Using Resin‐Based 3D Printing to Build Geometrically Accurate Proxies of Porous Sedimentary Rocks

Three‐dimensional (3D) printing is capable of transforming intricate digital models into tangible objects, allowing geoscientists to replicate the geometry of 3D pore networks of sedimentary rocks. We provide a refined method for building scalable pore‐network models (“proxies”) using stereolithography 3D printing that can be used in repeated flow experiments (e.g., core flooding, permeametry, porosimetry). Typically, this workflow involves two steps, model design and 3D printing. In this study, we explore how the addition of post‐processing and validation can reduce uncertainty in the 3D‐printed proxy accuracy (difference of proxy geometry from the digital model). Post‐processing is a multi‐step cleaning of porous proxies involving pressurized ethanol flushing and oven drying. Proxies are validated by: (1) helium porosimetry and (2) digital measurements of porosity from thin‐section images of 3D‐printed proxies. 3D printer resolution was determined by measuring the smallest open channel in 3D‐printed “gap test” wafers. This resolution (400 µm) was insufficient to build porosity of Fontainebleau sandstone (～13%) from computed tomography data at the sample's natural scale, so proxies were printed at 15‐, 23‐, and 30‐fold magnifications to validate the workflow. Helium porosities of the 3D‐printed proxies differed from digital calculations by up to 7% points. Results improved after pressurized flushing with ethanol (e.g., porosity difference reduced to ～1% point), though uncertainties remain regarding the nature of sub‐micron “artifact” pores imparted by the 3D printing process. This study shows the benefits of including post‐processing and validation in any workflow to produce porous rock proxies.     

Quantifying the effect of geomorphology on aeolian dust emission potential in northern China

Representation of dust sources remains a key challenge in quantifying the dust cycle and its environmental and climatic impacts. Direct measurements of dust fluxes from different landform types are useful in understanding the nature of dust emission and characterizing the dynamics of soil erodibility. In this study we used the PI-SWERL® instrument over a seasonal cycle to quantify the potential for PM₁₀ (particles with diameter ≤10 μm) emission from several typical landform types across the Tengger Desert and Mu Us Sandy Land, northern China. Our results indicate that sparse grasslands and coppice dunes showed relatively high emission potentials, with emitted fluxes ranging from 10⁻¹ to 10¹ mg m⁻² s⁻¹. These values were up to five times those emitted from sand dunes, and one to two orders of magnitude greater than the emissions from dry lake beds, stone pavements and dense grasslands. Generally, PM₁₀ emission fluxes were seen to peak in the spring months, with significant reductions in summer and autumn (by up to 95%), and in winter (by up to 98%). Variations in soil moisture were likely a primary controlling factor responsible for this seasonality in PM₁₀ emission. Our data provide a relative quantification of differences in dust emission potential from several key landform types. Such data allow for the evaluation of current dust source schemes proposed by prior researchers. Moreover, our data will allow improvements in properly characterizing the erodibility of dust source regions and hence refine the parameterization of dust emission in climate models. © 2019 John Wiley & Sons, Ltd. © 2019 John Wiley & Sons, Ltd.     

Stable isotope composition of dissolved sulfate and hydrogen sulfide in the Black Sea

The stable isotope ratio of sulfur (³⁴S/³²S) in dissolved sulfate and hydrogen sulfide was measured for 20 water samples from two deep hydrocasts from the south-central Black Sea. The isotope ratio of total reduced sulfur was also measured for surface sediment collected below each hydrocast. The range in the δ³⁴S measurements for sulfate was +18.20 to $\text{+20.17‰}$ and for hydrogen sulfide ?38.71 to $\text{?4.85‰}$. The distribution pattern for δ ³⁴S in both sulfate and sulfide appears to be the result of in situ sulfate reduction.     

Cross-Media Models of the Chesapeake Bay Watershed and Airshed

A continuous, deterministic watershed model of the Chesapeake Bay watershed, linked to an atmospheric deposition model is used to examine nutrient loads to the Chesapeake Bay under different management scenarios. The Hydrologic Simulation Program - Fortran, Version 11 simulation code is used at an hourly time-step for ten years of simulation in the watershed. The Regional Acid Deposition Model simulates management options in reducing atmospheric deposition of nitrogen. Nutrient loads are summed over daily periods and used for loading a simulation of the Chesapeake estuary employing the Chesapeake Bay Estuary Model Package. Averaged over the ten-year simulation, loads are compared for scenarios under 1985 conditions, forecasted conditions in the year 2000, and estimated conditions under a limit of technology scenario. Limit of technology loads are a 50%, 64%, and 42% reduction from the 1985 loads in total nitrogen, total phosphorus, and total suspended solids, respectively. Urban loads, which include point source, on-site wastewater disposal systems, combined sewer overflows, and nonpoint source loads have the highest flux of nutrient loads to the Chesapeake, followed by crop land uses.on assignment from NOAA Air Resources Laboratory     

Nutrient and carbon removal ratios and fluxes in the Ross Sea, Antarctica

Net community production (NCP) and nutrient deficits (Def(X)) were calculated using decreases in dissolved CO₂ and nutrient concentrations due to biological removal in the upper 200 m of the water column during four cruises in the Ross Sea, Antarctica along 76°30′S in 1996 and 1997. A comparison to excess dissolved and particulate organic carbon showed close agreement between surplus total organic carbon (TOC) and NCP during bloom initiation and productivity maximum; however, when TOC values had returned to low wintertime values NCP was still significantly above zero. This seasonal NCP, 3.9±1 mol C m⁻², must be equivalent to the particle export to depths greater than 200 m over the whole productive season. We estimate that the annual export was 55±22% of the seasonal maximum in NCP. The fraction of the seasonal maximum NCP that is exported through 200 m is significantly higher than that measured by moored sediment traps at a depth of 206 m. The removal of carbon, nitrate and phosphate (based on nutrient disappearance since early spring) and their ratios showed significant differences between regions dominated by diatoms and regions dominated by the haptophyte Phaeocystis antarctica. While the ΔC/ΔN removal ratio was similar (7.8±0.2 for diatoms and 7.2±0.1 for P. antarctica), the ΔN/ΔP and ΔC/ΔP removal ratios for diatoms (10.1±0.3 and 80.5±2.3) were significantly smaller than those of P. antarctica (18.6±0.4 and 134.0±4.7). The similarity in ΔC/ΔN removal ratios of the two assemblages suggests that preferential uptake of phosphate by diatoms caused the dramatic differences in ΔC/ΔP and ΔN/ΔP removal ratios. In contrast to low ΔC/ΔP and ΔN/ΔP removal ratio in diatom-dominated areas early in the growing season, deficit N/P and C/P ratios in late autumn indicate that the elemental stochiometry of exported organic matter did not deviate significantly from traditional Redfield ratios. Changes in biologically utilized nutrient and carbon ratios over the course of the growing season indicated either a substantial remineralization of phosphate or a decrease in phosphate removal relative to carbon and total inorganic nitrogen over the bloom period. The species dependence in C/P ratios, and the relative constancy in the C/N ratios, makes N a better proxy of biological utilization of CO₂.     

The Ecological Impact of Conquest and Colonization on a Medieval Frontier Landscape: Combined Palynological and Geochemical Analysis of Lake Sediments from Radzyń Chełminski,Northern Poland

Slavic and German colonization of the southern Baltic between the 8th and 15th centuries A.D. is well‐documented archaeologically and historically. Despite the large number of pollen profiles from Poland, few palaeoecological studies have examined the ecological impact of a process that was central to the expansion of European, Christian, societies. This study aims to redress this balance through multiproxy analysis of lake sediments from Radzyń Chełminski, Northern Poland, using pollen, element geochemistry (Inductively Coupled‐Optical Emission Spectroscopy [ICP‐OES]), organic content, and magnetic susceptibility. The close association between lake and medieval settlements presents the ideal opportunity to reconstruct past vegetation and land‐use dynamics within a well‐documented archaeological, historical, and cultural context. Three broad phases of increasing landscape impact are visible in the pollen and geochemical data dating from the 8th/9th, 10th/11th, and 13th centuries, reflecting successive phases of Slavic and German colonization. This involved the progressive clearance of oak‐hornbeam dominated woodland and the development of an increasingly open agricultural landscape. Although the castles and towns of the Teutonic Order remain the most visible signs of medieval colonization, the palynological and geochemical data demonstrate that the major phase of woodland impact occurred during the preceding phase of Slavic expansion; Germans colonists were entering a landscape already significantly altered.     

Influence of gusset plate connections and braces on the seismic performance of X‐braced frames

Braced frames are one of the most economical and efficient seismic resisting systems yet few full‐scale tests exist. A recent research project, funded by the National Science Foundation (NSF), seeks to fill this gap by developing high‐resolution data of improved seismic resisting braced frame systems. As part of this study, three full‐scale, two‐story concentrically braced frames in the multi‐story X‐braced configuration were tested. The experiments examined all levels of system performance, up to and including fracture of multiple braces in the frame. Although the past research suggests very limited ductility of SCBFs with HSS rectangular tubes for braces recent one‐story tests with improved gusset plate designs suggest otherwise. The frame designs used AISC SCBF standards and two of these frames designs also employed new concepts developed for gusset plate connection design. Two specimens employed HSS rectangular tubes for bracing, and the third specimen had wide flange braces. Two specimens had rectangular gusset plates and the third had tapered gusset plates. The HSS tubes achieved multiple cycles at maximum story drift ratios greater than 2% before brace fracture with the improved connection design methods. Frames with wide flange braces achieved multiple cycles at maximum story drift greater than 2.5% before brace fracture. Inelastic deformation was distributed between the two stories with the multi‐story X‐brace configuration and top story loading. Copyright © 2010 John Wiley & Sons, Ltd.     

Near-infrared spectra of the leading and trailing hemispheres of Enceladus

We present individual spectra 0.8-2.5 μm of the leading and trailing hemispheres of Enceladus obtained with the CorMASS spectrograph on the 1.8 m Vatican Advanced Technology Telescope (VATT) at the Mount Graham International Observatory. While the absorption bands of water ice dominate the spectrum of both hemispheres, most of these bands are stronger on the leading hemisphere than the trailing hemisphere. In addition, longward of 1 μm, the continuum slope is greater on the leading hemisphere than the trailing hemisphere. These differences could be produced by the presence of particles on the trailing side that are smaller and/or microstructurally more complex than those on the leading side, consistent with the preferential erosion or structural degradation of regolith particle grains on the trailing side by magnetospheric sweeping. We also explore compositional differences between the two hemispheres by applying Hapke spectrophotometric mixture models to the spectra whose components include water ice and ammonia hydrate (1% NH₃⋅H₂O). We find that spectral models which include as much as 25% by weight ammonia hydrate intimately mixed with water ice and covering 80% of the illuminated area of the satellite fit the observed spectrum of both the leading and trailing hemispheres. Areal (checkerboard) mixing models of ammonia hydrate and water ice fit the leading hemisphere with 15% of the surface comprised of ammonia hydrate and the trailing hemisphere with 10% ammonia hydrate. Therefore, while these spectral data do not contain an unambiguous detection of ammonia hydrate on Enceladus, our spectral models do not preclude the presence of a modest amount of 1% NH₃⋅H₂O on both hemispheres. We examine spectral differences and similarities between both hemispheres and the tenuous E ring within which Enceladus orbits. The spectral resolution (R=λ/Δλ) of these CorMASS data (R∼300) is comparable to but nevertheless higher than that of the Visual-Infrared Mapping Spectrometer (VIMS) (R=225) onboard the Cassini spacecraft.     

Multilevel Graph Partitioning for Three-Dimensional Discrete Fracture Network Flow Simulations

Mathematical Geosciences - We present a topology-based method for mesh-partitioning in three-dimensional discrete fracture network (DFN) simulations that takes advantage of the intrinsic...