A regional soil and sediment geochemical study in northern California

Regional-scale variations in soil geochemistry were investigated in a 20,000-km² study area in northern California that includes the western slope of the Sierra Nevada, the southern Sacramento Valley and the northern Coast Ranges. Over 1300 archival soil samples collected from the late 1970s to 1980 in El Dorado, Placer, Sutter, Sacramento, Yolo and Solano counties were analyzed for 42 elements by inductively coupled plasma-atomic emission spectrometry and inductively coupled plasma-mass spectrometry following a near-total dissolution. These data were supplemented by analysis of more than 500 stream-sediment samples from higher elevations in the Sierra Nevada from the same study site. The relatively high-density data (1 sample per 15 km² for much of the study area) allows the delineation of regional geochemical patterns and the identification of processes that produced these patterns. The geochemical results segregate broadly into distinct element groupings whose distribution reflects the interplay of geologic, hydrologic, geomorphic and anthropogenic factors. One such group includes elements associated with mafic and ultramafic rocks including Cr, Ni, V, Co, Cu and Mg. Using Cr as an example, elevated concentrations occur in soils overlying ultramafic rocks in the foothills of the Sierra Nevada (median Cr = 160 mg/kg) as well as in the northern Coast Ranges. Low concentrations of these elements occur in soils located further upslope in the Sierra Nevada overlying Tertiary volcanic, metasedimentary and plutonic rocks (granodiorite and diorite). Eastern Sacramento Valley soil samples, defined as those located east of the Sacramento River, are lower in Cr (median Cr = 84 mg/kg), and are systematically lower in this suite compared to soils from the west side of the Sacramento Valley (median Cr = 130 mg/kg). A second group of elements showing a coherent pattern, including Ca, K, Sr and REE, is derived from relatively silicic rocks types. This group occurs at elevated concentrations in soils overlying volcanic and plutonic rocks at higher elevations in the Sierras (e.g. median La = 28 mg/kg) and the east side of the Sacramento Valley (median 20 mg/kg) compared to soils overlying ultramafic rocks in the Sierra Nevada foothills (median 15 mg/kg) and the western Sacramento Valley (median 14 mg/kg). The segregation of soil geochemistry into distinctive groupings across the Sacramento River arises from the former presence of a natural levee (now replaced by an artificial one) along the banks of the river. This levee has been a barrier to sediment transport. Sediment transport to the Valley by glacial outwash from higher elevations in the Sierra Nevada and, more recently, debris from placer Au mining has dominated sediment transport to the eastern Valley. High content of mafic elements (and low content of silicic elements) in surface soil in the west side of the valley is due to a combination of lack of silicic source rocks, transport of ultramafic rock material from the Coast Ranges, and input of sediment from the late Mesozoic Great Valley Group, which is itself enriched in mafic elements. A third group of elements (Zn, Cd, As and Cu) reflect the impact of mining activity. Soil with elevated content of these elements occurs along the Sacramento River in both levee and adjacent flood basin settings. It is interpreted that transport of sediment down the Sacramento River from massive sulfide mines in the Klamath Mountains to the north has caused this pattern. The Pb, and to some extent Zn, distribution patterns are strongly impacted by anthropogenic inputs. Elevated Pb content is localized in major cites and along major highways due to inputs from leaded gasoline. Zinc has a similar distribution pattern but the source is tire wear.     

Climate change impacts on water management in the Puget Sound region, Washington State, USA

Climate change is projected to result, on average, in earlier snowmelt and reduced summer flows in the Pacific Northwest, patterns not well represented in historical observations used in water planning. We evaluate the sensitivities of water supply systems in the Puget Sound basin cities of Everett, Seattle, and Tacoma to historical and projected future streamflow variability and water demands. We simulate streamflow for the 2020s, 2040s, and 2080s using the distributed hydrology–soil–vegetation model (DHSVM), driven by downscaled ensembles of climate simulations archived from the 2007 IPCC Fourth Assessment Report. We use these streamflow predictions as inputs to reservoir system models for the three water supply systems. Over the next century, under average conditions all systems are projected to experience declines and eventual disappearance of the springtime snowmelt peak. How these shifts affect management depends on physical characteristics, operating objectives, and the adaptive capacity of each system. Without adaptations, average seasonal drawdown of reservoir storage is projected to increase in all three systems throughout the 21st century. Reliability of all systems in the absence of demand increases is robust through the 2020s however, and remains above 98% for Seattle and Everett in the 2040s and 2080s. With demand increases, however, reliability of the systems in their current configurations and with current operating policies progressively declines through the century.     

Large-Eddy Simulation of Flow and Pollutant Transport in Urban Street Canyons with Ground Heating

Our study employed large-eddy simulation (LES) based on a one-equation subgrid-scale model to investigate the flow field and pollutant dispersion characteristics inside urban street canyons. Unstable thermal stratification was produced by heating the ground of the street canyon. Using the Boussinesq approximation, thermal buoyancy forces were taken into account in both the Navier–Stokes equations and the transport equation for subgrid-scale turbulent kinetic energy (TKE). The LESs were validated against experimental data obtained in wind-tunnel studies before the model was applied to study the detailed turbulence, temperature, and pollutant dispersion characteristics in the street canyon of aspect ratio 1. The effects of different Richardson numbers (Ri) were investigated. The ground heating significantly enhanced mean flow, turbulence, and pollutant flux inside the street canyon, but weakened the shear at the roof level. The mean flow was observed to be no longer isolated from the free stream and fresh air could be entrained into the street canyon at the roof-level leeward corner. Weighed against higher temperature, the ground heating facilitated pollutant removal from the street canyon.     

Climate and land cover effects on the temperature of Puget Sound streams

We apply an integrated hydrology‐stream temperature modeling system, DHSVM‐RBM, to examine the response of the temperature of the major streams draining to Puget Sound to land cover and climate change. We first show that the model construct is able to reconstruct observed historic streamflow and stream temperature variations at a range of time scales. We then explore the relative effect of projected future climate and land cover change, including riparian vegetation, on streamflow and stream temperature. Streamflow in summer is likely to decrease as the climate warms especially in snowmelt‐dominated and transient river basins despite increased streamflow in their lower reaches associated with urbanization. Changes in streamflow also result from changes in land cover, and changes in stream shading result from changes in riparian vegetation, both of which influence stream temperature. However, we find that the effect of riparian vegetation changes on stream temperature is much greater than land cover change over the entire basin especially during summer low flow periods. Furthermore, while future projected precipitation change will have relatively modest effects on stream temperature, projected future air temperature increases will result in substantial increases in stream temperature especially in summer. These summer stream temperature increases will be associated both with increasing air temperature, and projected decreases in low flows. We find that restoration of riparian vegetation could mitigate much of the projected summer stream temperature increases. We also explore the contribution of riverine thermal loadings to the heat balance of Puget Sound, and find that the riverine contribution is greatest in winter, when streams account for up to 1/8 of total thermal inputs (averaged from December through February), with larger effects in some sub‐basins. We project that the riverine impact on thermal inputs to Puget Sound will become greater with both urbanization and climate change in winter but become smaller in summer due to climate change. Copyright © 2016 John Wiley & Sons, Ltd.     

Global river discharge and water temperature under climate change

Climate change will affect hydrologic and thermal regimes of rivers, having a direct impact on freshwater ecosystems and human water use. Here we assess the impact of climate change on global river flows and river water temperatures, and identify regions that might become more critical for freshwater ecosystems and water use sectors. We used a global physically based hydrological-water temperature modelling framework forced with an ensemble of bias-corrected general circulation model (GCM) output for both the SRES A2 and B1 emissions scenario. This resulted in global projections of daily river discharge and water temperature under future climate. Our results show an increase in the seasonality of river discharge (both increase in high flow and decrease in low flow) for about one-third of the global land surface area for 2071–2100 relative to 1971–2000. Global mean and high (95th percentile) river water temperatures are projected to increase on average by 0.8–1.6 (1.0–2.2) °C for the SRES B1–A2 scenario for 2071–2100 relative to 1971–2000. The largest water temperature increases are projected for the United States, Europe, eastern China, and parts of southern Africa and Australia. In these regions, the sensitivities are exacerbated by projected decreases in low flows (resulting in a reduced thermal capacity). For strongly seasonal rivers with highest water temperatures during the low flow period, up to 26% of the increases in high (95th percentile) water temperature can be attributed indirectly to low flow changes, and the largest fraction is attributable directly to increased atmospheric energy input. A combination of large increases in river temperature and decreases in low flows are projected for the southeastern United States, Europe, eastern China, southern Africa and southern Australia. These regions could potentially be affected by increased deterioration of water quality and freshwater habitats, and reduced water available for human uses such as thermoelectric power and drinking water production.     

Network configurations and R&D activities of the ICT industry in Suzhou municipality, China

This paper analyzes the network structure and R&D activities of the information and communication technology (ICT) industry in Suzhou municipality, known previously for its local state-directed Sunan model of development. Suzhou, however, has been undergoing dramatic restructuring to remake itself into a globalizing production center. We highlight the significance of the Chinese state and local/regional assets in shaping the trajectories of globalization and regional development, and the increasing importance of domestic markets and regional clusters/agglomeration for foreign ventures. We have found that Suzhou’s development path, heavily dependent on external forces, has made Suzhou a TNC (transnational corporation) satellite district. We also find that the ICT industry in Suzhou has a dual-structure, segmented between foreign-invested enterprises (FIEs) and domestic firms. TNCs tend to network among themselves and their interfirm networks are increasingly domestic and regionally embedded in the Yangtze River Delta, while the linkages between TNCs and local firms are weak. We argue that there is a series of technological, structural, spatial, and institutional “mismatches” that limits the establishment of “global pipelines” of knowledge exchange. We hold that the nature of global-local networks is contingent upon regional endogenous capacities and the specific ways in which global capital interacts with local institutions. Therefore, perspectives on TNCs’ local embeddedness must be positioned in their regional/external networks. We also analyze the constraints placed on Suzhou’s development into an innovative city and promote the integration of global and local/regional assets through development of indigenous capacities.     

Arsenic in sediments, groundwater, and streamwater of a glauconitic Coastal Plain terrain, New Jersey, USA—Chemical “fingerprints” for geogenic and anthropogenic sources

Glauconite-bearing deposits are found worldwide, but As levels have been determined for relatively few. The As content of glauconites in sediments of the Inner Coastal Plain of New Jersey can exceed 100 mg/kg, and total As concentrations (up to 5.95 μg/L) found historically and recently in streamwaters exceed the State standard. In a major watershed of the Inner Coastal Plain, chemical “fingerprints” were developed for streambed sediments and groundwater to identify contributions of As to the watershed from geologic and anthropogenic sources. The fingerprint for streambed sediments, which included Be, Cr, Fe and V, indicated that As was predominantly of geologic origin. High concentrations of dissolved organic C, nutrients (and Cl⁻) in shallow groundwater indicated anthropogenic inputs that provided an environment where microbial activity released As from minerals to groundwater discharging to the stream. Particulates in streamwater during high flow constituted most of the As load; the chemical patterns for these particulates resembled the geologic fingerprint of the streambed sediments. The As/Cr ratio of these suspended particles likely indicates they derived not only from runoff, but from groundwater inputs, because As contributed by groundwater is sequestered on streambed sediments. Agricultural inputs of As were not clearly identified, although chemical characteristics of some sediments indicated vehicle-related inputs of metals. Sediment sampling during dry and wet years showed that, under differing hydrologic conditions, local anthropogenic fingerprints could be obscured but the geologic fingerprint, indicating glauconitic sediments as an As source, was robust.     

Otolith Microchemistry Reveals Substantial Use of Freshwater by Southern Flounder in the Northern Gulf of Mexico

Southern flounder Paralichthys lethostigma is a recreationally and commercially important species along the western Atlantic and northern Gulf of Mexico coasts that can exhibit complex early-life habitat-use patterns. Herein, we used an otolith microchemical approach to test the conventional wisdom that juvenile southern flounder spend most of their early life in low-salinity areas of estuaries, focusing on the largely unstudied population in the Mobile-Tensaw Delta, AL. Analysis of strontium/calcium concentrations in otolith cores of age 0 juveniles demonstrated that 68% of these individuals hatched in high-salinity waters before moving into freshwater habitats, with the remaining individuals being spawned in or near freshwater habitat. Further, otolith edge Sr/Ca concentrations revealed that even juveniles used freshwater habitats, particularly during freshwater/oligohaline conditions in our study system. Otolith edge Sr/Ca ratios for fish collected during high-salinity periods differed significantly among collection regions, suggesting seasonal differences in patterns of habitat use between individuals collected upstream (i.e., freshwater habitats) vs. downstream (i.e., euryhaline habitats). These data support the hypothesis that early-life stages of a substantial portion of a coastal southern flounder population use freshwater habitat.     

Model initialization in a tidally energetic regime: A dynamically adjusted objective analysis

A simple improvement to objective analysis of hydrographic data is proposed to eliminate spatial aliasing effects in tidally energetic regions. The proposed method consists of the evaluation of anomalies from observations with respect to circulation model fields. The procedure is run iteratively to achieve convergence. The method is applied in the Bay of Fundy and compared with traditional objective analysis procedures and dynamically adjusted climatological fields. The hydrographic skill (difference between observed and model temperature and salinity) of the dynamically adjusted objective analysis is significantly improved by reducing bias and correcting the vertical structure. Representation of the observed velocities is also improved. The resulting flow is consistent with the known circulation in the Bay.     

The Weather of the European Atlantic Seaboard During October 1805: An Exercise in Historical Climatology

Several thousand ships' logbooks havesurvived from the eighteenth and nineteenth centuries.They provide a valuable source of climaticinformation. This paper takes the Battle of Trafalgaras an example of how this source can be used toprovide a better knowledge and understanding ofweather and climate from those distant times. Thereliability of the non-instrumental climatic recordsof the logbooks is confirmed and a simple statisticalmeasure is used to quantify their degree ofconsistency. Reconstructions of daily weather patternsare made and a zonal index is calculated to representthe circulation patterns of the region. The movementsof pressure systems are plotted and indicate that thezonal index was negative (air pressure increasing fromsouth to north) for most of the month. The storm thatfollowed the battle is identified as one of notableseverity. This extreme behaviour is interpreted withinthe context of longer-term aspects of the contemporaryclimate.