Thermodynamic model for sorption of bivalent heavy metals on calcite in natural-technogenic environments

Approaches to the construction of thermodynamic models for sorption of trace-element cations on carbonates are considered. To calculate thermodynamic equilibria by the method of Gibbs free-energy minimization, the existing database of reaction constants and thermodynamic potentials was extended. Different types of models are illustrated by the example of precipitation of Cd, Cu, Pb, and Zn from the water of a drainage stream flowing out of the impoundment of barite-polymetallic ore-dressing wastes. It is shown that the mobility of metals in such cases can be controlled by their sorption by calcite present in bottom sediments and suspension. Any approach can be successfully applied to both the modeling of experimental data on cation sorption and the prediction of the ecologo-geochemical situation in the districts of dressing works.     

The quality of life in Ukraine and in Russia as a factor of socio-economic development

The characteristic features of the socio-geographical approach in analyzing the “quality of life of population” category are highlighted. Experience in assessing the balanced development of Ukraine and Russia is presented; the most important factors that are responsible for the quality of life in these countries are determined.     

Distribution and abundance of tidal marshes along the coast of maine

Planimetry studies of coastal geology maps prepared by the Maine Geological Survey show that there is more than an order of magnitude more tidal marsh area in the state of Maine than documented in previously published estimates. The highly convoluted coast of Maine, which is approximately 5,970 km long, contains almost 79 km² of salt marsh, far more than any other New England state, New York, or the Bay of Fundy region. Reasonable estimates for the per-unit primary productivity of salt marshes lead to projections of total marsh productivity on the order of 10¹⁰ g dry weight yr^?1 for the Maine coast and 10¹¹ g dry weight yr^?1 for the Gulf of Maine as a whole. Distribution of tidal marsh area is strongly controlled by coastal geomorphology, which varies considerably along the coast of Maine. The salt marsh area is concentrated in the southwestern coastal region of arcuate bays, where marshes have developed behind sandy beaches. A series of long islands and bedrock peninsulas in the south-central portion of the coast also provides sheltered areas where large marshes occur. Northeast of Penobscot Bay salt marshes become more numerous and smaller in average areal extent. A lack of protection from waves, along with limited sources of glacio-fluvial and glacio-marine sediments, restricts the occurrence of salt marshes in that region to the frignes of coves and tidal rivers.     

Lead isotopes of the carbonate-hosted Kabwe, Tsumeb, and Kipushi Pb-Zn-Cu sulphide deposits in relation to Pan African orogenesis in the Damaran-Lufilian Fold Belt of Central Africa

Lead isotope ratios of galena from the carbonate-hosted massive sulphide deposits of Kabwe (Pb-Zn) and Tsumeb (Pb-Zn-Cu) in Zambia and Namibia, respectively, have been measured and found to be homogeneous and characteristic of upper crustal source rocks. Kabwe galena has average isotope ratios of ^206/204Pb = 17.997 ± 0.007, ^207/204Pb = 15.713 ± 0.010 and ^208/204Pb = 38.410 ± 0.033. Tsumeb galena has slightly higher ^206/204Pb (18.112 ± 0.035) and slightly lower ^207/204Pb (15.674 ± 0.016) and ^208/204Pb (38.276 ± 0.073) ratios than Kabwe galena. The isotopic differences are attributed to local differences in the age and composition of the respective source rocks for Kabwe and Tsumeb. The homogeneity of the ore lead in the two epigenetic deposits suggests lead sources of uniform isotopic composition or, alternatively, thorough mixing of lead derived from sources with relatively similar isotopic compositions. Both deposits have relatively high ²³⁸U/²⁰⁴Pb ratios of 10.31 and 10.09 for Kabwe and Tsumeb galenas, respectively. These isotope ratios are considered to be typical of the upper continental crust in the Damaran-Lufilian orogenic belt, as also indicated by basement rocks and Cu-Co sulphides in stratiform Katangan metasediments which have a mean μ-value of 10.25 ± 0.12 in the Copperbelt region of Zambia and the Democratic Republic of Congo (formerly Zaire). The ²³²Th/²⁰⁴Pb isotope ratios of 43.08 and 40.42 for Kabwe and Tsumeb suggest Th-enriched source regions with ²³²Th/²³⁵U (κ-values) of 4.18 and 4.01, respectively. Model isotopic ages determined for the Kabwe (680 Ma) and Tsumeb (530 Ma) deposits indicate that the timing of the mineralisation was probably related to phases of orogenic activity associated with the Pan-African Lufilian and Damaran orogenies, respectively. Galena from the carbonate-hosted Kipushi Cu-Pb-Zn massive sulphide deposit in the Congo also has homogeneous lead isotope ratios, but its isotopic composition is comparable to that of the average global lead evolution curve for conformable massive sulphide deposits. The μ (9.84) and κ (3.69) values indicate a significant mantle component, and the isotopic age of the Kipushi deposit (456 Ma) suggests that the emplacement of the mineralisation was related to a post-tectonic phase of igneous activity in the Lufilian belt. The isotope ratios (^206/204Pb, ^207/204Pb, ^208/204Pb) of the three deposits are markedly different from the heterogeneous lead ratios of the Katangan Cu-Co stratiform mineralisation of the Copperbelt as well as those of the volcanogenic Nampundwe massive pyrite deposit in the Zambezi belt which typically define radiogenic linear trends on lead-lead plots. The host-rock dolomite of the Kabwe deposit also has homogeneous lead isotope ratios identical to the ore galena. This observation indicates contamination of the Kabwe Dolomite Formation with ore lead during mineralisation. Received: 8 September 1997 / Accepted: 21 August 1998     

Clay minerals as indicators of late quaternary sedimentation constraints in the Mendeleev Rise, Amerasian Basin, Arctic Ocean

The results of study of six cores taken from different morphostructural zones in the Mendeleev Ridge area are discussed. Average contents of minerals of the illite group, chlorite, kaolinite, and smectite are about 60, 21, 12, and 5%, respectively. It was found that fluctuations of minerals along the section correlate with variations in sedimentation constraints in the Late Quaternary. Peaks of kaolinite usually coincide with increased contents of the sand fraction, probably, due to its delivery by icebergs. In contrast, illite shows good correlation with the pelite fraction, testifying to its transport mainly by ices and currents. Minerals of the chlorite and smectite groups in the studied cores are less informative.     

Source-specific variability in post-depositional DNA preservation with potential implications for DNA based paleoecological records

Recent studies have shown that genotyping preserved plankton DNA in marine and lacustrine sediment records using ancient DNA methods is a promising approach for refining paleoenvironmental information. However, the extent to which the preservation of fossil plankton DNA differs between species is poorly understood. Using a continuous 2700 year sediment record from Watts Basin in Ellis Fjord (Antarctica), we compared the level of preservation of fossil DNA derived from important plankton members with varying cellular architecture. The amount of preserved small subunit ribosomal DNA (SSU rDNA; ca. 500 base pair fragments) of dinoflagellates (as extracellular DNA rather than as preserved cysts) that could be amplified by way of PCR declined up to five orders of magnitude with increasing sediment depth and age. In contrast, the amount of similar-sized, PCR-amplifiable, diatom SSU rDNA (predominantly from a cyst-forming Chaetoceros sp.) declined only up to tenfold over 2700 years of deposition. No obvious decline in copy numbers with increasing sediment age was observed for similar-sized SSU rDNA of past chemocline-associated photosynthetic green sulfur bacteria (GSB), which do not have a protective resting stage. In good agreement with the quantitative data, the extent of post-depositional natural degradation to fragments too small to serve as a template for the quantitative PCR assays was greatest for dinoflagellates and lowest for GSB. An increase in the ratio between GSB-derived DNA and intact carotenoids with sediment depth implies that short GSB DNA fragments were better preserved than intact carotenoids and provide a more accurate view into paleoproductivity and the sediment flux of GSB in Watts Basin. We discuss the possible causes behind the variation in the level of DNA preservation among the plankton groups investigated, as well as consequences for the use of using fossil DNA records in paleoecology studies.     

Population genetic diversity and structure of a dominant tropical seagrass,Cymodocea rotundata,in the Western Pacific region

Cymodocea rotundata is an ecologically important tropical pioneer seagrass species distributed in the Indo‐Pacific region. The population genetic diversity and structure of this species were analysed at 46 sites spanning the Philippines, Ryukyu Islands (northern limit) and Hainan Island, by using microsatellite simple sequence repeat (SSR) markers. Analyses revealed the persistence of C. rotundata likely relies on local population dynamics and fitness influenced by environmental gradients, with sexual reproduction prevalent in the Philippines while the Ryukyu and Hainan populations were predominantly established by clonal spread. Analysis of molecular variance showed significant genetic differentiation (P < 0.001) among three geographic regions: the Philippines, Ryukyu and Hainan. Furthermore, the mean fixation index value was very high (F_ST = 0.36), indicating poor dispersal potential or limited gene flow. Allelic richness and heterozygosity of C. rotundata was comparable in the Philippines and Ryukyu Islands populations. More private alleles were found in the Philippines and excess heterozygotes in the Ryukyu Islands. STRUCTURE analysis revealed that the Ryukyu and Hainan populations were mosaics of admixed alleles of individuals from the Philippines. An assignment test suggested that recruitment occurs from the Northeast Philippines to Ryukyu Islands. These results suggest that the Philippine populations are tropical seagrass hotspots and perhaps the origin of the populations in the Ryukyu and Hainan Islands. This scenario is most likely driven by the Kuroshio Current and island integration events during plate tectonic activities. The Philippine Archipelago is considered of high importance for conservation objectives and management plan of seagrasses. Likewise, the Ryukyu Islands are also important in terms of conserving regional diversity because locally adapted genotypes have important evolutionary potential in the face of environmental change.     

Characterization of rocking shallow foundations using centrifuge model tests

This paper presents new results of centrifuge model tests exploring the behavior of rocking shallow foundations embedded in dry sand, which provides a variety of factors of safety for vertical bearing. The results of slow (quasi‐static) cyclic tests of rocking shear walls and dynamic shaking tests of single‐column rocking bridge models are presented. The moment–rotation and settlement–rotation relationships of rocking footings are investigated. Concrete pads were placed in the ground soil to support some models with the objective of reducing the settlement induced by rocking. The behavior of rocking foundation was shown to be sensitive to the geometric factor of safety with respect to bearing failure, L_f/L_c, where L_f was the footing length, and the L_c was the critical soil‐footing contact length that would be required to support pure axial loading. Settlements were shown to be small if L_f/L_c was reasonably large. Placement of concrete pads under the edges of the footing was shown to be a promising approach to reduce settlements resulting from rocking, if settlements were deemed to be excessive and also had impacts on the energy dissipation and rocking moment capacity. A general discussion of the tradeoffs between energy dissipation and re‐centering of rocking foundations and other devices is included. Copyright © 2011 John Wiley & Sons, Ltd.     

Bender Elements在测试土样剪切波速中的应用

本文以作者在香港理工大学土木与结构工程系设计制作的一套BenderElements为例,介绍了BenderElements的原理、发展历史、应用范围、使用方法和注意事项等。BenderElements是由压电陶瓷材料制成的,在拉伸、压缩作用下,会产生正、负电荷,反过来,给它施加正、负电荷后,它又可产生弯曲振动,正是利用它的这一特性,将其作成接收和发射装置,来测试土样的剪切波速Vs。BenderElements在安装使用时,防水和静电屏蔽十分关键。Vs可在场地地震反应、液化判别、动力基础设计、检测地基改良效果等方面获得应用。震相识别的原则是接收信号的第一个峰值为到时。     

The constancy of galactic cosmic rays as recorded by cosmogenic nuclides in iron meteorites

We measured the He, Ne, and Ar isotopic concentrations and the ¹⁰Be, ²⁶Al, ³⁶Cl, and ⁴¹Ca concentrations in 56 iron meteorites of groups IIIAB, IIAB, IVA, IC, IIA, IIB, and one ungrouped. From ⁴¹Ca and ³⁶Cl data, we calculated terrestrial ages indistinguishable from zero for six samples, indicating recent falls, up to 562 ± 86 ka. Three of the studied meteorites are falls. The data for the other 47 irons confirm that terrestrial ages for iron meteorites can be as long as a few hundred thousand years even in relatively humid conditions. The ³⁶Cl‐³⁶Ar cosmic ray exposure (CRE) ages range from 4.3 ± 0.4 Ma to 652 ± 99 Ma. By including literature data, we established a consistent and reliable CRE age database for 67 iron meteorites. The high quality of the CRE ages enables us to study structures in the CRE age histogram more reliably. At first sight, the CRE age histogram shows peaks at about 400 and 630 Ma. After correction for pairing, the updated CRE age histogram comprises 41 individual samples and shows no indications of temporal periodicity, especially not if one considers each iron meteorite group separately. Our study contradicts the hypothesis of periodic GCR intensity variations (Shaviv 2002, 2003), confirming other studies indicating that there are no periodic structures in the CRE age histogram (e.g., Rahmstorf et al. 2004; Jahnke 2005). The data contradict the hypothesis that periodic GCR intensity variations might have triggered periodic Earth climate changes. The ³⁶Cl‐³⁶Ar CRE ages are on average 40% lower than the ⁴¹K‐K CRE ages (e.g., Voshage 1967). This offset can either be due to an offset in the ⁴¹K‐K dating system or due to a significantly lower GCR intensity in the time interval 195–656 Ma compared to the recent past. A 40% lower GCR intensity, however, would have increased the Earth temperature by up to 2 °C, which seems unrealistic and leaves an ill‐defined ⁴¹K‐K CRE age system the most likely explanation. Finally, we present new ²⁶Al/²¹Ne and ¹⁰Be/²¹Ne production rate ratios of 0.32 ± 0.01 and 0.44 ± 0.03, respectively.