Thorough wetting and drainage of a peat lysimeter in a climate change scenario

A peat deposit (Zennare basin, Venice coastland, Italy) was monitored in previous field studies to investigate the hydrological response of organic soil to meteorological dynamics. Field tests and modelling predictions highlighted the risk of the complete loss of this peat layer during the next 50 years, due to oxidation enhanced by the increased frequency of warmer periods. Unfortunately, despite the considerable impacts that are expected to affect peat bogs (in this area and worldwide), only a few experimental studies have been carried out to assess the hydrologic response of peat to severe water scarcity. Because of that, an undisturbed 0.7 m³ peat monolith was collected, transferred to the laboratory and instrumented. The total weight (representative of the water content dynamics of the peat monolith as a whole), and two vertical profiles of matric potentials and water content were monitored in controlled water-scarce conditions. After an extended air-drying period, the monolith was used as an undisturbed peat lysimeter and a complete cycle of wetting and drainage was performed. Supplementary measurements of matric potential ψ and water content θ were collected by testing peat subsamples on a suction table apparatus. A set of water retention curves was determined in a range of matric potentials broader (ψ down to −7 m) than the current natural conditions in the field (minimum ψ = −1 m). While water content at saturation showed values similar to those in the original natural conditions (θ ≅ 0.8), a remarkable loss of water holding capacity (even for low potentials) has been highlighted, especially in deep layers that are now permanently below the water table. The retention curves changed shape and values, with a more pronounced hysteresis visible in an increasing distance between wetting and drying data. Hydraulic non-equilibrium between the water content and water potential could be a possible cause and it is worth modelling in future studies. The parameters of the van Genuchten retention curves were obtained for the wetting and the drying phases.     

MgAl2O4 spinels from Allende and NWA 763 carbonaceous chondrites: Structural refinement,cooling history,and trace element contents

MgAl₂O₄ spinels from Allende and NWA 763 carbonaceous chondrites were studied by X‐ray single crystal diffraction, SEM, electron microprobe, LA‐ICP‐MS, and Raman spectroscopy. Those from Allende are almost pure, but, in one case, we found a strong FeO_tot zonation. Spinels from NWA 763 show Mg‐Fe²⁺ substitutions. Almost pure MgAl₂O₄ spinels from both meteorites underwent slow cooling and reached their intracrystalline closure temperature (T_c) in the range 460–520 °C. The NWA 763 spinel with higher FeO content shows a T_c of about 720 °C. X‐ray single crystal diffraction and Raman spectroscopy suggest a slow cooling and an ordered structure with trivalent cations in M site and divalent in T site. Among the trace elements, Ti and Co are enriched with respect to the terrestrial analogs, while Mn, Ni, and Sn show intermediate values between different terrestrial occurrences. Vanadium cannot be used as a tracer of extraterrestrial origin as for Cr‐spinels, because its content is similar in extraterrestrial and terrestrial spinels. In the zoned crystal from Allende, Co show a strong zonation similar to that of FeO.     

Constraints on the bulk Lorentz factor in the internal shock scenario for gamma-ray bursts

We investigate, independently of specific emission models, the constraints on the value of the bulk Lorentz factor Γ of a fireball. We assume that the burst emission comes from internal shocks in a region transparent to Thomson scattering, and before deceleration caused by the swept-up external matter is effective. We consider the role of Compton drag in decelerating fast-moving shells before they interact with slower ones, thus limiting the possible differences in the bulk Lorentz factor of shells. Tighter constraints on the possible range of Γ are derived by requiring that the internal shocks transform more than a few per cent of the bulk energy into radiation. Efficient bursts may require a hierarchical scenario, where a shell undergoes multiple interactions with other shells. We conclude that fireballs with average Lorentz factors larger than 1000 are unlikely to give rise to the observed bursts.     

Structure of magnetite (Fe<Subscript>3</Subscript>O<Subscript>4</Subscript>) above the Curie temperature: a cation ordering study

A pristine magnetite (Fe₃O₄) specimen was studied by means of Neutron Powder Diffraction in the 273–1,073 K temperature range, in order to characterize its structural and magnetic behavior at high temperatures. An accurate analysis of the collected data allowed the understanding of the behavior of the main structural and magnetic features of magnetite as a function of temperature. The magnetic moments of both tetrahedral and octahedral sites were extracted by means of magnetic diffraction up to the Curie temperature (between 773 and 873 K). A change in the thermal expansion coefficient around the Curie temperature together with an increase in the oxygen coordinate value above 700 K can be observed, both features being the result of a change in the thermal expansion of the tetrahedral site. This anomaly is not related to the magnetic transition but can be explained with an intervened cation reordering, as magnetite gradually transforms from a disordered configuration into a partially ordered one. Based on a simple model which takes into account the cation-oxygen bond length, the degree of order as a function of temperature and consequently the enthalpy and entropy of the reordering process were determined. The refined values are ΔH⁰ = −23.2(1.7) kJ mol⁻¹ and ΔS⁰ = −16(2) J K⁻¹ mol⁻¹. These results are in perfect agreement with values reported in literature (Mack et al. in Solid State Ion 135(1–4):625–630, 2000; Wu and Mason in J Am Ceramic Soc 64(9):520–522, 1981).     

Robust resolution of Kepler’s equation in all eccentricity regimes

The singularity for the big bang state can be represented using the generalized anisotropic Friedmann equation, resulting in a system of differential equations in a central force field. We study the regularizability of this singularity as a function of a parameter, the equation of state, w. We prove that for w > 1 it is regularizable only for w satisfying relative prime number conditions, and for w ≤ 1 it can always be regularized. This is done by using a McGehee transformation, usually applied in the three and four-body problems. This transformation blows up the singularity into an invariant manifold. The relationship of this result to other cosmological models is briefly discussed.     

Structural changes in the FeAl2O4–FeCr2O4 solid solution series and their consequences on natural Cr-bearing spinels

The influence of Al–Cr substitution on the spinel structure was studied in synthetic single crystals belonging to the FeCr₂O₄–FeAl₂O₄ series produced by flux growth at 1,000–1,300 °C in controlled atmosphere. Samples were characterized by single-crystal X-ray diffraction, electron microprobe analyses and Mössbauer spectroscopy. Crystals of sufficient size and quality for single-crystal X-ray diffraction were obtained in the ranges Chr_0–0.45 and Chr_70–100 but not for intermediate compositions, possibly due to a reduced stability in this range. The increase in chromite component leads to an increase in the cell edge from 8.1534 (6) to 8.3672 (1) Å and a decrease in the u parameter from 0.2645 (2) to 0.2628 (1). Chemical analyses show that Fe²⁺ is very close to 1 apfu (0.994–1.007), Al is in the range 0.0793–1.981 apfu, Cr between 0 and 1.925 apfu. In some cases, Fe³⁺ is present in amounts up to 0.031 apfu. Spinels with intermediate Cr content (Chr component between 40 and 60) are strongly zoned with Cr-rich cores and Cr-poor rims. Mössbauer analyses on powdered spinels of the runs from which single crystal has been used for X-ray structural data show values of Fe³⁺/Fe_tot consistently larger than that calculated by EMPA on single crystals, presumably due to chemical variation between single crystals from the same runs. The synthesis runs ended at a temperature of 1,000 °C, but it is possible that cation ordering continued in the Cr-poor samples towards lower temperatures, possibly down to 700 °C.     

Inferring groundwater system dynamics from hydrological time-series data

Abstract

The problem of identifying and reproducing the hydrological behaviour of groundwater systems can often be set in terms of ordinary differential equations relating the inputs and outputs of their physical components under simplifying assumptions. Conceptual linear and nonlinear models described as ordinary differential equations are widely used in hydrology and can be found in several studies. Groundwater systems can be described conceptually as an interlinked reservoir model structured as a series of nonlinear tanks, so that the groundwater table can be schematized as the water level in one of the interconnected tanks. In this work, we propose a methodology for inferring the dynamics of a groundwater system response to rainfall, based on recorded time series data. The use of evolutionary techniques to infer differential equations from data in order to obtain their intrinsic phenomenological dynamics has been investigated recently by a few authors and is referred to as evolutionary modelling. A strategy named Evolutionary Polynomial Regression (EPR) has been applied to a real hydrogeological system, the shallow unconfined aquifer of Brindisi, southern Italy, for which 528 recorded monthly data over a 44-year period are available. The EPR returns a set of non-dominated models, as ordinary differential equations, reproducing the system dynamics. The choice of the representative model can be made both on the basis of its performance against a test data set and based on its incorporation of terms that actually entail physical meaning with respect to the conceptualization of the system.

Citation Doglioni, A., Mancarella, D., Simeone, V. & Giustolisi, O. (2010) Inferring groundwater system dynamics from hydrological time-series data. Hydrol. Sci. J. 55(4), 593–608.     

Evidence for subaqueously resedimented sulphate evaporites on Mars

This article documents the clastic nature of sulphate evaporite beds in the Tithonium Chasma located in the Valles Marineris region of Mars. These beds form a stratified succession characterised by very thick interbedded channel-fill breccia bodies. We infer that the bouldery channel-fills were deposited by voluminous mass-flow processes occurring in a relatively deep subaqueous environment. The redeposition of the coarse-grained evaporite would have responded to phases of high denudation rates in rapidly uplifting hinterlands. Tectonic activity also caused the diapiric uprise and exhumation of evaporite diapirs within the Valles Marineris chasmata, where the apparently young and well development karstic landforms probably formed during the late Amazonian age. These new data strongly suggest the deposition of both primary and resedimented evaporites in a marginal basin area, which effectively restricted ocean access through the proposed “proto-Valles Marineris Strait”. The associated ocean may be the “Ocean Borealis” of Late Noachian-Early Hesperian age.     

Patterns of decadal-scale Arctic warming events in simulated climate

Pronounced positive decadal-scale temperature anomalies occurred in the Arctic region in the first half of the twentieth century, an episode known as the early twentieth century warming (ETCW). Analyzing a 3,000-year unperturbed climate simulation performed with the Max Planck Institute Earth System Model, we demonstrate that internal variability of the Northern Hemisphere climate system is sufficient to reproduce warm events matching the observed ETCW. We perform a superposed epoch analysis on simulated data and identify 26 Arctic warming episodes compatible with the ETCW. The simulated events reproduce, in their ensemble average, magnitude as well as spatial and temporal extent of the observed ETCW. In individual realizations, the ETCW-like events indicate that different patterns of internally generated decadal Arctic warming are possible, including pan-Arctic warming events. We investigate the dynamics that typically lead to the simulated warming events: positive oceanic heat transport anomalies that form in the North Atlantic initialize the warming events and trigger an ocean-ice-albedo feedback in the Barents Sea region. The consequent reduction in sea-ice extent leads to enhanced multi-year surface warming through strengthened ocean heat release to the atmosphere. The oceanic heat transport anomalies reduce to pre-event levels around the year of the maximum warming. However, the warming events typically lasts for another 5–7 years until the sea-ice extent recovers to pre-event conditions.     

The DRASTIC-Sg model: an extension to the DRASTIC approach for mapping groundwater vulnerability in aquifers subject to differential land subsidence,with application to Mexico City

Mexico City relies on groundwater for most of its domestic supply. Over the years, intensive pumping has led to significant drawdowns and, subsequently, to severe land subsidence. Tensile cracks have also developed or reactivated as a result. All such processes cause damage to urban infrastructure, increasing the risk of spills and favoring contaminant propagation into the aquifer. The effects of ground deformation are frequently ignored in groundwater vulnerability studies, but can be relevant in subsiding cities. This report presents an extension to the DRASTIC methodology, named DRASTIC-Sg, which focuses on evaluating groundwater vulnerability in urban aquifers affected by differential subsidence. A subsidence parameter is developed to represent the ground deformation gradient (Sg), and then used to depict areas where damage risk to urban infrastructure is higher due to fracture propagation. Space-geodetic SqueeSAR data and global positioning system (GPS) validation were used to evaluate subsidence rates and gradients, integrating hydrogeological and geomechanical variables into a GIS environment. Results show that classic DRASTIC approaches may underestimate groundwater vulnerability in settings such as the one at hand. Hence, it is concluded that the Sg parameter is a welcome contribution to develop reliable vulnerability assessments in subsiding basins.