1958～2018年永定河流域蒸发皿蒸发量的变化特征及其影响因子分析

基于永定河流域1958～2018年14个气象站的逐日观测数据,采用气候倾向率、Mann–Kendall趋势检验法分析蒸发皿蒸发量时空变化特征,并通过完全相关系数和多元回归分析识别气候因子与蒸发量的相关程度并定量计算其贡献率.结果表明:在全球气候变暖的背景下,60年来永定河流域气温以0.29°C/10 a的速率上升,而蒸...     

Platinum-group element distribution in base-metal sulfides of the Merensky Reef from the eastern and western Bushveld Complex, South Africa

Base-metal sulfides in magmatic Ni-Cu-PGE deposits are important carriers of platinum-group elements (PGE). The distribution and concentrations of PGE in pentlandite, pyrrhotite, chalcopyrite, and pyrite were determined in samples from the mineralized portion of four Merensky Reef intersections from the eastern and western Bushveld Complex. Electron microprobe analysis was used for major elements, and in situ laser ablation inductively-coupled plasma mass spectrometry (LA-ICP-MS) for trace elements (PGE, Ag, and Au). Whole rock trace element analyses were performed on representative samples to obtain mineralogical balances. In Merensky Reef samples from the western Bushveld, both Pt and Pd are mainly concentrated in the upper chromitite stringer and its immediate vicinity. Samples from the eastern Bushveld reveal more complex distribution patterns. In situ LA-ICP-MS analyses of PGE in sulfides reveal that pentlandite carries distinctly elevated PGE contents, whereas pyrrhotite and chalcopyrite only contain very low PGE concentrations. Pentlandite is the principal host of Pd and Rh in the ores. Palladium and Rh concentrations in pentlandite reach up to 700 and 130 ppm, respectively, in the samples from the eastern Bushveld, and up to 1,750 ppm Pd and up to 1,000 ppm Rh in samples from the western Bushveld. Only traces of Pt are present in the base-metal sulfides (BMS). Pyrrhotite contains significant though generally low amounts of Ru, Os, and Ir, but hardly any Pd or Rh. Chalcopyrite contains most of the Ag but carries only extremely low PGE concentrations. Mass balance calculations performed on the Merensky Reef samples reveal that in general, pentlandite in the feldspathic pyroxenite and the pegmatoidal feldspathic pyroxenite hosts up to 100 % of the Pd and Rh and smaller amounts (10–40 %) of the Os, Ir, and Ru. Chalcopyrite and pyrrhotite usually contain less than 10 % of the whole rock PGE. The remaining PGE concentrations, and especially most of the Pt (up to 100 %), are present in the form of discrete platinum-group minerals such as cooperite/braggite, sperrylite, moncheite, and isoferroplatinum. Distribution patterns of whole rock Cu, Ni, and S versus whole rock Pd and Pt show commonly distinct offsets. The general sequence of “offset patterns” of PGE and BMS maxima, in the order from bottom to top, is Pd in pentlandite?→?Pd in whole rock?→?(Cu, Ni, and S). The relationship is not that straightforward in general; some of the reef sequences studied only partially show similar trends or are more complex. In general, however, the highest Pd concentrations in pentlandite appear to be related to the earliest, volumetrically rather small sulfide liquids at the base of the Merensky Reef sequence. A possible explanation for the offset patterns may be Rayleigh fractionation.     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

应用改进的相干算法提高三维地震资料解释精度

作者在文中详细探讨了C1、C2和C3三种相干算法及其。根据三维地震数据体的特点提出了实用的相干算法，并编制了相应的软件。我们对三种相干算法对应相干数据体的解释结果进行了细致的分析，C2相干算法基本能够平衡提高横向分辨率和信噪比之间的矛盾，而C3相干算法则取得了更精确的效果。     

Quantification of river water infiltration in shallow aquifers using acesulfame and anthropogenic gadolinium

This study has investigated the use of the artificial sweetener acesulfame and the magnetic resonance imaging contrast agent gadolinium as quantitative tracers for river water infiltration into shallow groundwater. The influence of a river on alluvial groundwater in a subalpine catchment in western Europe has been assessed using the ‘classical’ hydrochemical tracer chloride and the trace contaminants acesulfame and anthropogenic gadolinium. Mixing ratios for riverine bank filtrate with ambient groundwater and the uncertainties associated with the temporal and spatial tracer variability were calculated using acesulfame and gadolinium and compared with those obtained using chloride. The temporal variability of tracer concentrations in river water of gadolinium (standard deviation SD: 63%) and acesulfame (SD: 71%) both exceeded that of chloride (SD: 27%), and this was identified as the main source of uncertainty in the mixing analysis. Similar spatial distributions were detected in the groundwater for chloride and gadolinium, but not for acesulfame. Mixing analyses using acesulfame resulted in calculated mixing ratios that differed from those obtained using gadolinium and chloride by up to 83% and 92%, respectively. At the investigated site, which had oxic conditions and moderate temperatures, acesulfame was found to be a less reliable tracer than either gadolinium or chloride, probably because of natural attenuation and input from other sources. There was no statistically significant difference between the mixing ratios obtained using chloride or gadolinium, the mixing ratios obtained using gadolinium were 40–50% lower than those obtained using chloride. This is mainly due to a bias of the mean gadolinium concentration in river water towards higher values. In view of the uncertainties of the two tracers, neither could be preferred over the other for the quantification of bank filtrate in groundwater. At this specific site gadolinium was able to reliably identify river water infiltration and was a more precise tracer than chloride at low mixing ratios (<20%), because of the exclusive occurrence of gadolinium in river water and its high dynamic range. Copyright © 2015 John Wiley & Sons, Ltd.     

Mineralogical,geochemical and microfabric evidences of gypsum crusts: a case study from Budapest

High levels of SO₂ and particulate pollution enable the rapid development of gypsum-rich weathering crusts in Budapest. Two types of white crusts, thin and thick ones, and two forms of black crusts, laminar and framboidal ones, were studied in limestone buildings of the parliament and Citadella. The percentage of crust cover and damage categories were documented on selected walls. Petrographic, XRD, XRF and sulphur isotope analyses were performed under laboratory conditions to understand the mechanism of crust formation. White crusts found both on exposed and sheltered walls display a calcite-rich layer with gypsum, while black crusts are enriched with gypsum. The sulphur isotopic composition of white and black crusts overlaps, but the crusts are slightly enriched in heavy isotopes compared to rainwater. S content, Si/Al ratios and particulates in black crusts suggest that air pollution (SO₂, dust) contributes to black crust formation. The accumulation of sulphur and Zn enrichment of white crusts were also documented indicating that under high pollution levels, even these compound can accumulate on exposed facades.     

卫星遥感在监视地震中的可应用性

阐述了卫星遥感技术及其产品在地震监视中的可应用性。已有震例的研究结果表明 ,震中附近存在着显著的震前地表增热现象。利用 RS热红外卫星遥感资料地气系统射出长波辐射信息 (即 OL R值 ) ,不仅可以有效地预测未来地震发生的区域 ,还可以对地表监测项目 (如地磁、地下流体、形变等 )中资料的可靠程度作出诊断。采用卫星遥感系统与地面监视系统的“融合”,形成空间与地面相结合的多源观测信息支撑的地震监视体系 ,将有助于提高我国的震情监视和预测能力     

Analysis and modelling of rainfall fields at different resolutions in southern Italy

Abstract

The spatial and temporal variability of the scaling properties and correlation structure of a data set of rainfall time series, aggregated over different temporal resolutions, and observed in 70 raingauges across the Basilicata and Calabria regions of southern Italy, is investigated. Two types of random cascade model, namely canonical and microcanonical models, were used for each raingauge and selected season. For both models, different hypotheses concerning dependency of parameters on time scale and rainfall height can be adopted. In particular, a new approach is proposed which consists of several combinations of models with a different scale dependence of parameters for different temporal resolutions. The goal is to improve the modelling of the main features of rainfall time series, especially for cases where the variability of rainfall changes irregularly with temporal aggregation. The results obtained with the new methodology showed good agreement with the observed data, in particular, for the summer months. In fact, during this season, rainfall heights aggregated at fine temporal resolutions (from 5 to 20 min) are more similar (relative to the winter season) to the values cumulated on 1 or 3 h (due to convective phenomena) and, consequently, the process of rainfall breakdown is nearly stationary for a range of finer temporal resolutions.

Editor D. Koutsoyiannis; Associate editor A. Montanari     

North-south asymmetries in the green corona brightness between 1947 and 1976

The north-south asymmetry has been studied using the green emission corona brightness in the period of 1947–1976. (N - S)/(N + S) values are constructed with the 5-deg opposite coronal belts brightnesses between ± 5 and ± 60 deg. Power spectra analyses were performed to study periodicities of these (N - S)/(N + S) values. Two noticeable periodicities (14.5 and 5 yr) have been found.