Late Quaternary palaeoenvironment of northern Guatemala: evidence from deep drill cores and seismic stratigraphy of Lake Petén Itzá

Long sediment cores were collected in spring 2006 from Lake Petén Itzá, northern Guatemala, in water depths ranging from 30 to 150 m, as part of an International Continental Scientific Drilling Program project. The sediment records from deep water consist mainly of alternating clay, gypsum and carbonate units and, in at least two drill sites, extend back >200 kyr. Most of the lithostratigraphic units are traceable throughout the basin along seismic reflections that serve as seismic stratigraphic boundaries and suggest that the lithostratigraphy can be used to infer regional palaeoenvironmental changes. A revised seismic stratigraphy was established on the basis of integrated lithological and seismic reflection data from the basin. From ca 200 to ca 85 ka, sediments are dominated by carbonate‐clay silt, often interbedded with sandy turbidites, indicating a sediment regime dominated by detrital sedimentation in a relatively humid climate. At ca 85 ka, an exposure horizon consisting of gravels, coarse sand and terrestrial gastropods marks a lake lowstand or partial basin desiccation, indicating dry climate conditions. From ca 85 to ca 48 ka, transgressive carbonate‐clay sediments, overlain by deep‐water clays, suggest a lake level rise and subsequent stabilization at high stage. From ca 48 ka to present, the lithology is characterized by alternating clay and gypsum units. Gypsum deposition correlates with Heinrich Events (i.e. dry climate), whereas clay units coincide with more humid interstadials.     

Role of carbonates in mitigation of metal release from mining waste. Evidence from humidity cells tests

 Leaching of two contrasting types of sulphidic tailings in humidity cells has been performed. The release of heavy metals and the oxidation rate have been studied. Tailings from the Laver mine contain a few percent sulphides and lack carbonates, whereas tailings from the Stekenjokk mine are both sulphide- and carbonate-rich. The results showed that in the leachates from the Laver samples, the metal concentrations increased and pH decreased with time, indicating an increased oxidation rate. In the Stekenjokk samples, pH remained high during the experiment, thereby keeping the metal concentrations low in the leachates. The oxidation rate also decreased with time, probably due to Fe-hydroxide coatings on sulphide surfaces. The results show that addition of carbonates and the maintenance of a high pH not only reduce the solubility of heavy metals, but also decrease the oxidation rate of sulphides. Received: 20 January 1998 · Accepted: 2 April 1998     

Modeling River Stage‐Discharge Relationships Using Different Neural Network Computing Techniques

One of the most important problems in hydrology is the establishment of rating curves. The statistical tools that are commonly used for river stage‐discharge relationships are regression and curve fitting. However, these techniques are not adequate in view of the complexity of the problems involved. Three different neural network techniques, i. e., multi‐layer perceptron neural network with Levenberg‐Marquardt and quasi‐Newton algorithms and radial basis neural networks, are used for the development of river stage‐discharge relationships by constructing nonlinear relationships between stage and discharge. Daily stage and flow data from three stations, Yamula, Tuzkoy and Sogutluhan, on the Kizilirmak River in Turkey were used. Regression techniques are also applied to the same data. Different input combinations including the previous stages and discharges are used. The models' results are compared using three criteria, i. e., root mean square errors, mean absolute error and the determination coefficient. The results of the comparison reveal that the neural network techniques are much more suitable for setting up stage‐discharge relationships than the regression techniques. Among the neural network methods, the radial basis neural network is found to be slightly better than the others.     

Genetic algorithms for the classification and prediction of precipitation occurrence

Abstract

Using an approach similar to the biological processes of natural selection and evolution, the genetic algorithm (GA) is a nonconventional optimum search technique. Genetic algorithms have the ability to search large and complex decision spaces and handle nonconvexities. In this paper, the GA is applied for solving the optimum classification of rainy and non-rainy day occurrences based on vertical velocity, dewpoint depression, temperature and humidity data. The problem involves finding optimum classification based on known data, training the future prediction system and then making reliable predictions for rainfall occurrences which have significance in agricultural, transportation, water resources and tourism activities. Various statistical approaches require restrictive assumptions such as stationarity, homogeneity and normal probability distribution of the hydrological variables concerned. The GAs do not require any of these assumptions in their applications. The GA approach for the occurrence classifications and predictions is presented in steps and then the application of the methodology is shown for precipitation occurrence (non-occurrence) data. It has been shown that GAs give better results than classical approaches such as discriminant analysis. The application of the methodology is presented independently for the precipitation event occurrences and forecasting at the Lake Van station in eastern Turkey. Finally, the amounts of precipitation are predicted with a model similar to a third order Markov model whose parameters are estimated by the GA technique.     

Chemical Weathering Rates, Erosion Rates and Mobility of Major and Trace Elements in a Boreal Granitic Till

Chemical weathering rates and erosionrates of granitic till in northern Sweden have beenestimated. The present-day chemical weathering rate iscompared with the long-term average weathering ratesince the last deglaciation approximately 8,700 yearsago. Also, the present-day release rates of major andtrace elements due to chemical weathering are comparedwith the mobility of these elements in a spodosolprofile as shown by soil water samples from the vadozezone. The estimation of the past weathering rate isbased on elemental depletion trends in a soil profile(typic haplocryod), whereas the present weatheringrate is based on elemental input/output budgets in asmall catchment (9.4 km²). The long-term averagechemical erosion rate, expressed as the sum of majorelement oxides (SiO₂, Al₂O₃, CaO,Fe₂O₃, K₂O, MgO, MnO, Na₂O,P₂O₅, TiO₂), was estimated to be4.9 gm^-2 yr^-1. The long-term base cation(Ca²⁺, Mg²⁺, Na⁺, K⁺) depletionwas 0.325 keq ha^-1 yr^-1. The currentchemical erosion rate was estimated to be2.43.0 g ^-2 yr^-1, which is at least an order ofmagnitude higher than the rate of physical erosion,and the base cation flux due to chemical weathering is0.356–0.553~keq ha^-1 yr^-1. However,0.074 keq ha^-1 yr^-1 of this flux may be related tocation exchange processes induced by atmospheric inputof acid rain. There is no evidence for any recentlyincreased weathering rate of silicates in this area.The inputs of Cd, Cu, Ni and Zn exceed the outputs,and hence, these elements are currently accumulatingin the soil.There is a distinct seasonal variation in thechemical composition of the soil water. Results fromthe soil water samples show that Na, followed by Siand S (Cl was not measured), are the most mobileelements in the spodosol profile between the E-horizonand the C-horizon, and that Al and Fe were the leastmobile elements. However, there is no simplerelationship between the mobility of an element in thespodosol profile and the current release rate due toweathering of that element. This fact may haveimplications for the validity of the comparisonbetween the past and present weathering rates asperformed in this study.     

Aragonite and magnesite in eclogites from the Jæren nappe,SW Norway: disequilibrium in the system CaCO3–MgCO3 and petrological implications

Eclogites from the Jæren nappe in the Caledonian orogenic belt of SW Norway contain aragonite, magnesite and dolomite in quartz‐rich layers. The carbonates comprise composite grains that occur interstitially between phases of the eclogite facies assemblage: garnet + omphacite + zoisite + clinozoisite + quartz + apatite + rutile ± dolomite ± kyanite ± phengite. Pressure and temperature conditions for the main eclogite stage are estimated to be 2.3–2.8 GPa and 585–655 °C. Published ultrahigh pressure (UHP) experiments on CaO‐, MgO‐ and CO₂‐bearing systems have shown that equilibrium assemblages of aragonite and magnesite form as a result of dolomite breakdown at pressures >5 GPa. As a result, recognition of magnesite and aragonite in eclogite facies rocks has been used as an indicator for UHP conditions. However, petrological testing showed that the samples studied here have not experienced such conditions. Aragonite and magnesite show disequilibrium textures that indicate replacement of magnesite by aragonite. This process is inferred to have occurred via a coupled dissolution–precipitation reaction. The formation of aragonite is constrained to eclogite facies conditions, which implies that the studied rocks have experienced metasomatic, reactive fluid flow during their residence at high pressure (HP) conditions. During decompression, the bimineralic carbonate aggregates were overgrown by rims of dolomite, which partially reacted with aragonite to form Mg‐calcite. The well‐preserved carbonate assemblages and textures observed in the studied samples provide a detailed record of the reaction series that affected the rocks during and after their residence at P–T conditions near the coesite stability field. Recognition of the HP mechanism of magnesite replacement by aragonite provides new insight into metasomatic processes that occur in subduction zones and illustrates how fluids facilitate HP carbonate reactions that do not occur in dry systems at otherwise identical physiochemical conditions. This study documents that caution is warranted in interpreting aragonite‐magnesite associations in eclogite facies rocks as evidence for UHP metamorphic conditions.     

20th-CENTURY CHANGES OF TEMPERATURE IN THE MOUNTAIN REGIONS OF CENTRAL EUROPE

Daily maximum and minimum temperatures from 29 low-lying and mountain stations of 7 countries in Central Europe were analyzed. The analysis of the annual variation of diurnal temperature range helps to distinguish unique climatic characteristics of high and low altitude stations. A comparison of the time series of extreme daily temperatures as well as mean temperature shows a good agreement between the low-lying stations and the mountain stations. Many of the pronounced warm and cold periods are present in all time series and are therefore representative for the whole region. A linear trend analysis of the station data for the period 1901–1990 (19 stations) and 1951–1990 (all 29 stations) shows spatial patterns of similar changes in maximum and minimum daily temperatures and diurnal temperature range. Mountain stations show only small changes of the diurnal temperature range over the 1901–1990 period, whereas the low-lying stations in the western part of the Alps show a significant decrease of diurnal temperature range, caused by strong increase of the minimum temperature. For the shorter period 1951–1990, the diurnal temperature range decreases at the western low-lying stations, mainly in spring, whereas it remains roughly constant at the mountain stations. The decrease of diurnal temperature range is stronger in the western part than in the eastern part of the Alps.