Biofouling confounds the uptake of trace organic contaminants by semi-permeable membrane devices (SPMDs)

The outer layers of layflat, low density polyethylene plastic tubing (the principal component of semi-permeable membrane devices, SPMDs) were biofouled at a clean site in Hong Kong coastal waters for periods of 1–4 weeks. Following pre-fouling, triolein was added to the SPMDs and, along with control (unfouled) devices, they were exposed to a range of organochlorine pesticides (-HCH, aldrin, p,p^′-DDT) and PAHs (anthracene, fluoranthene and benzo(a)pyrene) under laboratory conditions. Results showed that the uptake of contaminants by SPMDs was severely reduced by as much as 50% under fouling conditions in comparison to unfouled controls. The ultimate utility of SPMDs as passive monitors is thus reduced, although alternative measures, such as the use of permeability reference compounds may compensate, and allow for realistic evaluations of dissolved environmental concentrations in aquatic environments. However, due to the complexities involved in such procedures––especially as they need to be conducted on a case-by-case basis––the utility of SPMDs appears to be limited for estimates of bioavailability unless necessary calibrations are undertaken within each environment that the sampler is used.     

A Measurement of Omega from the North American Test Flight of Boomerang

We use the angular power spectrum of the cosmic microwave background, measured during the North American test flight of the Boomerang experiment, to constrain the geometry of the universe. Within the class of cold dark matter models, we find that the overall fractional energy density of the universe Omega is constrained to be 0.85相似文献   

Near-Surface Flow Fields Deduced Using Correlation Tracking and Time-Distance Analyses

Near-photospheric flow fields on the Sun are deduced using two independent methods applied to the same time series of velocity images observed by SOI-MDI on SOHO. Differences in travel times between f modes entering and leaving each pixel measured using time-distance helioseismology are used to determine sites of supergranular outflows. Alternatively, correlation tracking analysis of mesogranular scales of motion applied to the same time series is used to deduce the near-surface flow field. These two approaches provide the means to assess the patterns and evolution of horizontal flows on supergranular scales even near disk center, which is not feasible with direct line-of-sight Doppler measurements. We find that the locations of the supergranular outflows seen in flow fields generated from correlation tracking coincide well with the locations of the outflows determined from the time-distance analysis, with a mean correlation coefficient after smoothing of _s=0.890. Near-surface velocity field measurements can be used to study the evolution of the supergranular network, as merging and splitting events are observed to occur in these images. The data consist of one 2048-min time series of high-resolution (0.6 pixels) line-of-sight velocity images taken by MDI on 1997 January 16–18 at a cadence of one minute.     

An analysis of Pc3 and Pc4 pulsations at Terra Nova Bay (Antarctica)

We conducted a statistical analysis of the physical characteristics of the micropulsation activity (Pc3 and Pc4 range) detected, during the austral summer 1994/95, at Terra Nova Bay (Antarctica, corrected latitude 80.0°S), a station which is few degrees poleward of those where most of the Antarctic measurements in these frequency ranges have been performed. The emerging overview suggests that the correspondence between the pulsation power and the external parameters (solar wind speed, interplanetary magnetic field magnitude and orientation) is significantly stronger than at somewhat lower latitudes. The day-to-day power variability was found to be strictly related to the general level of the geomagnetic activity, and the power level sharply maximizes at local magnetic noon. In the Pc4 range peaks of correlation with the SW speed are found in the dawn and dusk sides of the Earths magnetosphere and the daily variation of the polarization pattern is closely consistent with that found at auroral latitudes and at lower frequencies. In the Pc3 range the correlation coefficient between the pulsation power and the SW speed has maximum values in the local morning, and the frequency of selected events reveals a strong IMF control during closed magnetospheric conditions. The local time dependence of the correlation coefficient between the pulsation power and the cone angle reveals an additional control by the IMF orientation, which becomes more explicit around local noon.     

Remotely sensed estimation of forest canopy density: A comparison of the performance of four methods

In recent years, a number of alternative methods have been proposed to predict forest canopy density from remotely sensed data. To date, however, it remains difficult to decide which method to use, since their relative performance has never been evaluated. In this study the performance of: (1) an artificial neural network, (2) a multiple linear regression, (3) the forest canopy density mapper and (4) a maximum likelihood classification method was compared for prediction of forest canopy density using a Landsat ETM+ image. Comparison of confusion matrices revealed that the regression model performed significantly worse than the three other methods. These results were based on a z-test for comparison of weighted kappa statistics, which is an appropriate statistic for analysis of ranked categories. About 89% of the variance of the observed canopy density was explained by the artificial neural networks, which outperformed the other three methods in this respect. Moreover, the artificial neural networks gave an unbiased prediction, while other methods systematically under or over predicted forest canopy density. The choice of biased method could have a high impact on canopy density inventories.     

Seeding agent dispersion within convective cloud as simulated by a 3-D numerical model

Summary The three-dimensional mesoscale cloud-resolving model ARPS (Advanced Regional Prediction System) was used to investigate the dispersal of an inert seeding agent within a cumulonimbus (Cb) cloud developing from two different initial states. In this paper, we stress the influence vortices in the cloud have on seeding agent dispersion. If a strong directional ambient wind shear is present in the lowest layer, a vortex pair formed at the flanks of the simulated cloud. Following the velocity field, a considerable amount of the injected seeding agent would be thrown out to the rear of the cloud, where both updrafts associated with vortices and downdrafts occurred. After a short time the agent was present only in the cloud periphery. If the Cb cloud developed under conditions where directional ambient wind shear did not exist, seeding agent dispersion would be quite different. In this case, almost all the seeding agent was transported into the main updraft, while the residence time of the agent within the cloud was longer due to the weaker cloud dynamics. Therefore, we must pay attention to whether or not the cloud contains vortices when we make the decision where to seed. This is necessary in order to minimize the loss of seeding material.     

Impact of storm runoff from tropical watersheds on coastal water quality and productivity

Storm runoff in the steep watersheds in Hawaii leads to sediment and freshwater pulses to coastal waters that quickly affect nearshore water quality. This is particularly true in semi-enclosed embayments, such as Kaneohe Bay, Oahu, where water has a relatively long residence time compared to more open coastal areas of the islands. In this paper the authors discuss water quality and productivity in Kaneohe Bay after back-to-back rain events in late November and early December 2003, following a particularly dry summer. The short-term biogeochemical response of coastal waters and the ecosystem to runoff and physical forcing was evaluated through a combination of continuous in situ measurements and adaptive synoptic sampling carried out on a variety of temporal and spatial scales.     

Analysis and modeling of the seasonal South China Sea temperature cycle using remote sensing

The present paper describes the analysis and modeling of the South China Sea (SCS) temperature cycle on a seasonal scale. It investigates the possibility to model this cycle in a consistent way while not taking into account tidal forcing and associated tidal mixing and exchange. This is motivated by the possibility to significantly increase the model’s computational efficiency when neglecting tides. The goal is to develop a flexible and efficient tool for seasonal scenario analysis and to generate transport boundary forcing for local models. Given the significant spatial extent of the SCS basin and the focus on seasonal time scales, synoptic remote sensing is an ideal tool in this analysis. Remote sensing is used to assess the seasonal temperature cycle to identify the relevant driving forces and is a valuable source of input data for modeling. Model simulations are performed using a three-dimensional baroclinic-reduced depth model, driven by monthly mean sea surface anomaly boundary forcing, monthly mean lateral temperature, and salinity forcing obtained from the World Ocean Atlas 2001 climatology, six hourly meteorological forcing from the European Center for Medium range Weather Forecasting ERA-40 dataset, and remotely sensed sea surface temperature (SST) data. A sensitivity analysis of model forcing and coefficients is performed. The model results are quantitatively assessed against climatological temperature profiles using a goodness-of-fit norm. In the deep regions, the model results are in good agreement with this validation data. In the shallow regions, discrepancies are found. To improve the agreement there, we apply a SST nudging method at the free water surface. This considerably improves the model’s vertical temperature representation in the shallow regions. Based on the model validation against climatological in situ and SST data, we conclude that the seasonal temperature cycle for the deep SCS basin can be represented to a good degree. For shallow regions, the absence of tidal mixing and exchange has a clear impact on the model’s temperature representation. This effect on the large-scale temperature cycle can be compensated to a good degree by SST nudging for diagnostic applications.     

Luminescence dating of old (>70 ka) Chinese loess: A comparison of single-aliquot OSL and IRSL techniques

The applicability of two different approaches in the luminescence dating of old (>70 ka) Chinese loess is investigated. Both SAR-OSL ages obtained on 63–90 μm quartz grains and SAR-IRSL ages obtained on 4–11 μm polymineral grains, for samples collected from two sites in the Chinese Loess Plateau (Luochuan and Dongchuan) are presented. The characteristics of the luminescence signals stimulated by blue and infrared light are investigated in terms of dose response and dose recovery, and as a function of age. Additionally, anomalous fading measurements from the 410 nm IRSL emission in polymineral fine-grains are reported. An average value of g_2days amounting to 3% per decade was measured and seems to be independent of site location and age. For the samples from Luochuan, independent age control (pedostratigraphy and palaeomagnetism) is available. At both sites, the SAR-OSL ages are always lower than the SAR-IRSL ages after they have been corrected for anomalous fading. It seems that the quartz-based SAR-OSL ages are accurate for the younger ages, but that they underestimate the true age of deposition for loess that was deposited about 60–70 ka ago. The fading-corrected SAR-IRSL ages are in better agreement with the pedostratigraphic age control (75 and 130 ka) and allow dating beyond the quartz OSL range. Based on our results, we suggest that conventional SAR-OSL and SAR-IRSL protocols at these sites should be restricted to samples of ages not exceeding 40–50  and 100–120 ka, respectively.     

The Temaguessine Fe-cordierite orbicular granite (Central Hoggar, Algeria): U–Pb SHRIMP age, petrology, origin and geodynamical consequences for the late Pan-African magmatism of the Tuareg shield

The Temaguessine high-level subcircular pluton is intrusive into the LATEA metacraton (Central Hoggar) Eburnian (2 Ga) basement and in the Pan-African (615 Ma) granitic batholiths along a major NW–SE oriented major shear zone. It is dated here (SHRIMP U–Pb on zircon) at 582 ± 5 Ma. Composed of amphibole–biotite granite and biotite syenogranite, it comprises abundant enclaves: mafic magmatic enclaves, country-rock xenoliths and remarkable Fe-cordierite (#Fe = 0.87) orbicules. The orbicules have a core rich in cordierite (40%) and a leucocratic quartz–feldspar rim. They are interpreted as resulting from the incongruent melting of the meta-wacke xenoliths collapsed into the magma: the breakdown of the biotite + quartz assemblage produced the cordierite and a quartz–feldspar minimum melt that is expelled, forming the leucocratic rim. The orbicule generation occurred at T < 850° and P < 0.3 GPa. The Fe-rich character of the cordierite resulted from the Fe-rich protolith (wacke with 4% Fe₂O₃ for 72% SiO₂). Strongly negative ε_Nd (−9.6 to −11.2), Nd T_DM model ages between 1.64 and 1.92 Ga, inherited zircons between 1.76 and 2.04 Ga and low to moderately high I_Sr (0.704–0.710) indicate a Rb-depleted lower continental crust source for the Temaguessine pluton; regional considerations impose however also the participation of asthenospheric material. The Temaguessine pluton, together with other high-level subcircular pluton, is considered as marking the end of the Pan-African magma generation in the LATEA metacraton, resulting from the linear delamination along mega-shear zones, allowing asthenospheric uprise and melting of the lower continental crust. This implies that the younger Taourirt granitic province (535–520 Ma) should be considered as a Cambrian intraplate anorogenic event and not as a very late Pan-African event.