Porphyroblast rotation during crenulation cleavage development: an example from the aureole of the Mooselookmeguntic pluton, Maine, USA

In the low‐pressure, high‐temperature metamorphic rocks of western Maine, USA, staurolite porphyroblasts grew at c. 400 Ma, very late during the regional orogenesis. These porphyroblasts, which preserve straight inclusion trails with small thin‐section‐scale variation in pitch, were subsequently involved in the strain and metamorphic aureole of the c. 370 Ma Mooselookmeguntic pluton. The aureole shows a progressive fabric intensity gradient from effectively zero emplacement‐related deformation at the outer edge of the aureole ～2900 m (map distance) from the pluton margin to the development of a pervasive emplacement‐related foliation adjacent to the pluton. The development of this pervasive foliation spanned all stages of crenulation cleavage development, which are preserved at different distances from the pluton. The spread of inclusion‐trail pitches in the staurolite porphyroblasts, as measured in two‐dimensional (2‐D) thin sections, increases nonlinearly from ～16° to 75° with increasing strain in the aureole. These data provide clear evidence for rotation of the staurolite porphyroblasts relative to one another and to the developing crenulation cleavage. The data spread is qualitatively modelled for both pure and simple shear, and both solutions match the data reasonably well. The spread of inclusion‐trail orientations (40–75°) in the moderately to highly strained rocks is similar to the spread reported in several previous studies. We consider it likely that the sample‐scale spread in these previous studies is also the result of porphyroblast rotation relative to one another. However, the average inclusion‐trail orientation for a single sample may, in at least some instances, reflect the original orientation of the overgrown foliation.     

Controls on low-pressure anatexis

Low-pressure anatexis, whereby rocks melt in place after passing through the andalusite stability field, develops under more restricted conditions than does low-pressure metamorphism. Our thermal modelling and review of published work indicate that the following mechanisms, operating alone, may induce anatexis in typical pelitic rocks without inducing wholesale melting in the lower crust: (i) magmatic advection by pervasive flow; (ii) crustal-scale detachment faulting; and (iii) the presence of a high heat-producing layer. Of these, only magmatic advection by pervasive flow and crustal-scale detachment faulting have been shown quantitatively to provide sufficient heat to cause widespread melting. Combinations of the above mechanisms with pluton-scale magmatic advection, shear heating, removal of the lithospheric mantle, or with each other provide additional means of developing suitable high temperatures at shallow crustal levels to generate low-pressure anatexis.     

From source terrains of the Eastern Alps to the Molasse Basin: Detrital record of non-steady-state exhumation

Fission-track cooling ages of detrital apatite (AFT) in the East Alpine Molasse Basin display age groups corresponding to geodynamic events in the orogen since Jurassic times. These age groups are typical of certain thermotectonic units, which formed a patchwork in the Swiss and Eastern Alps. By a combination of petrographic and thermochronologic data, progressive erosion of source terrains is monitored in different catchments since the Oligocene. The AFT cooling ages show a decrease in lag time until when rapidly cooled debris derived from tectonically exhumed core complexes became exposed. After termination of tectonic exhumation, lag times of debris derived from the core complexes increased. Neither on the scale of the entire Eastern Alps, or on the scale of individual catchments, steady-state exhumation is observed, due to the highly dynamic changes of exhumation rates since Late Eocene collision.     

Aftershocks series monitoring of the September 18, 2004 M = 4.6 earthquake at the western Pyrenees: A case of reservoir-triggered seismicity?

On September 18, 2004, a 4.6 mbLg earthquake was widely felt in the region around Pamplona, at the western Pyrenees. Preliminary locations reported an epicenter less than 20 km ESE of Pamplona and close to the Itoiz reservoir, which started impounding in January 2004. The area apparently lacks of significant seismic activity in recent times. After the main shock, which was preceded by series of foreshocks reaching magnitudes of 3.3 mbLg, a dense temporal network of 13 seismic stations was deployed there to monitor the aftershocks series and to constrain the hypocentral pattern. Aftershock determinations obtained with a double-difference algorithm define a narrow epicentral zone of less than 10 km², ESE–WNW oriented. The events are mainly concentrated between 3 and 9 km depth. Focal solutions were computed for the main event and 12 aftershocks including the highest secondary one of 3.8 mbLg. They show mainly normal faulting with some strike-slip component and one of the nodal planes oriented NW–SE and dipping to the NE. Cross-correlation techniques applied to detect and associate events with similar waveforms, provided up to 33 families relating the 67% of the 326 relocated aftershocks. Families show event clusters grouped by periods and migrating from NW to SE. Interestingly, the narrow epicentral zone inferred here is located less than 4 km away from the 111-m high Itoiz dam. These hypocentral results, and the correlation observed between fluctuations of the reservoir water level and the seismic activity, favour the explanation of this foreshock–aftershock series as a rapid response case of reservoir-triggered seismicity, burst by the first impoundment of the Itoiz reservoir. The region is folded and affected by shallow dipping thrusts, and the Itoiz reservoir is located on the hangingwall of a low angle southward verging thrust, which might be a case sensible to water level fluctuations. However, continued seismic monitoring in the coming years is mandatory in this area to infer more reliable seismotectonic and hazard assessments.     

Modeling of the classification behavior of the diaphragms used in multi-chamber cement mills

A new approach has been developed for describing the classification that arises at the diaphragm in multi-chamber ball mills. Fourteen industrial scale cement mills have been sampled in this study and after mass balancing, model fits of the equipment were done. Successive mill product predictions for the sampled conditions were achieved, and requirements to build up an optimization capable model are discussed.     

Flotation and depression control of arsenopyrite through pH and pulp redox potential using xanthate as the collector

The role of pH and pulp redox potential (E_H) to control the flotation and depression of arsenopyrite has been investigated through studies on microflotation of arsenopyrite crystals and batch flotation of an arsenopyritic ore using isopropyl xanthate as collector. The transition between flotation and depression of arsenopyrite is established by the reversible potential of the xanthate/dixanthogen couple. Adsorption of arsenate ions on ferric hydroxide has been studied through electrokinetics to delineate mechanisms involved in the depression of arsenopyrite using oxidants. Chemical binding between arsenate species and ferric hydroxide sites on arsenopyrite is suggested as the mechanism responsible for depression of arsenopyrite. E_H conditions are given for the flotation and depression of arsenopyite at various pH values for the arsenopyritic ore.     

Une approche innovante pour modéliser la biodégradation des composés organochlorés volatils en aquifères poreux

The goal of this study was to develop an innovative chloroethene biodegradation module based on biological, thermodynamical and mechanistic concepts. The biodegradation scheme was based on the postulate that in each part of an aquifer only one degradation mechanism is dominant: the one involving the most energetic electron acceptor. Thus, the selection of the active degradation mechanism was a function of the concentration of different electron acceptors. Modified Monod-type kinetics was used in order to take into account the possible influence of some compounds on the biodegradation of a given organic compound. The numerical model developed was applied to a simple test case, whose results are presented here. To cite this article: F. Nex et al., C. R. Geoscience 338 (2006).     

Climate variability in the Spanish Pyrenees during the last 30,000 yr revealed by the El Portalet sequence

Palynological, sedimentological and stable isotopic analyses of carbonates and organic matter performed on the El Portalet sequence (1802 m a.s.l., 42°48′00?N, 0°23′52?W) reflect the paleoclimatic evolution and vegetation history in the central-western Spanish Pyrenees over the last 30,000 yr, and provide a high-resolution record for the late glacial period. Our results confirm previous observations that deglaciation occurred earlier in the Pyrenees than in northern European and Alpine sites and point to a glacial readvance from 22,500 to 18,000 cal yr BP, coinciding with the global last glacial maximum. The patterns shown by the new, high-resolution pollen data from this continental sequence, chronologically constrained by 13 AMS ¹⁴C dates, seem to correlate with the rapid climate changes recorded in Greenland ice cores during the last glacial-interglacial transition. Abrupt events observed in northern latitudes (Heinrich events 3 to 1, Oldest and Older Dryas stades, Intra-Allerød Cold Period, and 8200 cal yr BP event) were also identified for the first time in a lacustrine sequence from the central-western Pyrenees as cold and arid periods. The coherent response of the vegetation and the lake system to abrupt climate changes implies an efficient translation of climate variability from the North Atlantic to mid latitudes.     

Up-temperature flow of surface-derived fluids in the mid-crust: the role of pre-orogenic burial of hydrated fault rocks

The Walter‐Outalpa shear zone in the southern Curnamona Province of NE South Australia is an example of a shear zone that has undergone intensely focused fluid flow and alteration at mid‐crustal depths. Results from this study have demonstrated that the intense deformation and ductile shear zone reactivation, at amphibolite facies conditions of 534 ± 20 °C and 500 ± 82 MPa, that overprint the Proterozoic Willyama Supergroup occurred during the Delamerian Orogeny (c. 500 Ma) (EPMA monazite ages of 501 ± 16 and 491 ± 19 Ma). This is in contrast to the general belief that the majority of basement deformation and alteration in the southern Curnamona Province occurred during the waning stages of the Olarian Orogeny (c. 1610–1580 Ma). These shear zones contain hydrous mineral assemblages that cut wall rocks that have experienced amphibolite facies metamorphism during the Olarian Orogeny. The shear zone rock volumes have much lower δ¹⁸O values (as low as 1‰) than their unsheared counterparts (7–9‰), and calculated fluid δ¹⁸O values (5–8‰) consistent with a surface‐derived fluid source. Hydrous minerals show a decrease in δD_(H2O) from ?14 to ?22‰, for minerals outside the shear zones, to ?28 to ?40‰, for minerals within the shear zones consistent with a contribution from a meteoric source. It is unclear how near‐surface fluids initially under hydrostatic pressure penetrate into the middle crust where fluid pressures approach lithostatic, and where fluid flow is expected to be dominantly upward because of pressure gradients. We propose a mechanism whereby faulting during basin formation associated with the Adelaidean Rift Complex (c. 700 Ma) created broad hydrous zones containing mineral assemblages in equilibrium with surface waters. These panels of fault rock were subsequently buried to depths where the onset of metamorphism begins to dehydrate the fault rock volumes evolving a low δ¹⁸O fluid that is channelled through shear zones related to Delamerian Orogenic activity.     

Timing effects on the fragmentation of small scale blocks of granodiorite

A series of small scale tests, simulating multi-hole blasts have been performed to establish the effect of delays on blast fragmentation. The blasts were performed in high quality granodiorite blocks, which were cut from stone prepared by dimensional stone quarry operations. The pattern used was equilateral triangular, with a distance of 10.2 cm between boreholes, which had a diameter of 11 mm, were loaded with detonating cord and the coupling medium was water. The delays used were achieved using different lengths of detonating cord for the cases of delays between 0 and 100 μs between holes and a sequential blasting machine firing seismic detonators for larger delays up to 4 ms. All fragments were collected and screened. The experiments showed that the worst fragmentation was achieved with simultaneous initiation of all charges. Fragmentation improved with the delay time between holes up to 1 ms between holes. If the experiments are scaled up, the results show that in granodiorite, fragmentation optimization requires delays of few milliseconds per metre of burden. The findings, agree with previously published work, involving larger scale experiments and other rock types.