Wet deposition of excess sulfate at Macquarie Island, 54° S

Annual wet deposition of excess sulfate at Macquarie Island has been estimated from 5 months of rainwater composition data covering the Austral summer of 1985/86. The resulting figure of 2.1±0.6 mmol/m²/yr is at the low end of previous estimates of maritime excess sulfate deposition by precipitation. Within estimated uncertainty limits this figure is consistent with the DMS emission flux which would be predicted for latitude 50°–60° S, based solely on available Northern Hemispheric DMS measurements.Temporarily at the International Meteorological Institute, Stockholm University, S-106 91, Stockholm, Sweden.     

Cesstibtantite—a geologic introduction to the inverse pyrochlores

Summary The crystal structure of cesstibtantite has been solved from diffractometer data collected on samples from Leshaia, Russia and the Tanco pegmatite, Manitoba. Cesstibtantite from the Leshaia pegmatite (type locality) hasa 10.515(2) Å, space groupFd3m, composition Cs_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_O.91(Ta_1.88Nb_0.12)₂(O_5.69[OH, F]_0.31)₆(OH, F)_0.69, Z 8; its structure was refined toR 3.8,wR 4.3% using 96 observed (F > 3[F]) reflections (MoK). Cesstibtantite from the Tanco pegmatite hasa 10.496(1) Å, space groupFd3m, composition (Cs_0.22K_0.01)_0.23(Na_0.45Sb_0.39Pb_0.14· Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78[OH,F]_0.22)₆(OH,F)_0.55,Z 8; its structure was refined toR 3.9w R 3.7% using 104 observed reflections. Cesstibtantite differs from the normal pyrochlores in that it contains significant amounts of very large cations such as Cs. As these cations are too large (^VIII[r] > 1.60 Å) for the conventional [8]-coordinated A site, they occupy the [18]-coordinated site, which normally contains monovalent anions. Natural cesstibtantite samples are non-ideal in that both Cs and monovalent anions occur at the site; thus cesstibtantite is intermediate to thenormal pyrochlores (with only monovalent anions at the site) and theinverse pyrochlores (with only large cations at the site).

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Cesstibtantit—eine geologische Einfiihrung in die inversen Pyrochlore

Zusammenfassung Die Kristallstruktur von Cesstibtantit wurde auf der Basis von Diffraktometerdaten von Proben von Leshaia, Russland and dem Tanco Pegmatit, Manitoba, gelöst. Cesstibtantit aus dem Leshaia Pegmatit (Typlokalität) hat a 10.515(2) Å, RaumgruppeFd3m, die Zusammensetzung CS_0.31(Sb_0.57Na_0.31Pb_0.02Bi_0.01)_0.91(Ta_1.88Nb_0.12)₂· (O_5.69OH, F_0.31)₆(OH, F)_0.69 Z 8; die Struktur wurde aufR 3.8,wR 4.3% verfeinert unter Benützung von 96 beobachteten Reflexen. Cesstibtantit vom Tanco Pegmatit hat a 10.496(1) Å, RaumgruppeFd3m, die Zusammensetzung (Cs_0.22K_0.01)_0.23(Na_0.45· Sb_0.39Pb_0.14Ca_0.06Bi_0.02)_1.06(Ta_1.95Nb_0.05)₂(O_5.78OH,F_0.22)₆(OH,F)_0.55,Z 8; seine Struktur wurde aufR 3.9wR 3.7% auf der Basis von 104 beobachteten Rettexen verfeinert. Cesstibtantit unterscheidet sich von normalen Pyrochloren insofern, als er signifikante Mengen von sehr großen Kationen, wie z.B. Cs enthält. Da these Kationen zu groß sind (^VIII r 1.60 Å) für eine konventionelle [8]-koordinierteA Stelle, nehmen she die [18]-koordinierten Positionen ein, welche normalerweise monovalente Anionen enthalten. Natürliche Cesstibtantitproben sind nicht ideal insofern als sowohl Cs als auch monovalente Anionen in der Position vorkommen. Somit ist Cesstibtantit intermediär zu den normalen Pyrochloren (mit nur monovalenten Anionen auf der Position) and den inversen Pyrochloren (mit ausschließlichen großen Kationen an der Position).

     

The upper Bathonian ammonite zonation of East Siberia

Modifications to the upper Bathonian zonal scale for northern East Siberia provided by the newly available paleontological record on Middle Jurassic reference sections in the Arctic regions of Yakutia and by the revised earlier collections, are justified. The oldest East Siberian members of Cadoceras are found to be characteristic not of the initial Callovian age as believed by Russian paleontologists, but of the terminal Bathonian age as was previously shown in the biostratigraphic scheme of East Greenland. The succession of zones and index species analogous to that of the latter is revealed in the studied region and the zonal boundaries in Siberia and East Greenland are inferred to be synchronous. Finds of Cadoceras calyx in the upper Bathonian scale permitted, for the first time, the recognition of a corresponding zone. The Bathonian-Callovian boundary is placed between the calyx and anabarense zones. The upper Bathonian zonal scale of northern East Siberia is now in total agreement with the East Greenland zonal scale.     

An ephemeral turbidity maximum generated by resuspension of organic-rich matter in a macrotidal estuary, S.W. Wales

An ephemeral estuarine turbidity maximum (ETM) occurs at high water in the macrotidal Taf estuary (SW Wales, United Kingdom). A new mechanism of ETM formation, due to resuspension and advection of material by flood tidal currents, is observed that differs from classical mechanisms of gravitational circulation and tidal pumping. The flood tide advances across intertidal sand flats in the main body of the estuary, progressively entraining material from the rippled sands. Resuspension creates, a turbid front that has suspended sediment concentrations (SSC) of about 4,000 mg I⁻¹ by the time it reaches its landward limit which is also the landward limit of salt penetration. This turbid body constitutes the ETM. Deposition occurs at high slack water but the ETM retains SSC values up to 800 mg I⁻¹, 1–2 orders of magnitude greater than ambient SSC values in the river and estuarine waters on either side. The ETM retreats down the estuary during the ebb; some material is deposited thinly across emergent intertidal flats and some is flushed out of the estuary. A new ETM is generated by the next flood tide. Both location and SSC of the ETM scale on Q/R³ where Q is tidal range and R is river discharge. The greatest expression of the ETM occurs when a spring tide coincides with low river discharge. It does not form during high river discharge conditions and is poorly developed on neap tides. Particles in the ETM have effective densities (120–160 kg m⁻³) that are 3–4 times less than those in the main part of the estuary at high water. High chlorophyll concentrations in the ETM suggest that flocs probably originate from biological production in the estuary, including production on the intertidal sand flats.     

Holocene climate variability as derived from alkenone sea surface temperature and coupled ocean-atmosphere model experiments

Holocene climate modes are identified by the statistical analysis of reconstructed sea surface temperatures (SSTs) from the tropical and North Atlantic regions. The leading mode of Holocene SST variability in the tropical region indicates a rapid warming from the early to mid Holocene followed by a relatively weak warming during the late Holocene. The dominant mode of the North Atlantic region SST captures the transition from relatively warm (cold) conditions in the eastern North Atlantic and the western Mediterranean Sea (the northern Red Sea) to relatively cold (warm) conditions in these regions from the early to late Holocene. This pattern of Holocene SST variability resembles the signature of the Arctic Oscillation/North Atlantic Oscillation (AO/NAO). The second mode of both tropical and North Atlantic regions captures a warming towards the mid Holocene and a subsequent cooling. The dominant modes of Holocene SST variability emphasize enhanced variability around 2300 and 1000 years. The leading mode of the coupled tropical-North Atlantic Holocene SST variability shows that an increase of tropical SST is accompanied by a decrease of SST in the eastern North Atlantic. An analogy with the instrumental period as well as the analysis of a long-term integration of a coupled ocean-atmosphere general circulation model suggest that the AO/NAO is one dominant mode of climate variability at millennial time scales.     

Magnetic stratigraphy observed in ferromanganese crust

Summary. A sample of ferromanganese crust deposit (SCHW-1D) was cut into two sets of 1 mm slices for palaeomagnetic study. Alternating field and thermal demagnetization, and isothermal remanent magnetization analyses were performed on each thin slice. The results reveal the presence of a stable magnetism and both normal and reversed polarity intervals in the specimens. The observed polarity intervals cannot be confidently correlated with the geomagnetic polarity time-scale of the last 10 Myr due to the polarity overlap inherent in the sampling technique. But the results confirm the slow accretion rate of ferromanganese deposit determined by ¹⁰Be method and suggest potential use of ferromanganese deposits in palaeomagnetic and tectonic studies.     

Geometrical spreading factor of head waves in cased and open boreholes

Factors (coefficients) of geometrical spreading of compressional and shear head waves are calculated for an impulse multipole source of elastic oscillations in boreholes. It is shown that the length of the logging tool (i.e., the distance between the source and the nearest receiver) used for sonic measurements and the velocities of elastic waves in the medium both contribute to the factor of geometrical spreading. For a high-velocity formation (the shear wave velocity in the rock is higher than the compressional wave velocity in the fluid that fills the borehole) and a sufficiently long sonic tool with a monopole source, the coefficient of geometrical spreading is approximated by asymptotic formula 1/Z [Roever et al., 1974; Krauklis and Krauklis, 1976], where Z is the length of the tool; i.e., the amplitude of the compressional head wave decreases proportionally to the distance between the source and the receiver. In acoustically soft formations, this approximation is inapplicable even for long tools with length Z > 4 m. Waveforms in cased boreholes have a significant frequency dispersion even in case of good-quality cementing, and the factor of geometrical spreading there depends considerably on the length of the tool and the elastic properties of the rocks.     

Estimation of contaminant transport parameters for a tropical sand in a sand tank model

This research describes the goals, design and implementation of a quasi natural gradient, laboratory scale, sand tank (aquifer) model experiment. The model was used to study the transport of an inorganic tracer (Chloride) in groundwater, within a tropical aquifer (porous medium) material. Three-dimensional sand tank (1.8 m × 0.3 m × 0.8 m) experiments were conducted to investigate contaminant transport and natural attenuation within the sand tank. In all, 360 samples were collected during 24 sampling sessions, for the three days of the tracer experiments in the Sand Tank. The Owena sand is a poorly graded sand with 88.1 % sand and 11.9 % gravel. Geotechnical properties including; coefficient of uniformity C_u = 2.53, coefficient of gradation C_z = 0.181, hydraulic conductivity K = 5.76 × 10^?4 m/s, bulk density p = 1.9 Mg/m³, effective porosity n_e = 0.215 and median grain diameter D₅₀ = 0.55 mm, were determined. Other relevant hydraulic and solute transport parameters, such as dispersion coefficients and dispersivities were also established for the tropical soil.