Organic Geochemical and Petrographic Characteristics of the Coal Measure Source Rocks of Pinghu Formation in the Xihu Sag of the East China Sea Shelf Basin: Implications for Coal Measure Gas Potential

Coal measure source rocks, located in the Xihu Sag of the East China Sea Shelf Basin, were analyzed to define the hydrocarbon generation potential, organic geochemistry/petrology characteristics, and coal preservation conditions. The Pinghu source rocks in the Xihu Sag are mainly gas-prone accompany with condensate oil generation. The coals and shales of the Pinghu Formation are classified from "fair" to "excellent" source rocks with total organic carbon(TOC) contents ranging from 25.2% to 77.2% and 1.29% to 20.9%, respectively. The coals are richer in TOC and S1+S2 than the shales, indicating that the coals have more generation potential per unit mass. Moreover, the kerogen type of the organic matter consists of types Ⅱ-Ⅲ and Ⅲ, which the maturity Ro ranges from 0.59% to 0.83%. Petrographically, the coals and shales are dominated by vitrinite macerals(69.1%–96.8%) with minor proportions of liptinite(2.5%–17.55%) and inertinite(0.2%–6.2%). The correlation between maceral composition and S1+S2 indicates that the main contributor to the generation potential is vitrinite. Therefore, the coals and shales of the Pinghu Formation has good hydrocarbon generation potential, which provided a good foundation for coal measure gas accumulation. Furthermore, coal facies models indicates that the Pinghu coal was deposited in limno-telmatic environment under high water levels, with low tree density(mainly herbaceous) and with low-moderate nutrient supply. Fluctuating water levels and intermittent flooding during the deposition of peat resulted in the inter-layering of coal, shale and sandstone, which potentially providing favorable preservation conditions for coal measure gas.     

Characterizing sources of groundwater to a tropical coastal lagoon in a karstic area using radium isotopes and water chemistry

Radium isotopes (²²³Ra, ²²⁴Ra, ²²⁶Ra, and ²²⁸Ra) and water chemistry were used to identify two chemically distinct sources of submarine groundwater discharge (SGD) in Celestún Lagoon, Yucatán, Mexico. Low salinity groundwater discharging from springs within the lagoon has previously been identified and extensively sampled for nutrient concentrations. However, a second type of groundwater discharging into the lagoon was detected during this study using radium isotope activity measurements. This second type of groundwater is characterized by moderate salinities (within the range of lagoon salinities) and very elevated radium activities in comparison to the low salinity groundwater, mixed lagoon water, and seawater. Further analysis showed that the two types of groundwater also have distinct chloride, strontium, and sulfate ratios, along with slightly different nutrient concentrations. Groundwater discharge occurs through large and small springs scattered throughout the lagoon, and both types of groundwater were detected discharging from one of the larger springs. The relative proportions of low salinity groundwater and brackish high radium groundwater varied over the tidal cycle. In order to better understand the relative contributions of each type of groundwater to the lagoon, a three end-member mixing model based on the distinct chemical and isotopic compositions of both types of groundwater and of seawater was used to estimate the distribution of each water type throughout the lagoon in different seasons. This study suggests that substantial groundwater discharge to the lagoon can occur during both dry and rainy seasons. The presence of two groundwater sources has implications for monitoring and protection of the Celestún Lagoon Biosphere Reserve, since the two sources may have different susceptibilities to anthropogenic contamination depending on their respective recharge area and recharge rates.     

The computation of deformations

The mathematics of irrotational deformation are simplified by presentation in matrix form. Matrix equations are easily programmed and are easily interpreted in geometrical terms. Graphical operations commonly carried out on orientation nets such as rotation of data can be translated into simple matrix equations for use with a computer. If the shape and orientation of the deformation ellipsoid for a pure shear are known, a matrix can be constructed for use as a deformation matrix. This can be used to deform other deformation ellipsoids to obtain a resultant ellipsoid. It can also be used to deform geological structures such as lineations and planes. The matrix equations for these operations are very simple, but their numerical solution often requires a computer.     

Microplastic Contamination in Karst Groundwater Systems

Groundwater in karst aquifers constitutes about 25% of drinking water sources globally. Karst aquifers are open systems, susceptible to contamination by surface-borne pollutants. In this study, springs and wells from two karst aquifers in Illinois, USA, were found to contain microplastics and other anthropogenic contaminants. All microplastics were fibers, with a maximum concentration of 15.2 particles/L. The presence of microplastic was consistent with other parameters, including phosphate, chloride and triclosan, suggesting septic effluent as a source. More studies are needed on microplastic sources, abundance, and impacts on karst ecosystems.     

Beach recovery from extreme storm activity during the 2013–14 winter along the Atlantic coast of Europe

The storm sequence of the 2013–14 winter left many beaches along the Atlantic coast of Europe in their most eroded state for decades. Understanding how beaches recover from such extreme events is essential for coastal managers, especially in light of potential regional increases in storminess due to climate change. Here we analyse a unique dataset of decadal beach morphological changes along the west coast of Europe to investigate the post-2013–14 winter recovery. We show that the recovery signature is site specific and multi-annual, with one studied beach fully recovered after 2 years, and the others only partially recovered after 4 years. During the recovery phase, winter waves primarily control the timescales of beach recovery, as energetic winter conditions stall the recovery process whereas moderate winter conditions accelerate it. This inter-annual variability is well correlated with climate indices. On exposed beaches, an equilibrium model showed significant skill in reproducing the post-storm recovery and thus can be used to investigate the recovery process in more detail. © 2018 John Wiley & Sons, Ltd.     

The mixed-bed glacial landform imprint of the North Sea Lobe in the western North Sea

During the last glacial cycle an intriguing feature of the British-Irish Ice Sheet was the North Sea Lobe (NSL); fed from the Firth of Forth and which flowed south and parallel to the English east coast. The controls on the formation and behaviour of the NSL have long been debated, but in the southern North Sea recent work suggests the NSL formed a dynamic, oscillating terrestrial margin operating over a deforming bed. Further north, however, little is known of the behaviour of the NSL or under what conditions it operated. This paper analyses new acoustic, sedimentary and geomorphic data in order to evaluate the glacial landsystem imprint and deglacial history of the NSL offshore from NE England. Subglacial tills (AF2/3) form a discontinuous mosaic interspersed with bedrock outcrops across the seafloor, with the partial excavation and advection of subglacial sediment during both advance and retreat producing mega-scale glacial lineations and grounding zone wedges. The resultant ‘mixed-bed’ glacial landsystem is the product of a dynamic switch from a terrestrial piedmont-lobe margin with a net surplus of sediment to a partially erosive, quasi-stable, marine-terminating, ice stream lobe as the NSL withdrew northwards. Glaciomarine sediments (AF4) drape the underlying subglacial mixed-bed imprint and point to a switch to tidewater conditions between 19.9 and 16.5 ka cal BP as the North Sea became inundated. The dominant controls on NSL recession during this period were changing ice flux through the Firth of Forth ice stream onset zone and water depths at the grounding line; the development of the mixed-bed landsystem being a response to grounding line instability. © 2018 John Wiley & Sons, Ltd.     

Evaluation of burst liability in kimberlite using support vector machine

Due to the complex mechanisms of rockburst, there is no current effective method to reliably predict these events. A statistical learning method, support vector machine (SVM), is employed in this paper for kimberlite burst prediction. Four indicators \(\sigma_{\theta } ,\sigma_{c} ,\sigma_{t} ,W_{\text{ET}}\) are chosen as input indices for the SVM, which is trained using 108 groups of rockburst cases from around the world. Data uniformization is used to avoid negative impact of differing dimensions across the original data. Parameter optimization is embedded in the training process of the SVM to achieve optimized predictive ability. After training and optimization, the SVM reaches an accuracy of 95% in rock burst prediction for validation samples. The constructed SVM is then employed in kimberlite burst liability evaluation. The model indicated a moderate burst risk, which matches observed instances of rockburst at a diamond mine in north Canada. The SVM method ignores the focus on rockburst mechanisms, instead relying on representative indicators to develop a predictive model through self-learning. The prediction results show an excellent accuracy, which means this method has a potential application in rockburst prediction.     

Morphologic adjustments of actively evolving highly curved neck cutoffs

Neck cutoffs and their resultant oxbow lakes are important and prominent features of riverine landscapes. Detailed field-based research focusing on the morphologic evolution of neck cutoffs is currently insufficient to fully characterize cutoff evolution. High-resolution bathymetric data were collected over 3 years for the purpose of determining channel morphology and morphologic change on three actively evolving neck cutoffs. Results indicate the following general trends in morphologic adjustment: (1) a longitudinal bar in the upstream meander limb that develops near the entrance to the abandoned bend; (2) a deep scour hole in the downstream meander limb immediately downstream of the cutoff channel; (3) erosion of the bank opposite the cutoff in the downstream meander limb; (4) a cutoff bar in the downstream meander limb at the junction corner of the cutoff channel and the downstream meander limb; and (5) perching of the exit of the abandoned bend above the cutoff channel due to channel bed incision. The results presented herein were used to develop a conceptual model that depicts the morphologic evolution of highly curving neck cutoffs. The findings of this research are combined with recent analyses of the three-dimensional flow structure through neck cutoffs to provide a mechanistic explanation for the morphodynamics of neck cutoffs. © 2019 John Wiley & Sons, Ltd.