A two-dimensional photochemical model of the stratosphere with Rayleigh scattering

Computations of concentrations of minor stratospheric gases using a two-dimensional model of the stratosphere are reported. The model includes Rayleigh scattering. This results in an increase in the photodissociation rate computation time by a factor of 1.5. The effect of ground albedo is assessed by comparing our results with a calculation of photolysis rates for a constant albedo with latitude. Comparison of results with a reference model including only molecular absorption are also made. The largest differences (50%) occur in NO and OH. An approximate expression for including the effects of Rayleigh scattering and surface reflectance in multi-dimensional models is suggested.     

Stable isotope studies of fluid inclusions in speleothems and their paleoclimatic significance

Fluid inclusions found trapped in speleothems (cave deposited travertine) are interpreted as samples of seepage water from which enclosing calcium carbonate was deposited. The inclusions are assumed to have preserved their D/H ratios since the time of deposition. Initial ¹⁸O/¹⁶O ratios can be inferred from δD because rain- and snow-derived seepage waters fall on the meteoric water line (δD = 8δ¹⁸O + 10). Estimates of temperature of deposition of the carbonate can be calculated from inclusion D/H ratios and δ¹⁸O of enclosing calcite in Pleistocene speleothems. For most speleothems investigated (0–200,000 yr old) δ¹⁸O of calcite appears to have decreased with increasing temperature of deposition indicating that the dominant cause of climate-dependent change in δ¹⁸O of calcite was the change in K_cw, the isotope fractionation equilibrium constant, with temperature; δ¹⁸O of meteoric precipitation generally increased with increasing temperature, but not sufficiently to compensate for the decrease in K_cw.     

First cosmogenic 10Be age constraint on the timing of Younger Dryas glaciation and ice cap thickness,western Scottish Highlands

We use cosmogenic ¹⁰Be surface exposure age techniques at a locality close to Rannoch Moor, western Scottish Highlands, in order to establish the age and chronology of its most recent glaciation. Glacial erratics and an in situ bedrock quartz vein sampled from this site—the summit of Beinn Inverveigh—have yielded zero‐erosion exposure ages of 12.9 ± 1.5 ka to 11.6 ± 1.0 ka, implying complete ice cover of the mountain during the Younger Dryas, or Loch Lomond Stadial. These results fit closely with published ¹⁴C dates that bracket the maximum (lateral) extent of ice cap outlet glaciers, and are the first internally consistent ages to specifically address this period of glaciation in Scotland. Furthermore, the dates imply that previous palaeoglaciological reconstructions for this area may have underestimated both the thickness of the former ice cap and, by implication, its volume. © British Geological Survey/Natural Environment Research Council copyright 2007. Reproduced with the permission of BGS/NERC. Published by John Wiley & Sons, Ltd.     

Evaporation effects on the formation of martian gullies

In order to investigate the formation of martian gullies and the stability of fluids on Mars, we examined about 120 gully images. Twelve HiRISE images contained a sufficient number of Transverse Aeolian Ridges (TARs) associated with the gullies to make the following measurements: overall gully length, length of the alcove, channel and apron, and we also measured the frequency of nearby TARs. Six of the 12 images examined showed a statistically significant negative correlation between overall gully length (alcove, channel and apron length) and TAR frequency. Previous experimental work from our group has shown that at temperatures below ∼200 K, evaporation rate increases by about an order of magnitude as wind speed increases from 0 to ∼15 m/s. Thus the negative correlations we observe between gully length and dune frequency can be explained by formation at temperatures below ∼200 K where wind speed/evaporation is a factor governing gully length. In these cases evaporation of the fluid carving the gully was a constraint on their dimensions. Cases where there is no correlation between gully length and TAR frequency, can be explained by formation at temperatures >200 K. The temperatures are consistent with Global Circulation Model and Thermal Emission Spectrometer (TES) data for these latitudes. The temperatures suggested by these trends are consistent with the fluid responsible for gully formation being a strong brine, such as Fe₂(SO₄)₃ which has a eutectic temperature of ∼200 K. We also find that formation timescales for gullies are 10⁵-10⁶ years.     

Observed and modelled tidal currents in the New Zealand region

Tidal currents derived from current meter measurements are compared with the output from a barotropic tidal model of the New Zealand region. For the semi‐diurnal constituents there was very good agreement for the M₂ tide and good agreement for the S₂ tide. For the diurnal constituents (K_l, O_l) it was found that as the amplitude of the constituents decreased so did both the model/observation agreement and the accuracy of the observed tidal ellipse parameters. Consequently it was not possible to decide whether differences arose through shortcomings in the model or in the data. However, the overall performance of the model as a prognostic tool for ocean tidal current simulation appears to be good.     

El Niño and decadal effects on sea‐level variability in northern New Zealand: A wavelet analysis

Sea‐level data from two sites in northern New Zealand, along with the Southern Oscillation Index (SOI), are analysed for interannual and decadal variability using wavelets. The analysis shows, using statistically significant wavelet power, there is a significant relationship between mean sea level (MSL) and SOI. However, the relationship is highly variable, both in magnitude and in the range of time‐scales over which it occurs. This non‐stationarity necessitates the use of techniques such as wavelets for analysis. An interdecadal response in MSL around northern New Zealand has been isolated, with shifts occurring in 1950 and the late 1970s. This behaviour in MSL appears to coincide with shifts in the Pacific Decadal Oscillation, thought previously to be largely centred in the North Pacific. A strong correlation between SOI and sea surface temperature (SST) is also demonstrated. This relationship appears to be stable in magnitude (a large change in SOI produces a large change in SST) and to occur over the same range of time‐scales. More SST and MSL data are required for other parts of New Zealand to determine whether these findings apply elsewhere.     

Food with a visible face: Traceability and the public promotion of private governance in the Japanese food system

The years since 2000 have seen a constant stream of high-profile scandals relating to food safety and food labeling in Japan. One response of Japan’s Ministry of Agriculture, Forestry and Fisheries (MAFF) has been to promote food traceability as a mechanism to improve food safety and to provide reliable information to consumers about their food. MAFF’s main approach to traceability promotion, however, has not involved making traceability mandatory (as has been done in the EU) but encouraging private companies to adopt it. These actions constitute, I argue, an example of the public promotion of private governance. When viewed against the literature on the private governance of food safety and quality, MAFF’s traceability activities are surprising for three reasons: their forms and extent, the relative lack of interest the Ministry has shown in third-party certification, and the way MAFF has responded to concerns about the safety of imported food by focusing almost entirely on domestic traceability. I also argue, however, that looking at the literature from a Japanese perspective suggests that public encouragement is more central to the rise of private governance in the global agri-food system than is usually appreciated.