The stable isotopic composition (Cl/Cl) of dissolved chloride in rainwater

The stable isotopic composition of dissolved Cl^-${\text{Cl}}^{-}$ in rainwater was measured from a coastal and an interior location in eastern Canada. At the interior Bonner Lake, Ontario, site the δ³⁷Cl values of dissolved Cl^-${\text{Cl}}^{-}$ in precipitation ranged from −3.5‰ to −1.2‰ (SMOC) with an amount-weighted annual average of −2.3‰. At the coastal site, Bay D’Espoir, Newfoundland, δ³⁷Cl values of dissolved Cl^-${\text{Cl}}^{-}$ values ranged from −3.1‰ to 0.0‰ with an amount-weighted annual average of −1.3‰. These negative δ³⁷Cl values provide evidence that atmospheric HCl is ³⁷Cl depleted, presumably from acidification of sea-salt aerosols. Accordingly, dissolved Cl^-${\text{Cl}}^{-}$ in the headwaters of two montane rivers in Western Canada had similarly depleted δ³⁷Cl values. These results have implications to the interpretation of the isotopic compositions of dissolved Cl^-${\text{Cl}}^{-}$ in surface waters, formation fluids, and groundwaters.     

Energy cost-accounting of Louisiana fishery production

A quantitative relationship between gross primary production and secondary production of aquatic upper level consumers was derived for the inshore portion of the Louisiana coastal zone. We estimate that 1,700 units of gross primary production are required to produce one unit of upper level consumers. Lower and mid-level consumers are estimated to require lesser amounts, 300 and 600 units, respectively. Harvested fishery groups in the inshore ecosystem represent a total average of about 23,000 metric tons (dry wt) or about 1.2×10¹¹ Kcal (5.0×10¹¹ KJ) annually. This harvest “costs” the system about 7×10¹³ Kcal (3.3×10¹⁴ KJ) of gross primary production, or an equivalent of 4×10¹⁴ Kcal (1.7×10¹⁵KJ) of fossil fuel.     

Centrifuge modeling of load-deformation behavior of rocking shallow foundations

Shallow foundations supporting building structures might be loaded well into their nonlinear range during intense earthquake loading. The nonlinearity of the soil may act as an energy dissipation mechanism, potentially reducing shaking demands exerted on the building. This nonlinearity, however, may result in permanent deformations that also cause damage to the building. Five series of tests on a large centrifuge, including 40 models of shear wall footings, were performed to study the nonlinear load-deformation characteristics during cyclic and earthquake loading. Footing dimensions, depth of embedment, wall weight, initial static vertical factor of safety, soil density, and soil type (dry sand and saturated clay) were systematically varied. The moment capacity was not observed to degrade with cycling, but due to the deformed shape of the footing–soil interface and uplift associated with large rotations, stiffness degradation was observed. Permanent deformations beneath the footing continue to accumulate with the number of cycles of loading, though the rate of accumulation of settlement decreases as the footing embeds itself.     

A study of the chemistry of pore fluids and authigenic carbonates in methane seep environments: Kodiak Trench, Hydrate Ridge, Monterey Bay, and Eel River Basin

Analyses of the chemical and isotopic composition of carbonates rocks recovered from methane seepage areas of the Kodiak Trench, Hydrate Ridge, Monterey Bay Clam Flats, and the Eel River Basin, coupled with the studies of the chemistry of the pore fluids, have shown that these carbonates have grown within the sediment column. Geochemical profiles of pore fluids show that, in deep water seeps (Kodiak Trench—4450 m; Monterey Bay—1000 m; Hydrate Ridge—650 m), δ¹³C (DIC) values are low (isotopically light), whereas in the Eel River area ( 350–500 m), δ¹³C (DIC) values are much higher (isotopically heavier). In all cases, the δ¹³C values indicate that processes of methane oxidation, associated with sulfate reduction, are dominant in the shallow sediments. Data on the isotopic composition of authigenic carbonates found at sites in Kodiak Trench, Eel River Basin South, and Eel River Basin North indicate a variable composition and origin in different geochemical environments. Some of the authigenic carbonates from the study sites show a trend in their δ¹³C values similar to those of the pore fluids obtained in their vicinity, suggesting formation at relatively shallow depths, but others indicate formation at greater sediment depths. The latter usually consist of high magnesium calcite or dolomite, which, from their high values of δ¹³C (up to 23‰;) and δ¹⁸O (up to 7.5‰), suggest formation in the deeper horizons of the sediments, in the zone of methanogenesis. These observations are in agreement with observations by other workers at Hydrate Ridge, in Monterey Bay, and in the Eel River Basin.     

Slope aspect, slope length and slope inclination controls of shallow soils vegetated by sclerophyllous heath—links to long-term landscape evolution

On upland Triassic sandstone slopes of the western Blue Mountains, nonswamp, sclerophyllous heath (shrub-dominated vegetation) on shallow soils is commonly found downslope and adjacent to sclerophyllous forest on deeper soils. Some consider heath—and thus shallow soils—as favouring west-facing slopes, which are expected to experience drier microclimates due to insolation, strong and desiccating winds, and severe summer fires. However, our analysis of extensive areas with heath on shallow soils, based on vegetation and topographic maps, and fieldwork of uplands with various degrees of dissection, suggests that aspect is a poor predictor of shallow soils. Rather, shallow soils and heath are found on short slopes and the lower segments of longer slopes with the latter significantly steeper than forested segments.The shallow–deep soil boundary, marked by contrasting modern vegetation structures, does not signify a catchment area threshold, and correspondingly, the vegetation patterns are not in balance with distributary catchment processes, as short slopes are mantled exclusively by shallow soils. Instead, the soil depth boundary represents the propagation of base-level lowering signals, which takes place not only by the headward retreat of knickpoints but also via increased lowering of slope segments adjacent to drainage lines. This leads to steep slopes immediately adjacent to canyons, narrow gorges, and small steep valleys, that are mantled by shallow, discontinuous soils undergoing rapid erosion. These steep slopes persist in the landscape for ≥ 10 My after upland stream rejuvenation until incision of more weatherable Permian sediments, underlying the Triassic cliff-forming sandstones, triggers rapid lateral expansion of gorges. Once shallowly mantled and steeper slopes adjacent to streams are consumed by gorge widening, slopes adjacent to wide gorge clifflines reflect former upland drainage patterns rather than the redirected flow to rapidly widening gorges. Hence, modern vegetation patterns reflect a significant phase of landform development, perhaps combined with enhanced erosion during the Last Glacial Period that is compounded by a humped soil production function on bedrock.