An adaptive finite element model for wellbore breakout simulation

A finite element formulation is proposed and implemented for analysing the stability of excavated wells using the DiMaggio-Sandler constitutive elastoplastic model with a typical carbonate reservoir configuration. The quality of the finite element approximation is ensured by applying smooth curved elements adapted to the wellbore geometry, and h − p adaptive finite element meshes in the plastic zone. General purpose procedures are defined to transfer the elastoplastic deformation history to newly created integration points. A breakout damage criterion is proposed based on the second invariant of the deviatoric plastic deformation tensor. This damage criterion is used to apply a mesh movement algorithm to represent material collapse. The automatic successive application of the breakout damage criterion results in elliptical realistically looking geometries obtained in experiments reported in the literature.     

Fluid migration at the basement/sediment interface along the margin of the Southeast basin (France): implications for Pb–Zn ore formation

This study investigates the isotopic composition (C, O, S and Sr) of carbonates, sulphates and sulphide cements in the rock matrix and fracture fillings in geological formations of the Southeast basin of France, using core samples collected during the Deep Geology of France programme (GPF Ardèche theme). The Southeast basin belongs to the Alpine Tethyan margin. It is one of the thickest sedimentary basins in Europe, reaching upwards of 9 km in certain locations. The main fluid transfer from the basin is related to the large Pb–Zn Mississippi Valley-type district along the southern margin of the Massif Central block. A synthesis of the tectonic, mineralogical and petrographic investigations on the GPF boreholes shows that a major fluid circulation event occurred across the Alpine margin of Tethys during the Early Jurassic (Hettangian–Bathonian). It produced a general cementation of the rock porosity through precipitation of dolomite, sulphate and barite. Fracture fillings yield isotopic signatures distinct from the matrix cements. Matrix cements have particular characteristics, i.e. δ³⁴S and δ¹³C that agree with a marine origin. The δ³⁴S values of Permo-Carboniferous to Triassic sulphides from fracture cements are interpreted as resulting from the thermo-chemical reduction of sulphates. Fracture sulphates in the same geological formations yield δ³⁴S values that define a relatively homogeneous end-member, whose composition is similar to sulphates in the Largentière Pb–Zn ore deposit. The source of S is attributed to the Permo-Carboniferous succession. The borehole fracture fillings are attributed to a major fluid circulation stage compatible with the Early Jurassic stage identified from the geological investigation of the boreholes. The formation of the Largentière deposit is considered as resulting from the mixing of this Early Jurassic fluid with continental hydrothermal fluids circulating in a basement horst, along its margin with the sedimentary basin. Other Pb–Zn deposits may also be related to fluid migration along the basement/sedimentary cover interface in the eastern and western parts of the Massif Central. This regional fluid circulation event may represent a geodynamic marker of the Jurassic extensional phase.     

Variscan to eo-Alpine events recorded in European lower-crust zircons sampled from the French Massif Central and Corsica, France

Ion-microprobe U–Pb zircon dating of lower-crust metasedimentary granulite are reported on samples from two localities in Europe in order to determine (a) how this environment recorded the Variscan and eo-Alpine events, and (b) whether the transition between the two orogenic cycles was continuous or separated by a gap. The samples come from enclaves hosted by Miocene volcanoes at Bournac in the French Massif Central, and from the granulitic metasedimentary basement of the Alpine Santa Lucia nappe in Corsica, on the South European paleomargin of the Ligurian branch of the Tethys Sea. The zircon ages from Bournac range between 630 and 430 Ma and between 380 and 150 Ma with a major frequency peak at 285 Ma; the zircons older than 430 Ma are interpreted as detrital, whereas those younger than 380 Ma are considered to have formed by metamorphic processes after burial in the lower crust. Zircon ages from Santa Lucia range from to 356 to 157 Ma, with exception of one inherited Archean grain, and are interpreted like the younger Bournac zircons as having been formed by metamorphic processes.

In a granulite metamorphic environment, as opposed to an anatectic environment, new zircon growth can occur in the solid state. Once Zr has been incorporated into zircon, however, it is difficult to remobilize without dissolution; thus Zr available for new zircon growth must result from the breakdown of Zr-bearing minerals during prograde and/or retrograde events. In this light, the U–Pb zircon-age probability curves are interpreted as markers for major tectonometamorphic events, as suggested by the close correspondence between peaks in the curve and geological events recorded in the upper-crust, such as magma emplacement and basin subsidence.

Evidence of a tectonometamorphic gap between the Variscan and Alpine orogeneses is provided by the Santa Lucia zircon-age probability curve, which reveals a probable interlude during the Variscan–Alpine transition between 240 and 210 Ma. Here, the peak at 240 Ma is interpreted as the very beginning of crustal extension and the low at 210 Ma as a period of quiescence prior to the formation of an active margin and oceanization.     

Zinc mineral weathering as affected by plant roots

The re-vegetation of soils contaminated by potentially harmful metals is generally considered a suitable option to reduce the metal dispersion in surrounding environments. A continuous flow experiment was conducted to quantitatively assess the effect of Italian ryegrass (Lolium multiflorum Lam.) root activity on the weathering of smithsonite (ZnCO₃), a common Zn mineral. At the end of the experiment (10 days), the total amount of Zn released by smithsonite was increased by a factor of 2.25 in the presence of plants. This increase was due not only to plant uptake but also to the enhancement of the Zn release into leachates. The rate of Zn release from smithsonite to leachates was 2.9 × 10⁻⁴ μg g⁻¹ s⁻¹ and 1.5 × 10⁻⁴ μg g⁻¹ s⁻¹ in the presence and the absence of plants, respectively. The strong correlation (r = 0.95; p < 0.001) between concentrations of Zn and dissolved organic C (DOC) produced by the rhizosphere activity in leachates indicated that organic root exudates and secretions were closely involved in smithsonite weathering. Although the results are derived from laboratory study, and further in situ investigations over the long term are needed, they clearly highlighted that plants can enhance metal release into the environment by accelerating mineral weathering. Therefore, it is suggested that the ability of plants to alter metal phases in soils should be further taken into account when re-vegetation strategies are proposed for the rehabilitation of metal-polluted soils.     

Coleopteran evidence for a mosaic of environments at high altitude in the eastern Pyrénées,France, during the climatic transition between the Allerød and Younger Dryas

Late‐glacial environmental and climatic implications are inferred from an insect fauna from organic sediments infilling a palaeochannel on the banks of the River Têt, eastern Pyrénées, France. A pine cone in association with the insect fauna has been radiocarbon dated to 10 920 ± 60 yr BP, namely close to the Allerød – Younger Dryas boundary. Two distinct insect associations appear to be recognisable here. One is an assemblage typical of the high altitude forest and a second is characteristic of an alpine grassland. The close coexistence of these two assemblages is attributed to the climatic cooling towards the start of the Younger Dryas Stadial, when the forest cover broke up into remnant patches interspersed by alpine grassland. It is suggested that in a region of such high relief a mosaic of habitats may have been caused by patchy differences in insolation aspect, especially during a period of climatic deterioration. Copyright © 1999 John Wiley & Sons, Ltd.     

Structure and nuclear density distribution in the cheralite—CaTh(PO4)2: studies of its behaviour under high pressure (36?GPa)

The crystal structure of the cheralite—CaTh(PO₄)₂—has been revisited by neutron diffraction and its behaviour under high pressure investigated by X-ray diffraction up to 36?GPa. The neutron diffraction data at ambient pressure gave a more accurate determination of the Ca/Th cation position than previous XRD data, taking advantage that the neutron scattering lengths of calcium and thorium are of same order of magnitude. The nuclear density distribution was also determined using the maximum entropy method (MEM) confirming that the two cations are not located at the same position in the unit cell but are slightly displaced from one another along a specific direction in order to minimize the electrostatic repulsion with the surrounding phosphorus atoms. At high pressure, the compound did not show any phase transition or amorphization. From the evolution of the unit-cell volume as a function of the pressure, the zero-pressure bulk modulus B₀ and its pressure derivative B₀ ^′ have been determined by fitting the experimental compressibility curve to the Birch–Murnaghan equation of state. The results are B₀?=?140(2) GPa and B ₀ ^′ ?=?4.4(4) GPa.     

Present limitations of accurate satellite Doppler positioning for tectonics. An example: Djibouti

One of the possibilities of the Doppler positioning from satellite is to provide geodetic measurements continuous in time without the need for reference stations. If measurements of sufficient accuracy can be achieved they may be used to study local surface displacements in relation to tectonic activity. A Doppler receiver of the MEDOC network is located near Djibouti in the Ghoubhat-Asal rift region which corresponds to the accreting plate boundary between the Arabian and African plates. In November 1978, a seismic and volcanic crisis occured in this area. Surface geodetic measurements and levellings performed in 1973 and 1978–79, just after the crisis, reveal a 60–80 cm sinking of the graben floor and a lateral extension of about 2 meters. Here we analyse Doppler measurements for the period January 1977 to November 1980. Point positions are computed for 7 to 10 day intervals using a precise ephemeris, and a moving window analysis is applied to the data. An apparent 2 meter uplift preceding the November 1978 seismic crisis is detected at Djibouti, whereas no similar phenomenon is observed at the two closest stations, Pretoria and Uccle-Brussels. However, field observations rule out a tectonic origin for this uplift. In Djibouti, the correlation between the apparent vertical station position and the electron density in the ionospheric F-layer reveals that a bias may be induced by the third order term of the ionospheric refractive index not previously taken into account, or more probably by the ray curvature through the ionosphere. This bias is particularly strong for our data set, from a station located close to the magnetic equator, and related to a period of rapid increase in the solar activity. Although our analysis fails to detect any tectonic displacement related to the rift seismic activity, it shows that similar tectonic studies by the Doppler method will be possible once the residual ionospheric errors are removed, for example by use of higher radio frequencies.     

Challenges for integrated water resources management

During the past century, while world population tripled, the use of water increased sixfold. Irrigation accounts for 70% of global water withdrawals, industry for 20%, and municipal use for 10%. To meet the water resources challenges, a series of transitions is under way, with major implications for water management. The present paper underlines the major issues and the new role of engineers in charge of development and project management.