Strong hydrographic controls on spatial and seasonal variability of dissolved organic carbon in the Chukchi Sea

A detailed analysis of dissolved organic carbon (DOC) distribution in the Western Arctic Ocean was performed during the spring and summer of 2002 and the summer of 2003. DOC concentrations were compared between the three cruises and with previously reported Arctic work. Concentrations of DOC were highest in the surface water where they also showed the highest degree of variability spatially, seasonally, and annually. Over the Canada Basin, DOC concentrations in the main water masses were: (1) surface layer (71±4 μM, ranging from 50 to 90 μM); (2) Bering Sea winter water (66±2 μM, ranging from 58 to 75 μM); (3) halocline layer (63±3 μM, ranging from 59 to 68 μM), (4) Atlantic layer (53±2 μM, ranging from 48 to 57 μM), and (5) deep Arctic layer (47±1 μM, ranging from 45 to 50 μM). In the upper 200 m, DOC concentrations were correlated with salinity, with higher DOC concentrations present in less-saline waters. This correlation indicates the strong influence that fluvial input from the Mackenzie and Yukon Rivers had on the DOC system in the upper layer of the Chukchi Sea and Bering Strait. Over the deep basin, there appeared to be a relationship between DOC in the upper 10 m and the degree of sea-ice melt water present. We found that sea-ice melt water dilutes the DOC signal in the surface waters, which is contrary to studies conducted in the central Arctic Ocean.     

Isotopic and biochemical composition of particulate organic matter in a shallow water estuary (Great Ouse, North Sea, England)

The biogeochemistry of particulate organic matter was studied in the Great Ouse estuary draining to the North Sea embayement known as the Wash from March 1990 to January 1991. Eleven locations were sampled monthly on a 50 km transect across the shallow estuary from the tidal weir to the middle of the Wash. Particulate organic carbon (POC) and total carbohydrate, protein and lipid analyses were combined with the determination of stable carbon isotopes. δ¹³C often increased from −30‰ in the river to −22‰ in the tidal freshwater reach. The mixing zone between fresh and marine tidal waters displayed only a slight increase in δ¹³C to −19‰. The change in δ¹³C values in the freshwater tidal reach demonstrated that mixing of riverborne and marine suspended POC was not the only process affecting the carbon stable isotope composition. Complementary sources, interfering considerably with the two end-member sources, may be identified as autocthonous primary production and resuspension of sediment that may be transported upstream. The respective importance of these sources is subject to seasonal variation. From March to August, high concentrations in carbohydrate and protein through the whole estuary indicate that despite turbidity significant primary production occurred. The proportional importance of the uncharacterized fraction of POC, which is considered as complex organic matter, was high from September to January and low from March to August. During most of the year, the biochemical compositions of particulate organic matter in the turbidity maximum and the rest of the estuary were similar. This contradicted the principle that owing to the long residence times of particles degradation processes largely dominate the production processes within the turbidity maximum. The occurence of significant in situ production in such shallow water estuaries may partially compensate for the degradation of suspended particulate organics, resulting in a complex relationship between the biogeochemical cycling and the fate of nutrients.     

Evidence for frost on Rhea's surface

We have observed Rhea (S5) at 1.6 μm and 2.2 μm at Mt. Wilson using the Caltech photometer on the 1.52m and 2.54m telescopes. The infrared spectral reflectances relative to 0.55μm are 0.8 (±0.1 p.e.) at 1.65μm and 0.6 (±0.1 p.e.) at 2.2μm. Such absorption bands in the near infrared are not consistent with spectra of most rocks or minerals; even carbonaceous chondritic materials have nearly flat reflectances over this spectral region. Frosts, however, have strong absorption bands in the 1–3μm region. In particular, the broadband infrared reflectances of Rhea are similar to those of the Galilean satellites Europa (J2) and Ganymede (J3) and also the rings of Saturn (all of which are known from high resolution scans to have water frosts on their surfaces). The broadband photometry does not have sufficient resolution to identify the frost species: but Rhea's low density, high albedo and relatively flat reflectance from 0.3μm to 1.1μm as well as the low infrared reflectances reported here are consistent with the presence of water ice on Rhea's surface.     

The reaction of montmorillonite to mixed-layer clay: the effect of interlayer alkali and alkaline earth cations

The Wyoming bentonite was saturated with alkali and alkaline earth cations and allowed to react hydrothermally for one month at 300°C, and one week and one month at 400°C. Generally, the rate of formation of collapsed layers for the alkali clays was inversely related to interlayer hydration energy. This pattern of reaction is expected if layer dehydration results from an attraction between negatively charged 2:1 layers and the positive interlayer cation. In this mechanism, the greater the hydration energy of the interlayer region, the greater the charge that must develop on the 2:1 layers to cause dehydration, and, therefore, the slower the reaction rate. Reaction rate for the alkaline earth clays was directly related to interlayer hydration energy. Clays saturated with cations of hydration energy equal to or greater than Na⁺ did not react at 300°C, and ceased to react at 50% expandable layers at 400°C. Those saturated with cations of lower hydration energy continued to form mica-like layers with increasing run time at both 300° and 400°C. Clays saturated with monovalent cations reacted by a process of gradual transformation of smectite layers into collapsed layers, whereas those with divalent cations reacted directly from the smectite structure to form a rectorite-like phase.     

The natural basis of the formation of the dual-nuclei structural model

The dual-nuclei spatial structure is composed of a regional central city, a port city and their spatial relations in certain regions. In general, this spatial structure could be found in most of the coastal regions or regions along big rivers. In terms of the mechanism, the dual-nuclei structure is the result of the spatial interaction and the complementary characteristics of the center city and the port city. The "marginal function" of the port city and its relationship with the central city has long been discussed in the literature. On the one hand, drainage area is the main natural geographical background of the formation of the dual-nuclei spatial structure; therefore, we can build a theoretical geographic structure that is based on the drainage area. On the other hand, vicissitude of the coastline also has important influence on the formation of the dual-nuclei spatial structure. It is especially meaningful if we can notice this when we examine deeply the research on the spatial structure of delta.     

Social Attitudes Predict Biases in Geographic Knowledge*

Three principal components were found to underlie Texas university students' experiences with and attitudes toward Canada, the United States, and Mexico: diversity orientation, Mexican experiences, and Canadian experiences. Diversity orientation included positive attitudes toward Hispanics, Canadians, minorities, interethnic friendships, and dating and was negatively correlated with natio‐centrism (e.g., believing U.S. citizens receive the world's best education). Diversity orientation and natio‐centrism were not related to experiences with Mexico or Canada. Students estimated the locations of Canadian cities too far north and Mexican cities too far south. Biased estimates for Mexican cities were negatively correlated with diversity orientation, not experience with Mexico.     

Evaluation of Hydrologically Relevant PCM Climate Variables and Large-Scale Variability over the Continental U.S.

The ability of the Parallel Climate Model (PCM) to reproduce the mean and variability of hydrologically relevant climate variables was evaluated by comparing PCM historical climate runs with observations over temporal scales from sub-daily to annual. The domain was the continental U.S, and the model spatial resolution was T42 (about 2.8 degrees latitude by longitude). The climate variables evaluated include precipitation, surface air temperature, net surface solar radiation, soil moisture, and snow water equivalent. The results show that PCM has a winter dry bias in the Pacific Northwest and a summer wet bias in the central plains. The diurnal precipitation variation in summer is much stronger than observed, with an afternoon maximum in summer precipitation over much of the U.S. interior, in contrast with an observed nocturnal maximum in parts of the interior. PCM has a cold bias in annual mean temperature over most of the U.S., with deviations as large as ?8 K. The PCM daily temperature range is lower than observed, especiallyin the central U.S. PCM generally overestimates the net solar radiation over most of the U.S, although the diurnal cycle is simulated well in spring, summer and winter. In autumn PCM has a pronounced noontime peak in solar radiation that differs by 5–10% from observations. PCM'ssimulated soil moisture is less variable than that of a sophisticated land-surface hydrology model, especially in the interior of the country. PCM simulates the wetter conditions over the southeastern U.S. and California during warm (El Niño) events, but shifts the drier conditions in the PacificNorthwest northward and underestimates their magnitude. The temperature response to the North Pacific Oscillation is generally captured by PCM, but the amplitude of this response is overestimated by a factor of about two.