The nanoscale mineralogy of Fe,Ni sulfides in pristine and metamorphosed CM and CM/CI‐like chondrites: Tapping a petrogenetic record

We have sampled sulfide grains from one pristine CM2 chondrite (Yamato [Y‐] 791198), one thermally metamorphosed CM2 chondrite (Y‐793321), and two anomalous, metamorphosed CM/CI‐like chondrites (Y‐86720 and Belgica [B‐] 7904) by the focused ion beam (FIB) technique and studied them by analytical transmission electron microscopy (TEM). Our study aims at exploring the potential of sulfide assemblages and microstructures to decipher processes and conditions of chondrite petrogenesis. Complex exsolution textures of pyrrhotite (crystallographic NC‐type with N ≈ 6), troilite, and pentlandite occur in grains of Y‐791198 and Y‐793321. Additionally, polycrystalline 4C‐pyrrhotite‐pentlandite‐magnetite aggregates occur in Y‐791198, pointing to diverse conditions of gas–solid interactions in the solar nebula. Coarser exsolution textures of Y‐793321 grains indicate higher long‐term average temperatures in the <100 °C range compared to Y‐791198 and other CM chondrites. Sulfide mineralogy of Y‐86720 and B‐7904 is dominated by aggregates of pure troilite and metal, indicating metamorphic equilibration at sulfur fugacities (fS₂) of the iron‐troilite buffer. Absence of magnetite in equilibrium with sulfide and metal in Y‐86720 indicates higher peak temperatures compared with B‐7904, in which coexistence of troilite, metal, and magnetite constrains metamorphic temperature to less than 570 °C. NC‐pyrrhotite occurs in both meteorites as nm‐wide rims on troilite grains and, together with frequent anhydrite, indicates a retrograde metamorphic stage at higher fS₂ slightly above the fayalite‐magnetite‐quartz‐pyrrhotite buffer. Fine‐grained troilite‐olivine intergrowths in both meteorites suggest the pre‐metamorphic presence of tochilinite‐serpentine interlayer phases, pointing to mineralogical CM affinity. Pseudomorphs after euhedral pyrrhotite crystals in Y‐86720 in turn suggest CI affinity as do previously published O isotopic data of both meteorites.     

The influence of water on the stress supported by experimentally faulted Westerly granite

Summary. Fault zones in wet Westerly granite deformed at temperatures of 300° and 400°C require markedly lower shear stresses for sliding than when dry, even when the effective confining pressure is held constant between the wet and dry tests, provided that the strain rate is lower than 10⁻⁷s⁻¹. The rate of strength reduction is enhanced by increasing the pore water pressure. The deformation rate is a power function of the applied stress where the stress exponent is approximately 7 for pore water pressure of 100 MPa and 21 for pore water pressure of 20 MPa.
The experimental results are extrapolated to conditions believed to occur at depths of 10 km along the San Andreas Fault Zone. It is suggested that for slow tectonic deformation at strain rates of 10⁻¹¹ and 10⁻¹⁴s⁻¹ the shear stress for sliding on faults in granite would be approximately 60 and 20 MPa, respectively, at pore water pressures equal to the hydrostatic head. Fluid overpressures of c. 0.8 lithostatic pressure are required to lower the shear stress for sliding into the 10 MPa range at the slower strain rate.     

High energy observations of June 1980 solar flares

The paper presents a detailed study of the high energy X-ray observation of the most unusual solar events observed on 4 and 7 June, 1980 with the Hard X-Ray Burst Spectrometer (HXRBS) on Solar Maximum Mission (SMM) satellite. The hard X-ray data of the events are also compared with the radio microwave fluxes.The X-ray time profiles of these flares are characterized by the occurrence of impulsive phase superposed with a number of narrow spikes before the occurrence of the main energetic events. Studies of the temporal and spectral properties of these events indicated a quasi-oscillatory nature of the sources. Various models for explaining the evolution of the events are considered and the sequential firing loop model seems to be consistent with the observations of the events.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.     

The budget and geochemistry of arsenic in a continental shelf environment

The concentrations of arsenic species in continental-shelf waters of the southeastern U.S. are controlled mainly by simple physical mixing of shelf waters and Gulf Stream intrusions. The biota mediate redox reactions which result in a disequilibrium of arsenic species; up to 20% of the total arsenic (averaging 1.1 μg/l) occurs as unstable arsenite [As (III)] and dimethylarsenic, the remainder consists of thermodynamically favored arsenate [As (V)]. Uptake of arsenic by the biota has a minor effect on arsenic distribution in offshore waters, producing a deep-water arsenate maximum, and minima for arsenite and dimethylarsenic. Riverine and atmospheric arsenic inputs to the shelf waters are relatively insignificant. Southeastern rivers contain only about 0.3 μg/l dissolved arsenic, and the atmosphere adjacent to continental shelf waters contains about 1.7 ng/m³ of As (V), exclusively associated with the particulate fraction.     

Lithium isotope geochemistry and origin of Canadian shield brines

Hypersaline calcium/chloride shield brines are ubiquitous in Canada and areas of northern Europe. The major questions relating to these fluids are the origin of the solutes and the concentration mechanism that led to their extreme salinity. Many chemical and isotopic tracers are used to solve these questions. For example, lithium isotope systematics have been used recently to support a marine origin for the Yellowknife shield brine (Northwest Territories). While having important chemical similarities to the Yellowknife brine, shield brines from the Sudbury/Elliot Lake (Ontario) and Thompson/Snow Lake (Manitoba) regions, which are the focus of this study, exhibit contrasting lithium behavior. Brine from the Sudbury Victor mine has lithium concentrations that closely follow the sea water lithium-bromine concentration trajectory, as well as delta6Li values of approximately -28/1000. This indicates that the lithium in this brine is predominantly marine in origin with a relatively minor component of crustal lithium leached from the host rocks. In contrast, the Thompson/Snow Lake brine has anomalously low lithium concentrations, indicating that it has largely been removed from solution by alteration minerals. Furthermore, brine and nonbrine mine waters at the Thompson mine have large delta6Li variations of approximately 30/1000, which primarily reflects mixing between deep brine with delta6Li of -35 +/- 2/1000 and near surface mine water that has derived higher delta6Li values through interactions with their host rocks. The contrary behavior of lithium in these two brines shows that, in systems where it has behaved conservatively, lithium isotopes can distinguish brines derived from marine sources.     

Gamma-ray,neutron, and hard X-ray studies and requirements for a high-energy solar physics facility

The requirements for future high-resolution spatial, spectral, and temporal observations of hard X-rays, gamma rays and neutrons from solar flares are discussed in the context of current high-energy flare observations. There is much promise from these observations for achieving a deep understanding of processes of energy release, particle acceleration and particle transport in a complicated environment such as the turbulent and highly magnetized atmosphere of the active Sun.     

QuakeSim and the Solid Earth Research Virtual Observatory

We are developing simulation and analysis tools in order to develop a solid Earth Science framework for understanding and studying active tectonic and earthquake processes. The goal of QuakeSim and its extension, the Solid Earth Research Virtual Observatory (SERVO), is to study the physics of earthquakes using state-of-the-art modeling, data manipulation, and pattern recognition technologies. We are developing clearly defined accessible data formats and code protocols as inputs to simulations, which are adapted to high-performance computers. The solid Earth system is extremely complex and nonlinear, resulting in computationally intensive problems with millions of unknowns. With these tools it will be possible to construct the more complex models and simulations necessary to develop hazard assessment systems critical for reducing future losses from major earthquakes. We are using Web (Grid) service technology to demonstrate the assimilation of multiple distributed data sources (a typical data grid problem) into a major parallel high-performance computing earthquake forecasting code. Such a linkage of Geoinformatics with Geocomplexity demonstrates the value of the Solid Earth Research Virtual Observatory (SERVO) Grid concept, and advances Grid technology by building the first real-time large-scale data assimilation grid.     

iSERVO: Implementing the International Solid Earth Research Virtual Observatory by Integrating Computational Grid and Geographical Information Web Services

We describe the goals and initial implementation of the International Solid Earth Virtual Observatory (iSERVO). This system is built using a Web Services approach to Grid computing infrastructure and is accessed via a component-based Web portal user interface. We describe our implementations of services used by this system, including Geographical Information System (GIS)-based data grid services for accessing remote data repositories and job management services for controlling multiple execution steps. iSERVO is an example of a larger trend to build globally scalable scientific computing infrastructures using the Service Oriented Architecture approach. Adoption of this approach raises a number of research challenges in millisecond-latency message systems suitable for internet-enabled scientific applications. We review our research in these areas.     

Assimilating remotely sensed snow observations into a macroscale hydrology model

Accurate forecasting of snow properties is important for effective water resources management, especially in mountainous areas like the western United States. Current model-based forecasting approaches are limited by model biases and input data uncertainties. Remote sensing offers an opportunity for observation of snow properties, like areal extent and water equivalent, over larger areas. Data assimilation provides a framework for optimally merging information from remotely sensed observations and hydrologic model predictions. An ensemble Kalman filter (EnKF) was used to assimilate remotely sensed snow observations into the variable infiltration capacity (VIC) macroscale hydrologic model over the Snake River basin. The snow cover extent (SCE) product from the moderate resolution imaging spectroradiometer (MODIS) flown on the NASA Terra satellite was used to update VIC snow water equivalent (SWE), for a period of four consecutive winters (1999–2003). A simple snow depletion curve model was used for the necessary SWE–SCE inversion. The results showed that the EnKF is an effective and operationally feasible solution; the filter successfully updated model SCE predictions to better agree with the MODIS observations and ground surface measurements. Comparisons of the VIC SWE estimates following updating with surface SWE observations (from the NRCS SNOTEL network) indicated that the filter performance was a modest improvement over the open-loop (un-updated) simulations. This improvement was more evident for lower to middle elevations, and during snowmelt, while during accumulation the filter and open-loop estimates were very close on average. Subsequently, a preliminary assessment of the potential for assimilating the SWE product from the advanced microwave scanning radiometer (AMSR-E, flown on board the NASA Aqua satellite) was conducted. The results were not encouraging, and appeared to reflect large errors in the AMSR-E SWE product, which were also apparent in comparisons with SNOTEL data.     

Littoral fish assemblages of the alien-dominated Sacramento-San Joaquin Delta,California, 1980–1983 and 2001–2003

We analyzed monthly boat electrofishing data to characterize the littoral fish assemblages of five regions of the Sacramento-San Joaquin Delta (northern, southern, eastern, western, and central), California, during two sampling periods, 1980–1983 (1980s) and 2001–2003 (2000s), to provide information pertinent to the restoration of fish populations in this highly altered estuary. During the 1980s, almost 11,000 fish were captured, including 13 native species and 24 alien species. During the 2000s, just over 39,000 fish were captured, including 15 native species and 24 alien species. Catch per unit effort (CPUE) of total fish, alien fish, and centrarchid fish were greater in the 2000s compared with the 1980s, largely because of increased centrarchid fish CPUE. These differences in CPUE were associated with the spread of submerged aquatic vegetation (SAV), particularly an alien aquatic macrophyte,Egeria densa. Native fish CPUE declined from the 1980s to the 2000s, but there was no single factor that could explain the decline. Native fish were most abundant in the northern region during both sampling periods. Nonmetric multidimensional scaling indicated similar patterns of fish assemblage composition during the two sampling periods, with the northern and western regions characterized by the presence of native species. The separation of the northern and western regions from the other regions was most distinct in the 2000s. Our results suggest that native fish restoration efforts will be most successful in the northern portion of the Delta. Management decisions on the Delta should include consideration of possible effects on SAV in littoral habitats and the associated fish assemblages and ecological processes.