Metamorphic and deformational imprint of Cambrian–Lower Ordovician rifting in the Ossa-Morena Zone (Iberian Massif, Spain)

The high-temperature metamorphism recorded in the Valuengo and Monesterio areas constitutes a rare occurrence in the Ossa-Morena Zone of Southwest Iberia, where low-grade metamorphism dominates. The metamorphism of the Valuengo area has been previously considered either Cadomian or Variscan in age, whereas that of Monesterio has been interpreted as a Cadomian imprint. However, these areas share important metamorphic and structural features that point towards a common tectonometamorphic evolution. The metamorphism of the Valuengo and Monesterio areas affects Late Proterozoic and Early Cambrian rocks, and is syn-kinematic with a top-to-the-north mylonitic foliation, which was subsequently deformed by early Variscan folds and thrusts. The U–Pb zircon age (480±7 Ma) we have obtained for an undeformed granite of the Valuengo area is consistent with our geological observations constraining the age of the metamorphism. We propose that this high-temperature metamorphic imprint along a NW–SE ductile extensional shear zone is related to the crustal extension that occurred in the Ossa-Morena Zone during the Cambro-Ordovician rifting. In the same way, the tectonothermal effect of the preorogenic rifting stage may have been wrongly attributed to orogenic processes in other regions as well as in this one.     

Computational study of tetrahedral Al–Si and octahedral Al–Mg ordering in phengite

 As part of a wider study of the nature and origins of cation order–disorder in micas, a variety of computational techniques have been used to investigate the nature of tetrahedral and octahedral ordering in phengite, K₂ ^[6](Al₃Mg)^[4](Si₇Al)O₂₀(OH)₄. Values of the atomic exchange interaction parameters J _n used to model the energies of order–disorder were calculated. Both tetrahedral Al–Si and octahedral Al–Mg ordering were studied and hence three types of interaction parameter were necessary: for T–T, O–O and T–O interactions (where T denotes tetrahedral sites and O denotes octahedral sites). Values for the T–T and O–O interactions were taken from results on other systems, whilst we calculated new values for the T–O interactions. We have demonstrated that modelling the octahedral and tetrahedral sheets alone and independently produces different results from modelling a whole T–O–T layer, hence justifying the inclusion of the T–O interactions. Simulations of a whole T–O–T layer of phengite indicated the presence of short-range order, but no long-range order was observed. Received: 8 August 2002 / Accepted: 14 February 2003 Acknowledgements The authors are grateful to EPSRC (EJP) and the Royal Society (CIS) for financial support. Monte Carlo simulations were performed on the Mineral Physics Group's Beowulf cluster and the University of Cambridge's High Performance Computing Facility.     

Raman scattering and X-ray diffraction study of the thermal decomposition of an ettringite-group crystal

 A Raman scattering and X-ray diffraction study of the thermal decomposition of a naturally occurring, ettringite-group crystal is presented. Raman spectra, recorded with increasing temperature, indicate that the thermal decomposition begins at ≈55 °C, accompanied by dehydration of water molecules from the mineral. This is in contrast to previous studies that reported higher temperature breakdown of ettringite. The dehydration is completed by 175 °C and this results in total collapse of the crystalline structure and the material becomes amorphous. The Raman scattering results are supported by X-ray diffraction results obtained at increasing temperatures. Received: 9 July 2001 / Accepted: 14 August 2002     

The Upper Neoproterozoic-Lower Cambrian of the Central Iberian Zone, Spain: chemical and isotopic (Sm-Nd) evidence that the sedimentary succession records an inverted stratigraphy of its source

The Upper Neoproterozoic-Lower Cambrian sedimentary succession in the Central Iberian Zone has recently been divided into 12 sedimentary units (I to XII). Units I to IV are of Late Neoproterozoic age, and units V to XII are Early Cambrian.Throughout the stratigraphic section, shales with similar ranges of SiO₂ and Al₂O₃ have TiO₂ and Zr contents that are coupled and vary gradually from the bottom (unit I, TiO₂ = 1.0-1.1%, Zr = 245-287 ppm) to the top (unit XII, TiO₂ = 0.74-0.86%, Zr = 141-192 ppm). These two parameters clearly distinguish Upper Neoproterozoic from Lower Cambrian compositions, as do certain elemental ratios (Al₂O₃/TiO₂, Rb/Zr, Nb/Ti), which vary from low values at the bottom of the section to high at the top. However, other elements (the rare earth elements [REEs], Y) do not fit this general trend, with heavy REEs and Y showing extreme concentrations in some Lower Cambrian units, which also have negative Ce anomalies.Units I to III and units XI to XII have uniform T_DM neodymium model ages (∼1.1 and 1.7 Ga, respectively), but the units between these two groups have erratic values between 1.4 Ga (unit VII) and 3.4 Ga (unit VIII). Thus, the bottom and top units have neodymium isotope ratios that indicate the presence of two source compositions: a composition that records a juvenile contribution younger than 1.1 Ga and a composition mainly derived from an old basement. Some samples from Lower Cambrian units have disturbed REE abundances and neodymium isotope ratios that are attributed to extensive chemical alteration that resulted in REE and Y redistribution. This alteration probably affected the material now preserved as unit IV during a period of relative sea level fall at the end of the Late Neoproterozoic. Both elemental and isotopic results support the suggestion that the Upper Neoproterozoic-Lower Cambrian stratigraphic section records an inverse stratigraphy of a source hinterland composed of a cover sequence of relatively juvenile crustal materials underlain by an older basement. Through time, the deeper crust gradually increased its contribution to the sediments in the basin from Late Neoproterozoic to Lower Cambrian times. These results are compatible with data from many other European zones.     

Dleineation and characterization of geomorphological features in a part of lower maharahstra metamorphic plateau using IRS-ID LISS-III Data

In the present study, an attempt has been made to delineate and characterize the different geomorphic units of Tundiya river catchment in a part of Lower Maharahstra Metamorphic Plateau, north-eastern part of Nagpur district, Maharashtra. The drainage, contour and delineated geological units have been overlaid on IRS-ID LISS III satellite imagery (bands 2,3 and 4) in EASI/PACE analysis system to delineate and characterize different geomorphological units and analysis of their processes based on the field observations. The study area is basically of metamorphic in origin with different geological formations and is influenced by the various fluvio-morphological processes. Based on the satellite data analysis, the distinct geomorphological units viz., table top summits, structural hills, subdued plateau, linear ridges, shallow, moderate and deeply buried foot slopes, shallow valley fills and deep valley fills have been delineated and characterized. The information generated from satellite data in the form of vector layers has been used in GIS to generate geological and geomorphological maps of the study area. The present study demonstrates that IRS-ID LISS-III data in conjunction with geology, drainage and contour parameters to enable detailed evaluation of different geomorphological units and analysis of their processes based on the field observations. The delineated geomorphological units can be utilized for evaluation and management of natural resources and geo-environment on sustainable basis at river catchment level.     

Land damage assessment - a case study

The paper discusses the land damage assessment and change detection analysis with reference to a mineral bearing zone in Manjhi, Manuni and Churan valleys. The area is located in environmentally sensitive and fragile region of Himalaya and constitutes of nearly 400 small-scale mines of slate, which were operative since last one hundred years and are stopped by court of law since 1995 on account of environment deterioration. The status of land degradation has been studied using IRS-1B satellite data of 1988,1992 and 1995. The geo-coded data on 1:50,000 scale has been interpreted and an increase in land degradation status was noticed. Finally, the management strategy for arresting the further land damage in a broader perspective is suggested.     

Change detection in Sal forest in Dehradun Forest Division using remote sensing and geographical information system

The review of study site have revealed the change in vegetation cover of Sal Dense to Sal Medium and Sal Open in 6 forest Mosaics owing to biotic and abiotic conditions prevailing in the specific areas. Analysis carried out using thematic map derived from aerial photograph of 1976 and satellite data of IRS 1C LISS III False Colour Composite (FCC) of March 1999 revealed the cause for change in forest density classes. Deforestation, encroachment and agriculture have been identified as the underlying causes, which have affected some specific locations to a marked extent. There has been a progressive and remarkable change among vegetation classes from 1976 to 1999. It is evident from forest type and density map that Sal density has significantly reduced from Sal Dense 65.61 % in 1976 to Sal Dense 11.12% in the year 1999 followed by Sal Open 11.18 % and Sal Medium 18.24 %. The overall change has been estimated to be 42.11% of the total forested area.     

Estimation of recent glacial variations in baspa basin using remote sensing technique

The Himalayas has one of the largest concentrations of glaciers outside the Polar Regions. Various reports suggest that significant number of mountain glaciers is shrinking due to climatic variations. Monitoring of these glaciers is important to assess future availability of water resources in the Himalayan region. However, Himalayan glaciers are normally difficult to monitor due to the rugged, mountainous terrain. Therefore, images of Indian Remote Sensing Satellite were used to monitor glaciers in the Baspa basin. Investigations have shown the presence of 30 glaciers in the basin, with areal extent of 167 km2. Out of these, 19 glaciers, with areal extent of 140 km² were selected to estimate retreat. Investigation suggests that almost all glaciers are retreating in the study basin and overall 19% deglaciation has been observed from 1962 to 2001. In general, altitude distribution appears to have significant influence on glacial retreat. Glaciers located around 5000 m altitude range are showing 24% loss as compared to 14% by glaciers located in altitude range higher than 5400 m. In addition, mean altitude of glacier terminus is shifted upward by 88 m, i.e. from 4482 to 4570 m in last 39 years. The glacial volumes were estimated using regression relationship between area and depth. The investigations have suggested that 19.10 km³ of glacial water stored in the 19 glaciers in 1962, has been reduced to 14.71 km³ in 2001, respectively, an overall loss of 23 percent in a period between 1962 and 2001. These investigations suggest that all glaciers in the Baspa Basin are reducing and in long term, such reducing trend can create scarcity of water in the region.     

Remote sensing and gis applications in the identification of aquaculture hotspots at village level

Interpretation of IRS LISS II and LISS III imagery has revealed the various landforms as well as land use/land cover features in a part of the Godavari delta coastal belt. A comparative analysis of geomorphological vs. land use/land cover maps suggested that the landforms exert a certain degree of control over human land use activities even in this monotonously plain area. Further, an analysis of the sequential imagery pertaining to 1992 and 2001 aimed at detecting the land use/land cover change has indicated that the aquaculture has phenomenally increased by 9,293.5 ha during the 9-year period. At the same time, the cropland which occupied about 29,104 ha in 1992 has been reduced to 19,153.9 ha by 2001 mainly due to the encroachment of aquaculture. Village level data on temporal variation in land use/land cover extracted through GIS analysis revealed that in 14 out of the total 39 villages in the area, the conversion of cropland into aquaculture ponds was more than 30% with the highest conversion rate of 89.8% in Gondi village. These fourteen villages, which are designated as ‘aquaculture hotspots’ are grouped into 4 priority classes based on the intensity of conversion.