation of block maxima and the generalized Pareto distribution (GPD) to values over a predetermined threshold. Due to the non-stationary characteristic of the series of temperature values, the temporal trend was included as a covariable in the location parameter and substantial improvements were observed, particularly with the extreme minimum temperature, compared to that obtained with the GEV with no covariable and with the GPD. A positive and significant statistically trend in both summer maximum temperature and winter minimum temperature was found. By the end of 21st century the extreme maximum temperature could be 2 to 3 °C higher than current, and the winter could be less severe, as the probabilistic model suggests increases of 7 to 9 °C in the extreme minimum temperature with respect to the base period. The foreseeable consequences on Mexicali city are discussed.     

Total mercury in terrestrial systems (air-soil-plant-water) at the mining region of San Joaquín,Queretaro, Mexico

Deficient management of cinnabar mining left the San Joaquín region with high concentrations of mercury in its soils (2.4 – 4164 mg kg^-1). Numerous cinnabar mines have contributed to the dispersion of mercury into agricultural (0.5 –314 mg kg^-1) and forest (0.2 – 69 mg kg^-1) soils. Sediments are a natural means of transportation for mercury, causing its spreading, especially in areas near mine entrances (0.6 – 687 mg kg^-1). The nearness of maize crops to mines favors mercury accumulation in the different plant structures, such as roots, stems, leaves, and grain (0.04 – 8.2 mg kg^-1); these being related to mercury volatilization and accumulation in soils. Mercury vapor present in the settlements could indicate a constant volatilization from lands and soils (22 – 153 ng m^-3). The mercury levels found in the soils, in maize grain, and in the air resulted greater than the standards reported by the Official Mexican Norm (NOM) and the World Health Organization (WHO). Mercury in rainwater is due mainly to the presence of suspended atmospheric particles, later deposited on the surface (1.5 – 339 μg |^-1). Mercury dissolution was found in the drinking water (10 – 170 ng |^-1), with concentrations below those established by the NOM and the WHO. The contamination existing in the San Joaquín region does not reach the levels of the world’s greatest mercury producers: Almaden (Spain) and Idrija (Slovenia). It is, however, like that found in other important second degree world producers such as Guizhou (China). The population of San Joaquín, as well as its surrounding environment, are constantly exposed to mercury contamination, thus making a long term monitoring necessary to determine its effects, especially to people.     

Mixing, sediment accumulation and focusing using 210Pb and 137Cs

The Portil lagoon is a natural freshwater reservoir located at the southwest of Spain, near the coast. In its surroundings an important tourist complex has been developed since the earlier 1970s. This has resulted in increased loads of nutrients, specially during summer months. In order to evaluate the impact from humans on the lagoon caused by anthropogenic activities, we have determined vertical profiles of excess ²¹⁰Pb and ¹³⁷Cs in a sediment core taken from its bottom. Vertical profile of excess ²¹⁰Pb seems to indicate that the sediment core was affected by large-scale mixing processes. Nevertheless this possibility was ruled out based on the shape of the ¹³⁷Cs vertical distribution after modelling the ¹³⁷Cs profile considering large-scale mixing. The chronology developed from ²¹⁰Pb and ¹³⁷Cs has allowed us to calculate the temporal evolution of the mass sedimentation rate during the last century. This mass sedimentation rate increased in 1973: from 0.08(2) g cm^-2 a^-1 in the period 1900-1973 to 0.17(5) g cm^-2 a^-1 in the period 1973-1995. This increase could be related to land-movements in the drainage area and to permitted sewage inputs into the lagoon, both with its origin in the growing/running of the surrounding tourist complex.     

Sources and behavior of arsenic and trace elements in groundwater and surface water in the Poopó Lake Basin,Bolivian Altiplano

Water management in semiarid and arid catchments such as the Poopó Lake Basin requires improved understanding of the complex behavior of the various contaminants, which affect the drinking water quality and considered as crucial for sustainable development of the region. Mechanisms of arsenic (As) release in the surface and groundwater were studied. Hydrochemical data for surface water (4 samples) and groundwater (28 samples) were collected in a small watershed in the Poopó catchment at the highland of the Bolivian Andes (Altiplano). All of them show high electrical conductivity values and moderately oxidizing conditions. The surface water contains high concentration of sulfate and the trace elements As, Zn and Pb in the zone affected by acid mine drainage. There is a large variability of the concentration of As and of the trace elements in the groundwater in the five different regions within the Poopó catchment. The metal concentrations sensitive to changes of redox state and results of speciation modeling suggest that As (V) is a predominant aqueous species, which conforms to the prevailing oxidizing conditions in the shallow groundwater environment. Two generalized trends for As distribution were identified in groundwater: (a) high concentrations are found in the arid zone (100–250 μg/L) in the southern (region III) and in the northwestern (region V) regions, and (b) low concentrations (<50 μg/L) are found in the remaining part of the basin (region I, II and IV). However, the spatial distribution within these regions needs to be investigated further. A conclusion from the present study is that there are multiple sources of As as well as other trace elements (such as Cd, Mn and Zn) in the Poopó Lake Basin. Among the sources and the processes which led to the mobility of As and other trace metals in the region are: (a) weathering of sulfide minerals, (b) oxidation of pyrite and/or arsenopyrite in mineralized areas and (c) desorption from hydrous ferric oxide (HFO) surfaces. In non-mining areas, volcanic ash is suggested to be a significant source of As.     

Morphological redshift estimates for galaxy clusters in a Sunyaev–Zel'dovich effect survey

We develop a new method to estimate the redshift of galaxy clusters through resolved images of the Sunyaev–Zel'dovich effect (SZE). Our method is based on morphological observables which can be measured by actual and future SZE experiments. We test the method with a set of high-resolution hydrodynamical simulations of galaxy clusters at different redshifts. Our method combines the observables in a principal component analysis. After calibrating the method with an independent redshift estimation for some of the clusters, we show – using a Bayesian approach – how the method can give an estimate of the redshift of the galaxy clusters. Although the error bars given by the morphological redshift estimation are large, it should be useful for future SZE surveys where thousands of clusters are expected to be detected; a first preselection of the high-redshift candidates could be done using our proposed morphological redshift estimator. Although not considered in this work, our method should also be useful to give an estimate of the redshift of clusters in X-ray and optical surveys.     

Deterioration processes affecting prehistoric rock art engravings in granite in NW Spain

Prehistoric rock art sites are endangered despite conservation efforts. The lack of scientific documentation regarding weathering agents affecting rock art and the absence of specific diagnostic protocols hinder the development of conservation strategies. The aim of this research was to investigate active deterioration processes in a granite petroglyph site located in Mougás (Galicia, NW Spain) by characterizing the granite, conducting a geotechnical study of the outcrop and describing and analysing the main weathering processes. Two main deterioration factors were identified. First, water favours block disjunction at the massif scale and causes pitting and surface erosion at the millimetre scale that affects the readability of the engravings. Second, high temperatures associated with wildfires cause mineral transformations that increase the susceptibility of the rock to weathering. Identifying deterioration factors is a first step in developing appropriate preventive conservation measures, which should aim to reduce rock contact time with water (technically affordable in the short term) and to reduce the probability of wildfire occurrence (technically more complex and possibly with longer‐term results). Copyright © 2018 John Wiley & Sons, Ltd.