Solar and Heliospheric Observatory/Large Angle Spectrometric Coronagraph Polarimetric Calibration

We present a polarimetric characterization and correction for the Solar and Heliospheric Observatory/Large Angle Spectrometric Coronagraph (SOHO/LASCO) C2 and C3 white light coronagraphs. By measuring the uncorrected polarization angles in solar minimum C2 coronal images, we have determined that the coronagraph acts as an optical phase retarder which converts a small fraction of the incoming radiation polarization from linear to circular. In addition, from the measurements of polarization angle in C3 coronal images we have determined that a component of the instrumentally scattered light in that instrument is polarized. We infer the retardation angle for C2 and compute the corresponding Mueller matrix, and determine the polarized stray light spatial profile in C3. The C2 Mueller matrix and C3 polarized stray light profiles are used to correct for instrumental effects in solar minimum coronal observations to obtain polarized brightness between two and thirty-two solar radii, which show deep polar coronal holes extending to the limit of the field of view.     

Venus phase function and forward scattering from H2SO4

Ground-based and spacecraft photometry covering phase angles from 2° to 179° has been acquired in wavelength bands from blue to near infrared. An unexpected brightness surge is seen in the B and V bands when the disk of Venus is less than 2% illuminated. This excess luminosity appears to be the result of forward scattering from droplets of H₂SO₄ (sulfuric acid) in the high atmosphere of Venus. The fully sunlit brightness of Venus, adjusted to a distance of one AU from the Sun and observer, was found to be V=−4.38, and the corresponding geometric albedo is 67%. The phase integral is 1.35 and the resulting spherical albedo is 90%. Comparison between our data and photometry obtained over the past 50 years indicates a bias in the older photoelectric results, however atmospheric abundance variations suggest that brightness changes may have occurred too.     

Pleistocene fluvial sediments,palaeontology and archaeology of the upper River Thames at Latton,Wiltshire, England

Pleistocene fluvial sediments of the Northmoor Member of the Upper Thames Formation exposed at Latton, Wiltshire, record episodic deposition close to the Churn–Thames confluence possibly spanning the interval from Marine Isotope Stages (MIS) 7 to 2. The sequence is dominated by gravel facies, indicating deposition by a high‐energy, gravel‐bed river. A number of fine‐grained organic sediment bodies within the sequence have yielded palaeoenvironmental and biostratigraphical data from Mollusca, Coleoptera, vertebrates, pollen and plant macrofossils. The basal deposit (Facies Association A) contains faunal material indicating temperate conditions. Most of the palaeontological evidence including a distinctive small form of mammoth (Mammuthus cf. trogontherii), together with the U‐series age estimate of >147.4 ± 20 kyr suggest correlation with MIS 7. The overlying deposits (Facies Associations B and C) represent deposition under a range of climatic conditions. Two fine‐grained organic deposits occurred within Association B; one (Association Ba) in the northern part of the pit as a channel fill and the other (Association Bb) in its southern part as a scour‐fill deposit. The coleopteran assemblages from Ba, indicate that it accumulated under temperate oceanic conditions, while Bb, which also yielded a radiocarbon age estimate of 39 560 ± 780 ¹⁴C yr BP, was formed under much colder and more continental climatic conditions. The sequence is considered to represent deposition within an alluvial fan formed at the Churn–Thames confluence; a depositional scenario which may account for the juxtaposition of sediments and fossils of widely differing age within the same altitudinal range. Copyright © 2006 John Wiley & Sons, Ltd.     

Evaluation of extraction schemes for organic matter in anoxic estuarine sediments

A persistent criticism of studies of organic matter in sediments and soils has been that the extracted products used in these investigations may not resemble the original material, particularly if harsh extractants such as NaOH, Na₄P₂O₇ or HCl are employed. To minimize chemical changes, a mild separation procedure has been developed for obtaining soluble organic matter from anoxic estuarine sediments. The resulting complex mixture of organic compounds can be analyzed by reversed-phase liquid and size-exclusion chromatographic methods, which monitor the relative molecular polarity and size, respectively. The effects of the strong reagents NaOH, Na₄P₂O₇ and HCl, as well as exposure to the atmosphere and bacterial activity on this anoxic sedimentary extract has been investigated. In each instance, significant degradation of anoxic organic matter occurs, producing molecules of increased polarity and reduced molecular weight. These data indicate that extreme care is necessary to avoid artifacts in preparation and handling of samples.     

Development of a Multimetric Index for Integrated Assessment of Salt Marsh Ecosystem Condition

Tools for assessing and communicating salt marsh condition are essential to guide decisions aimed at maintaining or restoring ecosystem integrity and services. Multimetric indices (MMIs) are increasingly used to provide integrated assessments of ecosystem condition. We employed a theory-based approach that considers the multivariate relationship of metrics with human disturbance to construct a salt marsh MMI for five National Parks in the northeastern USA. We quantified the degree of human disturbance for each marsh using the first principal component score from a principal components analysis of physical, chemical, and land use stressors. We then applied a metric selection algorithm to different combinations of about 45 vegetation and nekton metrics (e.g., species abundance, species richness, and ecological and functional classifications) derived from multi-year monitoring data. While MMIs derived from nekton or vegetation metrics alone were strongly correlated with human disturbance (r values from ?0.80 to ?0.93), an MMI derived from both vegetation and nekton metrics yielded an exceptionally strong correlation with disturbance (r = ?0.96). Individual MMIs included from one to five metrics. The metric-assembly algorithm yielded parsimonious MMIs that exhibit the greatest possible correlations with disturbance in a way that is objective, efficient, and reproducible.     

Scientists' warning on extreme wildfire risks to water supply

2020 is the year of wildfire records. California experienced its three largest fires early in its fire season. The Pantanal, the largest wetland on the planet, burned over 20% of its surface. More than 18 million hectares of forest and bushland burned during the 2019–2020 fire season in Australia, killing 33 people, destroying nearly 2500 homes, and endangering many endemic species. The direct cost of damages is being counted in dozens of billion dollars, but the indirect costs on water-related ecosystem services and benefits could be equally expensive, with impacts lasting for decades. In Australia, the extreme precipitation (“200 mm day −1 in several location”) that interrupted the catastrophic wildfire season triggered a series of watershed effects from headwaters to areas downstream. The increased runoff and erosion from burned areas disrupted water supplies in several locations. These post-fire watershed hazards via source water contamination, flash floods, and mudslides can represent substantial, systemic long-term risks to drinking water production, aquatic life, and socio-economic activity. Scenarios similar to the recent event in Australia are now predicted to unfold in the Western USA. This is a new reality that societies will have to live with as uncharted fire activity, water crises, and widespread human footprint collide all-around of the world. Therefore, we advocate for a more proactive approach to wildfire-watershed risk governance in an effort to advance and protect water security. We also argue that there is no easy solution to reducing this risk and that investments in both green (i.e., natural) and grey (i.e., built) infrastructure will be necessary. Further, we propose strategies to combine modern data analytics with existing tools for use by water and land managers worldwide to leverage several decades worth of data and knowledge on post-fire hydrology.     

Objective definition of rainfall intensity–duration thresholds for the initiation of post-fire debris flows in southern California

Rainfall intensity–duration (ID) thresholds are commonly used to predict the temporal occurrence of debris flows and shallow landslides. Typically, thresholds are subjectively defined as the upper limit of peak rainstorm intensities that do not produce debris flows and landslides, or as the lower limit of peak rainstorm intensities that initiate debris flows and landslides. In addition, peak rainstorm intensities are often used to define thresholds, as data regarding the precise timing of debris flows and associated rainfall intensities are usually not available, and rainfall characteristics are often estimated from distant gauging locations. Here, we attempt to improve the performance of existing threshold-based predictions of post-fire debris-flow occurrence by utilizing data on the precise timing of debris flows relative to rainfall intensity, and develop an objective method to define the threshold intensities. We objectively defined the thresholds by maximizing the number of correct predictions of debris flow occurrence while minimizing the rate of both Type I (false positive) and Type II (false negative) errors. We identified that (1) there were statistically significant differences between peak storm and triggering intensities, (2) the objectively defined threshold model presents a better balance between predictive success, false alarms and failed alarms than previous subjectively defined thresholds, (3) thresholds based on measurements of rainfall intensity over shorter duration (≤60 min) are better predictors of post-fire debris-flow initiation than longer duration thresholds, and (4) the objectively defined thresholds were exceeded prior to the recorded time of debris flow at frequencies similar to or better than subjective thresholds. Our findings highlight the need to better constrain the timing and processes of initiation of landslides and debris flows for future threshold studies. In addition, the methods used to define rainfall thresholds in this study represent a computationally simple means of deriving critical values for other studies of nonlinear phenomena characterized by thresholds.     

A preliminary methods comparison for measurement of dissolved organic nitrogen in seawater

Routine determination of dissolved organic nitrogen (DON) is performed in numerous laboratories around the world using one of three families of methods: UV oxidation (UV), persulfate oxidation (PO), or high temperature combustion (HTC). Essentially all routine methods measure total dissolved nitrogen (TDN) and calculate DON by subtracting the dissolved inorganic nitrogen (DIN). While there is currently no strong suggestion that any of these methods is inadequate, there are continuing suspicions of slight inaccuracy by UV methods.This is a report of a broad community methods comparison where 29 sets (7 UV, 13 PO, and 9 HTC) of TDN analyses were performed on five samples with varying TDN and DIN concentrations. Analyses were done in a “blind” procedure with results sent to the first author. With editing out one set of extreme outliers (representing 5 out of 145 ampoules analyzed), the community comparability for analyzing the TDN samples was in the 8–28% range (coefficient of variation representing one standard deviation for the five individual samples by 28 analyses). When DIN concentrations were subtracted uniformly (single DIN value for each sample), the comparability was obviously worse (19–46% cv). This comparison represents a larger and more diverse set of analyses, but the overall comparability is only marginally better than that of the Seattle workshop of a decade ago. Grouping methods, little difference was seen other than inconclusive evidence that the UV methods gave TDN values for several of the samples higher than HTC methods. Since there was much scatter for each of the groups of methods and for all analyses when grouped, it is thought that more uniformity in procedures is probably needed. An important unplanned observation is that variability in DIN analyses (used in determining the final analyte in most UV and PO methods) is essentially as large as the variability in the TDN analyses.This exercise should not be viewed as a qualification exercise for the analysts, but should instead be considered a broad preliminary test of the comparison of the families of methods being used in various laboratories around the world. Based on many independent analyses here, none of the routinely used methods appears to be grossly inaccurate, thus, most routine TDN analyses being reported in the literature are apparently accurate. However, it is not reassuring that the ability of the international community to determine DON in deep oceanic waters continues to be poor. It is suggested that as an outgrowth of this paper, analysts using UV and PO methods experiment and look more carefully at the completeness of DIN conversion to the final analyte and also at the accuracy of their analysis of the final analyte. HTC methods appear to be relatively easy and convenient and have potential for routine adoption. Several of the authors of this paper are currently working together on an interlaboratory comparison on HTC methodology.     

Surface age of the ice–dust mantle deposit in Malea Planum,Mars

The mid- and high-latitudes of Mars are covered by a smooth young mantle that is interpreted as an atmospherically derived air-fall deposit of ice and dust related to recent climate changes. In order to determine relative and absolute ages of this surface unit within the southern hemisphere, a systematic survey of all available HiRISE and CTX images in the Malea Planum region from 55–60°S latitude and 50–70°E longitude was performed and the distribution and the morphology of small impact craters on the mantle deposit were investigated. Using crater size-frequency measurements, we derived absolute model ages of ～3–5 Ma for the surface of the mantle, immediately south of the Hellas basin rim. Morphologic observations of the mantle, its fresh appearance, very low number of craters, and superposition on older units support this very young Amazonian age. Nearly all observed craters on the smooth mantle in Malea Planum are small and show signs of erosion, evidence for the ongoing modification of the ice–dust mantle. However, this modification has not been strong enough to reset the surface age. Compared to the ice–dust mantle at higher latitudes in the northern and southern hemisphere, the surface of the mantle in Malea Planum is older and thus has been relatively stable during obliquity changes in the last ～3–5 Ma. This is consistent with the hypothesis that the ice–dust mantle is a complex surface deposit of different layers, that shows a strong latitude dependence in morphology and has been deposited and degraded at different times in martian history.