Geochemical and Nd‐Sr‐Pb isotopic evidence on the origin and geodynamic evolution of mid‐Cretaceous continental arc volcanic rocks of the Spences Bridge Group,south‐central British Columbia

The mid‐Cretaceous Spences Bridge Group (SBG) comprises a series of basaltic to rhyolitic lavas and related volcaniclastic rocks (Pimainus Formation) overlain by a succession of mainly amygdaloidal andesites (Spius Formation) related to the closure of the Methow–Tyaughton basin and accretion of the Insular terrane in the North American Cordillera. Geochemical variation in the SBG is related primarily to metasomatic processes in the mantle wedge. Pimainus lavas include low‐ to high‐K, tholeiitic and calc‐alkaline types, and have isotopic compositions (ε_Nd(100Ma) = + 5.2 to + 7.0, ε_Sr(100Ma) = − 10 to − 20, ²⁰⁶Pb/²⁰⁴Pb = 18.82 to 18.91, ²⁰⁷Pb/²⁰⁴Pb = 15.55 to 15.60, ²⁰⁸Pb/²⁰⁴Pb = 38.24 to 38.43) between the ranges for primitive arcs and accreted terrane crust. Crustal sources are identified only for some low–medium K dacite and rhyolite compositions. The occurrence of intermediate compositions with high MgO contents (up to 6 wt%) and the presence of adakitic trace element features in medium–high K felsic lavas attests to metasomatism of the mantle wedge by slab melts during Pimainus volcanism. Spius lavas have comparable K₂O and Pb isotopic compositions to the Pimainus, even higher MgO (up to 9.2 wt%), and display a mild intraplate character in having up to 0.6 wt% P₂O₅, 15 ppm Nb, and 240 ppm Zr. Spius Nd−Sr isotopic compositions (ε_Nd(100Ma) = + 5.3 to + 6.9, ε_Sr(100Ma) = − 14 to − 25) define an array extending from Pimainus to alkaline seamount compositions. The low ε_Sr values, elevated high field strength element contents, and moderate silica contents suggest Spius volcanism was related to the introduction of small melt fractions from the asthenosphere into the mantle wedge which had previously generated Pimainus melts. The range of compositional types in the Pimainus Formation constrains tectonic scenarios to include an elevated slab thermal regime, likely from approach of an ocean ridge system toward the continental margin. Spius volcanism may have been generated by asthenospheric upwelling triggered by slab window development or slab‐hinge roll‐back on closure of the Methow–Tyaughton basin. Copyright © 2002 John Wiley & Sons, Ltd.     

Estimating the size and travel distance of Klapperhorn Mountain debris flows for risk analysis along railway, Canada

Debris flows occurring on Klapperhorn Mountain in the Yellowhead Pass in the Canadian Rocky Mountains pose a significant hazard to railway operations at the base of the mountain. The size （volume） and travel distance of these debris flows play an important role in assessing the risk to the railway. GIS analysis, airphoto interpretation together with field work were undertaken on two debris flows located at track mileage 54.0 and 54.3. Characteristics of these two debris flow events were analyzed, including debris flow path morphology and event behavior. Their sizes and travel distances were estimated using an empirical-statistical model （UBCDFLOW） under different initiation conditions. Their potential impact on the railway bridge was evaluated using a bridge blockage ratio.     

Long-term trends in chloride concentrations in shallow aquifers near Chicago

The rapid expansion of major cities throughout the world is resulting in the degradation of water quality in local aquifers. Increased use of road deicers since the middle of the 20th century in cities in the northern United States, Canada, and Europe has been linked to degraded ground water quality. In this article, Chicago, Illinois, and its outlying suburban areas are used as an example of the effects of urbanization in a historical context. A statistical study of historical water quality data was undertaken to determine how urbanization activities have affected shallow (<60 m) ground water quality. Chloride (Cl⁻) concentrations have been increasing, particularly in counties west and south of Chicago. In the majority of shallow public supply wells in the western and southern counties, Cl⁻ concentrations have been increasing since the 1960s. About 43% of the wells in these counties have rate increases greater than 1 mg/L/year, and 15% have increases greater than 4 mg/L/year. Approximately 24% of the samples collected from public supply wells in the Chicago area in the 1990s had Cl⁻ concentrations greater than 100 mg/L (35% in the western and southern counties); median values were less than 10 mg/L before 1960. The greater increase in Cl⁻ concentrations in the outer counties is most likely due to both natural and anthropogenic factors, including the presence of more significant and shallower sand and gravel deposits, less curbing of major highways and streets, and less development in some parts of these counties.     

Multivariate analyses of water chemistry: surface and ground water interactions

Multivariate statistical methods (MSMs) applied to ground water chemistry provide valuable insight into the main hydrochemical species, hydrochemical processes, and water flowpaths important to ground water evolution. The MSMs of principal component factor analysis (FA) and k-means cluster analysis (CA) were sequentially applied to major ion chemistry from 211 different ground water-sampling locations in the Amargosa Desert. The FA reduces the number of variables describing the system and finds relationships between major ions. The CA of the reduced system produced objective hydrochemical facies, which are independent of, but in good agreement with, lithological data. The derived factors and hydrochemical facies are innovatively presented on biplots, revealing composition of hydrochemical processes and facies, and overlaid on a digital elevation model, displaying flowpaths and interactions with geologic and topographic features in the region. In particular, a distinct ground water chemical signature is observed beneath and surrounding the extended flowpath of Fortymile Wash, presenting some contradiction to contemporary water levels along with potential interaction with a fault line. The signature surrounding the ephemeral Fortymile Wash is believed to represent the relic of water that infiltrated during past pluvial periods when the amount of runoff in the wash was significantly larger than during the current drier period. This hypothesis and aforementioned analyses are supported by the examination of available chloride, oxygen-18, hydrogen-2, and carbon-14 data from the region.     

Laboratory simulation of the physical processes occurring on and near the surfaces of comet nuclei

Abstract— Laboratory comet simulation experiments are discussed in the context of theoretical models and recent ground-based and spacecraft observations, especially the Giotto observations of P/Halley. The set-up of various comet simulation experiments is reviewed. A number of small-scale experiments have been performed in many laboratories since the early 1960s. However, the largest and most ambitious series of experiments were the comet simulation experiments known as KOSI (German = Kometen Simulation). These experiments were prompted by the appearance of Comet P/Halley in 1986 and in planning for the European Space Agency's Rossetta mission that was originally scheduled to return samples. They were performed between 1987 and 1993 using the German Space Agency's (DLR) space hardware testing facilities in Cologne. As with attempts to reproduce any natural phenomenon in the laboratory, there are deficiencies in such experiments while there are major new insights to be gained. Simulation experiments have enabled the development of methods for making comet analogues and for exploring the properties of such materials in detail. These experiments have provided new insights into the morphology and physical behavior of aggregates formed from silicate grains likely to exist in comets. Formation of a dust mantle on the surfaces and a system of ice layers below the mantle caused by chemical differentiation have been identified after the insolation of the artificial comet. The mechanisms for heat transfer between the comet's surface and its interior, the associated gas diffusion from the interior of the surface, and compositional, structural, and isotopic changes that occur near the surface have been described by modeling the experimental results. The mechanisms of the ejection of dust and ice grains from the surface and the importance of gas-drag in propelling grains have also been explored.     

Separation of shoreline change signal from random noise

Investigation of shoreline change signals in the presence of possible non-stationarity is attempted via Karhunen–Loeve filtering to separate the actual shoreline signal change from that of random noise. Interpretation is made of the signal and noise normalized covariance and spectra to help in delineating natural change versus man-made change patterns for a section of shoreline where a navigation channel existed over a portion of the shoreline history.     

Longshore sediment transport via littoral drift rose

The littoral drift rose (LDR) concept is presented herein for improvement in understanding of longshore sediment transport and consequent shoreline processes in areas with smooth (gradually varying) offshore bathymetry extending over a coastal region where the deep water wave climate is reasonably uniform. The concept of the littoral drift rose (LDR) is presented and LDRs are shown to provide insight into coastal evolution and shoreline stability (or instability) for a given region having uniform wave climate. This paper reviews earlier documented applications and work using LDRs and provides an interpretation of earlier findings of shoreline stability using LDRs. Previously known but undocumented findings are also discussed herein which show that the wave climate and hence the LDR can be synthesized into an equivalent LDR developed from one wave component of given magnitude and direction. Practical applications using LDRs are presented, which show that the magnitude and direction of littoral drift throughout a region can be interpreted from limited measured, calculated, or observed data on littoral drift at two locations in the region.     

Mechanisms of ringwoodite formation in shocked meteorites: Evidence from L5 chondrite Dhofar 1970

The formation of the high‐pressure compositional equivalents of olivine and pyroxene has been well‐documented within and surrounding shock‐induced veins in chondritic meteorites, formed by crystallization from a liquid‐ or solid‐state phase transformation. Typically polycrystalline ringwoodite grains have a narrow range of compositions that overlap with those of their olivine precursors, whereas the formation of iron‐enriched ringwoodite has been documented from only a handful of meteorites. Here, we report backscattered electron images, quantitative wavelength‐dispersive spectrometry (WDS) analyses, qualitative WDS elemental X‐ray maps, and micro‐Raman spectra that reveal the presence of Fe‐rich ringwoodite (Fa_44‐63) as fine‐grained (500 nm), polycrystalline rims on olivine (Fa_24‐25) wall rock and as clasts engulfed by shock melt in a previously unstudied L5 chondrite, Dhofar 1970. Crystallization of majorite + magnesiowüstite in the vein interior and metastable mineral assemblages within 35 μm of the vein margin attest to rapid crystallization of a superheated shock melt (>2300 K) from 20─25 GPa to ambient pressure and temperature. The texture and composition of bright polycrystalline ringwoodite rims (Fa_44‐63; MnO 0.01─0.08 wt%) surrounding dark polycrystalline olivine (Fa_8‐14; MnO 0.56─0.65 wt%) implies a solid‐state transformation mechanism in which Fe was preferentially partitioned to ringwoodite. The spatial association between ringwoodite and shock melt suggests that the rapidly fluctuating thermal regimes experienced by chondritic minerals in contact with shock melt are necessary to both drive phase transformation but also to prevent back‐transformation.