Late Miocene to Pliocene stratigraphy of the Kura Basin,a subbasin of the South Caspian Basin: implications for the diachroneity of stage boundaries

Relative ages of late Cenozoic stratigraphy throughout the Caspian region are referenced to regional stages that are defined by changes in microfauna and associated extreme (>1000 m) variations in Caspian base level. However, the absolute ages of these stage boundaries may be significantly diachronous because many are based on the first occurrence of either transgressive or regressive facies, the temporal occurrence of which should depend on position within a basin. Here, we estimate the degree of diachroneity along the Akchagyl regional stage boundary within the Caspian basin system by presenting two late Miocene‐Pliocene aged measured sections, Sarica and Vashlovani, separated by 50 km and exposed within the Kura fold‐thrust belt in the interior of the Kura Basin. The Kura Basin is a western subbasin of the South Caspian Basin and the sections presented here are located >250 km from the modern Caspian coast. New U‐Pb detrital zircon ages from the Sarica section constrain the maximum depositional age for Productive Series strata, a lithostratigraphic package considered correlative with the 2–3 Myr‐long regional Eoakchagylian or Kimmerian stage that corresponds to a period of extremely low (>500 m below the modern level) Caspian base level. This new maximum depositional age from the Productive Series at Sarica of 2.5 ± 0.2 Ma indicates that the regionally extensive Akchagyl transgression, which ended the deposition of the Productive Series near the Caspian coast at 3.2 Ma, may have appeared a minimum of 0.5 Myr later in the northern interior of the Kura Basin than at the modern Caspian Sea coast. The results of this work have important implications for the tectonic and stratigraphic history of the region, suggesting that the initiation of the Plio‐Pleistocene Kura fold‐thrust belt may have not been as diachronous along strike as previously hypothesized. More generally, these results also provide a measure of the magnitude of diachroneity possible along sequence boundaries, particularly in isolated basins. Comparison of accumulation rates between units in the interior of the Kura subbasin and the South Caspian main basin suggest that extremely large variations in these rates within low‐stand deposits may be important in identifying the presence of subbasins in older stratigraphic packages.     

Nature and Estimated Human Toxicity of Polar Metabolite Mixtures in Groundwater Quantified as TPHd/DRO at Biodegrading Fuel Release Sites

Polar metabolites resulting from petroleum biodegradation are measured in groundwater samples as TPHd unless a silica gel cleanup (SGC) is used on the sample extract to isolate hydrocarbons. Even though the metabolites can be the vast majority of the dissolved organics present in groundwater, SGC has been inconsistently applied because of regulatory concern about the nature and toxicity of the metabolites. A two‐step approach was used to identify polar compounds that were measured as TPHd in groundwater extracts at five sites with biodegrading fuel sources. First, gas chromatography with mass spectrometry (GC‐MS) was used to identify and quantify 57 individual target polar metabolites. Only one of these compounds—dodecanoic acid, which has low potential human toxicity—was detected. Second, nontargeted analysis was used to identify as many polar metabolites as possible using both GC‐MS and GC×GC‐MS. The nontargeted analysis revealed that the mixture of polar metabolites identified in groundwater source areas at these five sites is composed of approximately equal average percentages of organic acids, alcohols and ketones, with few phenols and aldehydes. The mixture identified in downgradient areas at these five sites is dominated by acids, with fewer alcohols, far fewer ketones, and very few aldehydes and phenols. A ranking system consistent with systems used by USEPA and the United Nations was developed for evaluating the potential chronic oral toxicity to humans of the different classes of identified polar metabolites. The vast majority of the identified polar metabolites have a “Low” toxicity profile, and the mixture of identified polar metabolites present in groundwater extracts at these five sites is unlikely to present a significant risk to human health.     

Variability in reproductive effort of a keystone species: age and height of branch establishment

Carnegiea gigantea (saguaro, Cactaceae) is a protected and keystone species in the Sonoran Desert upon which nearly all of the ecosystem’s fauna rely. Little is known about its branching habits, which are particularly important as branching is directly related to seed production. This study assessed the ages and heights of plants when branching commenced under four different environmental regimes. Significant variations were observed in the onset of branching across the populations by both age (78–139?years) and height (4.4–5.5?m), likely related to the interplay between summer precipitation (and thus growth rate) and winter precipitation, which increases branching in any given individual. In all four populations, branches developed from areoles that are themselves reproductive (past or present); i.e., the lower areoles that pre-date the start of reproduction do not appear to contribute to branch production. Further, unlike the wide range of ages at the start of branching, the delay between the start of fruiting and the production of branches appears to be relatively consistent across populations, hovering around a 30-year time lag. Of greatest concern is the advanced age (around 140?years) at which branching begins at the most marginal, arid site, which is around the same time that old-age mortality may set in for the species (generally), dramatically diminishing reproductive output in an already marginal population. If this keystone species declines in this already arid to hyper-arid environment, it would have dramatic and irreversible consequences for the fauna and the ecosystem in this region.     

Why Web GIS May Not Be Enough: A Case Study with the Virtual Research Vessel

During several decades of investigation, the East Pacific Rise seafloor-spreading center at 9°-10°N has been explored by marine geologists, geophysicists, chemists, and biologists, and has emerged as one of the best studied sections of the global midocean ridge. It is an example of a region for which there is now a great wealth of observational data, results, and data-driven theoretical studies. However, these have yet to be fully utilized, either by research scientists or educators. While the situation is improving, a large amount of data, results, and related theoretical models still exist either in an inert, noninteractive form (e.g., journal publications) or as unlinked and currently incompatible computer data or algorithms. Presented here is the prototype of a computational environment and toolset, called the Virtual Research Vessel, to improve the situation by providing marine scientists and educators with simultaneous access to data, maps, and numerical models. While infrastructure is desired and needed for ready access to data and the resulting maps via web GIS in order to link disparate data sets (data to data), it is argued that data must also be linked to models for better exploration of new relations between observables, refinement of numerical simulations, and the quantitative evaluation of scientific hypotheses. For widespread data access, web GIS is therefore only a preliminary step rather than a final solution, and the ongoing implementation of the Virtual Research Vessel (scheduled for final completion in 2004-2005) is a case study for the midocean ridge community to test the effectiveness of moving beyond the data-to-data mode towards data-to-models and data-to-interpretation.     

Centimeter-Level Positioning of Seafloor Acoustic Transponders from a Deeply-Towed Interrogator

An array of three seafloor transponders was acoustically surveyed to centimeter precision with a deeply-towed interrogator. Measurements of two-way acoustic travel time and hydrostatic pressure made as the interrogator was towed above the array were combined in a least-squares adjustment to estimate the interrogator and transponder positions in two surveys spanning two years. No transponder displacements were expected at this site in the interior of the Juan de Fuca Plate (48^?11′ N, 127^?12′ W) due to the lack of active faults. This was confirmed to a precision of ±2 cm by least-squares adjustment. Marginally detectable blunders in the observations were shown to affect the transponder position estimates by no more than 3 mm, demonstrating the geometric strength of the data set. The accumulation of many hundreds of observations resulted in a significant computational burden on the least-squares inversion procedure. The sparseness of the normal matrix was exploited to reduce by a factor of 1000 the number of calculations. The acoustic survey results suggested that the near-bottom sound speed fields during the two surveys were in better agreement than inferred from yearly single-profile conductivity, temperature, and pressure (CTD) measurements.     

Palaeoenvironmental evolution of Cenote Aktun Ha (Carwash) on the Yucatan Peninsula,Mexico and its response to Holocene sea-level rise

A 61-cm core was obtained from 4 m below the water table in Cenote Aktun Ha, on the Yucatan Peninsula, Mexico. The cenote is 8.6 km from the Caribbean coast and its formation and evolution have been largely affected by sea-level change. The base of the core dates to 6,940–6,740 cal year BP and overlying sediments were deposited rapidly over the subsequent ~200 years. The pollen record shows that the cenote evolved from a marsh dominated by red mangrove (Rhizophora mangle) and fern (Polypodiaceae) to an open-water system. These vegetation changes were controlled by water level and salinity and are thus useful indicators of past sea level. At the base, the δ¹³C_org isotopic ratios reveal the influence of terrestrial vegetation (−29‰ VPDB), but shift to more negative values up-core (−33‰), indicating an influence from particulate matter in the flooded cenote pool. Although microfossil populations were nearly absent through most of the core, the microfossil assemblage in the upper 6 cm of the core is dominated by the juvenile foraminifer Ammonia tepida and the thecamoebian genus Centropyxis. These populations indicate open-water conditions in the cenote and a major environmental shift around 6,600 cal year BP, which is related to sea-level rise in the Caribbean basin. These data fit well with previously established sea-level curves for the Caribbean Sea. Our reconstruction of the environmental history of Cenote Aktun Ha helps elucidate the floral and hydrological history of the region, and highlights the utility of cenote sediments for studying the Holocene sea-level history of the Caribbean Sea.     

Suggested Methods to Mitigate Bias from Nondissolved Petroleum in Ground Water Samples Collected from the Smear Zone

This article provides actual site data that confirm that turbid ground water samples collected from within the smear zone at petroleum release sites can be significantly biased high by the inclusion of a nondissolved component that is an artifact of the sampling process. Side-by-side comparisons show that reducing sample turbidity can result in significant reductions of reported concentrations for the ground water samples and that the lower turbidity results are more representative of the petroleum actually dissolved in the ground water. Depending on site-specific factors, ground water sample turbidity can be reduced by four field-based and two laboratory-based methods. These methods should be used routinely at sites where turbid samples with a nondissolved component are being collected.     

Geomorphic controls on deposition of salt in the Greater Tamar Catchment,northeast Tasmania

In Tasmania, most salts in the landscape originate from rainfall and accumulate in landscapes after evaporation occurs. The distribution and quantity of salt in rainfall from an array of bulk deposition collectors in the Greater Tamar Catchment were assessed for the period September 2013 to August 2014. The bulk deposition samples were analysed for pH, electrical conductivity, major ions (Ca, Mg, Na, SO₄ and Cl) and a selection of trace ions. The average salt flux across the study area was 79 ± 10 kg/ha/yr region, ranging from 170 ± 12 kg/ha/yr near the coast in the north to 42 ± 6 kg/ha/yr inland. Deposition of most ions decreased from the northwest to the south and east, and peaked in winter and spring. Geomorphic factors such as elevation and topography have an important effect on the volume of rainfall and flux of salt from windblown dust and oceanic aerosols. A comparison of measured chloride and salt deposition in Tasmania with other Australian atmospheric studies indicates that continental-scale models of salt flux are not appropriate for Tasmania. New models are proposed that take into account the influence of the Southern Ocean, Tasman Sea and topographic variation in the study area. The results provide improved estimates of rainfall-derived salt inputs to catchments in northeast Tasmania and enable more accurate salt budget modelling. Improved understanding of volumes and distribution of salts has implications for the management of soils and infrastructure that degrade as a result of dryland salinity in Tasmania.