Metamorphism and aqueous alteration in low petrographic type ordinary chondrites

Abstract— In order to investigate the relative importance of dry metamorphism and aqueous alteration in the history of chondrules, chondrules were hand-picked from the Semarkona (petrographic type 3.0), Bishunpur (3.1), Chainpur (3.4), Dhajala (3.8) and Allegan (5) chondrites, and matrix samples were extracted from the first three ordinary chondrites. The thermoluminescence (TL) properties of all the samples were measured, and appropriate subsets of the samples were analyzed by electron-microprobe and radiochemical neutron activation and the water and H-isotopic composition determined. The TL data for chondrules from Semarkona and Bishunpur scatter widely showing no unambiguous trends, although group B1 chondrules tend to have lower sensitivities and lower peak temperatures compared with group A5 chondrules. It is argued that these data reflect the variety of processes accompanying chondrule formation. The chondrules show remarkably uniform contents of the highly labile elements, indicating mineralogical control on abundance and volatile loss from silicates and loss and recondensation of mobile chalcophiles and siderophiles in some cases. Very high D/H values (up to ～8000‰ SMOW) are observed in certain Semarkona chondrules, a confirmation of earlier work. With increasing petrographic type, mean TL sensitivities of the chondrules increase, the spread of values within an individual meteorite decreases, and peak temperatures and peak widths show trends indicating that the TL is mainly produced by feldspar and that dry, thermal metamorphism is the dominant secondary process experienced by the chondrules. The TL sensitivities of matrix samples also increase with petrographic type. Chainpur matrix samples show the same spread of peak temperatures and peak widths as Chainpur chondrules, indicating metamorphism-related changes in the feldspar are responsible for the TL of the matrix. The TL data for the Semarkona and Bishunpur matrix samples provide, at best, only weak evidence for aqueous alteration, but the matrix contains H with approximately terrestrial D/H values, even though it contains much water. Secondary processes (probably aqueous alteration) presumably lowered the D/H of the matrix and certain chondrules. While chondrule properties appear to be governed primarily by formation processes and subsequent metamorphism, the matrix of Semarkona has a more complex history involving aqueous alteration as a meteorite-wide process.     

Spatial variability of mercury emissions from soils in a southeastern US urban environment

We quantified gaseous mercury (Hg⁰) fluxes over soil surfaces in an urban setting during the winters of 2003 and 2004 across the metropolitan area of Tuscaloosa, AL. The objective was to provide a first inspection of the local spatial variability of mercury flux in an urban area. Flux sampling took place on bare, undisturbed, soil surfaces within four evenly spaced landuse areas of Tuscaloosa: industrial, commercial, residential, and mixed landuse. Median total gaseous mercury fluxes (ng/m² h) from each site were as follows: 4.45 (residential site), 1.40 (industrial site), 2.14 (commercial site), and 0.87 (mixed landuse site). Using non-parametric statistical analyses, the residential and mixed landuse sites were found to be statistically different from the overall median flux. Landuse and soil type are the suspected factors primarily controlling the observed spatially variable fluxes. The presence of statistically different fluxes over soil surfaces on a local scale in this preliminary study warrants additional investigation, particularly during the spring and summer seasons when terrestrial mercury emission is the highest. Providing such information will help develop better estimates of mercury emission from urban areas and, ultimately, lead to more accurate and useful spatially relevant inventories.     

Palaeoseismology in steep terrain: The Big Bend of the San Andreas fault, Transverse Ranges, California

Transpressional tectonics are typically associated with restraining bends on major active strike-slip faults, resulting in uplift and steep terrain. This produces dynamic erosional and depositional conditions and difficulties for established lines of palaeoseismological investigation. Consequently, in these areas data are lacking to determine tectonic behaviour and future hazard potential along these important fault segments. The Big Bend of the San Andreas fault in the Transverse Ranges of southern California exemplifies these problems. However, landslides, probably seismically triggered, are widespread in the rugged terrain of the Big Bend. Fluvial reworking of these deposits rapidly produces geomorphic planes and lines that are markers for subsequent fault slip. The most useful are offset and abandoned stream channels, for these are relatively high precision markers for identifying individual faulting events. Palaeoseismological studies from the central Big Bend, involving ¹⁴C ages of charcoal fragments from trench exposures, illustrate these points and indicate that the past three faulting events, including the great 1857 earthquake, were relatively similar in scale, each producing offsets of about 7–7.5 m. The mean recurrence interval is 140–220 years. The pre-1857 event here may be the 1812 event documented south of the Big Bend or an event which took place probably between 1630 and 1690. Ground breakage in both events extended south of the Big Bend, unlike the 1857 event where rupture was skewed to the north. The preceding faulting event ruptured both to the north and south of the Big Bend and probably occurred between 1465 and 1495. All these events centred on the Big Bend and may be typical for this fault segment, suggesting that models of uniform long-term slip rates may not be applicable to the south-central San Andreas. A slip-rate estimate of 34–51 mm a^{− 1} for the central Big Bend, although uncertain, may also imply higher slip in the Big Bend and highlights difficulties in correlating slip-rates between sites with different tectonic settings. Slip rates on the San Andreas may increase within the broad compressional tectonics zone of the Big Bend, compared to the north and south where the plate boundary is a relatively linear and sub-parallel series of dominantly strike-slip faults. Partitioning slip within the Big Bend is inherently uncertain and insufficient suitably comparable data are available to sustain a uniform slip model, although such models are a common working assumption.     

A record of Holocene climate change from lake geochemical analyses in southeastern Arabia

Lacustrine sediments from southeastern Arabia reveal variations in lake level corresponding to changes in the strength and duration of Indian Ocean Monsoon (IOM) summer rainfall and winter cyclonic rainfall. The late glacial/Holocene transition of the region was characterised by the development of mega-linear dunes. These dunes became stabilised and vegetated during the early Holocene and interdunal lakes formed in response to the incursion of the IOM at approximately 8500 cal yr BP with the development of C3 dominated savanna grasslands. The IOM weakened ca. 6000 cal yr BP with the onset of regional aridity, aeolian sedimentation and dune reactivation and accretion. Despite this reduction in precipitation, the lake was maintained by winter dominated rainfall. There was a shift to drier adapted C4 grasslands across the dune field. Lake sediment geochemical analyses record precipitation minima at 8200, 5000 and 4200 cal yr BP that coincide with Bond events in the North Atlantic. A number of these events correspond with changes in cultural periods, suggesting that climate was a key mechanism affecting human occupation and exploitation of this region.     

Thermoluminescence and the shock and reheating history of meteorites—II: Annealing studies of the Kernouve meteorite

Samples of the unshocked, equilibrated chondrite, Kernouve (H6), have been annealed for 1–100 hours at 500–1200°C, their thermoluminescence sensitivity measured and Na, K, Mn, Ca and Sc determined by instrumental neutron activation analysis. The TL sensitivity decreased with temperature until by 1000°C it had fallen by 40%. The process responsible has an activation energy of ~8 kcal/mole and probably involves diffusion. Samples annealed 1000–1200°C had TL sensitivities 10^?2 times the unannealed values, most of the decrease occurring ~1100°C. This process has an activation energy of ~100 kcal/mole and is probably related to the melting of the TL phosphor, feldspar, with some decomposition and loss of Cs, Na and K. Meteorites whose petrography indicates healing > 1100°C by natural shock heating events (shock facies d-f). have TL sensitivities similar to samples annealed > 1100°C. Our own and literature compositional data indicate that TL is more stable to annealing than Ag, In, Tl, Bi, Zn and Te and less stable than Na, K, Mn, Ca, Se and Co, while the TL decrease resembles very closely the pattern of Cs loss on annealing.