Surface tension effects on energy dissipation by small scale,experimental breaking waves

Much of the existing knowledge about breaking waves comes from physical model experiments scaled using Froude's law. A widely held assumption is that surface tension effects are not significant at typical laboratory scales and specifically for waves longer than 2 m. Since, however, smaller wavelengths are not untypical in small to medium scale laboratory facilities, a consideration of surface tension effects is indeed important. Although some emphasis has been given in the past, little is known regarding the importance of surface tension following impingement of the breaking-wave crest and especially on the overall energy dissipation by laboratory breaking waves.     

MgAl2O4 spinels from Allende and NWA 763 carbonaceous chondrites: Structural refinement,cooling history,and trace element contents

MgAl₂O₄ spinels from Allende and NWA 763 carbonaceous chondrites were studied by X‐ray single crystal diffraction, SEM, electron microprobe, LA‐ICP‐MS, and Raman spectroscopy. Those from Allende are almost pure, but, in one case, we found a strong FeO_tot zonation. Spinels from NWA 763 show Mg‐Fe²⁺ substitutions. Almost pure MgAl₂O₄ spinels from both meteorites underwent slow cooling and reached their intracrystalline closure temperature (T_c) in the range 460–520 °C. The NWA 763 spinel with higher FeO content shows a T_c of about 720 °C. X‐ray single crystal diffraction and Raman spectroscopy suggest a slow cooling and an ordered structure with trivalent cations in M site and divalent in T site. Among the trace elements, Ti and Co are enriched with respect to the terrestrial analogs, while Mn, Ni, and Sn show intermediate values between different terrestrial occurrences. Vanadium cannot be used as a tracer of extraterrestrial origin as for Cr‐spinels, because its content is similar in extraterrestrial and terrestrial spinels. In the zoned crystal from Allende, Co show a strong zonation similar to that of FeO.     

In situ high-temperature X-ray and neutron powder diffraction study of cation partitioning in synthetic Mg(Fe<Subscript>0.5</Subscript>Al<Subscript>0.5</Subscript>)<Subscript>2</Subscript>O<Subscript>4</Subscript> spinel

The intra-crystalline cation partitioning over T- and M-sites in a synthetic Mg(Fe,Al)₂O₄ spinel sample has been determined as a function of temperature by Rietveld structure refinements from powder diffraction data, combining in situ high-temperature neutron powder diffraction (NPD; POLARIS diffractometer, at ISIS, Rutherford Appleton Laboratory, UK), to determine the Mg and Al occupancy factors, with in situ high-temperature X-ray powder diffraction, to fix the Fe³⁺ distribution. The results obtained agree with a two-stage reaction, in which an initial exchange between Fe³⁺ and Mg, the former leaving and the latter entering tetrahedral sites, is successively followed by a rearrangement involving also Al. The measured cation distribution has then been compared and discussed with that calculated by the Maximum Configuration Entropy principle, for which only NPD patterns have been used. The cation partitioning has finally been interpreted in the light of the configuration model of O’Neill and Navrotsky.     

Different flavors of the Atlantic Multidecadal Variability

We investigate how differently-constructed indices for North Atlantic sea-surface temperatures (NASSTs) describe the “Atlantic Multidecadal Variability” (AMV) in a suite of unperturbed as well as externally-forced millennial (pre-industrial period) climate simulations. The simulations stem from an ensemble of Earth system models differing in both resolution and complexity. Different criteria exist to construct AMV indices capturing different aspects of the phenomenon. Although all representations of the AMV maintain strong multidecadal variability, they depict different characteristics of simulated low-frequency NASST variability, evolve differently in time and relate to different hemispheric teleconnections. Due to such multifaceted signatures in the ocean-surface as well as in the atmosphere, reconstructions of past AMV may not univocally reproduce multidecadal NASST variability. AMV features under simulated externally-forced pre-industrial climate conditions are not unambiguously distinguishable, within a linear framework, from AMV features in corresponding unperturbed simulations. This prevents a robust diagnosis of the simulated pre-industrial AMV as a predominantly internal rather than externally-forced phenomenon. We conclude that a multi-perspective assessment of multidecadal NASSTs variability is necessary for understanding the origin of the AMV, its physics and its climatic implications.     

Influence of the circumglobal wave-train on European summer precipitation

We investigate European summer (July–August) precipitation variability and its global teleconnections using the NCEP/NCAR reanalysis data (1950–2010) and a historical Coupled Model Intercomparison Project climate simulation (1901–2005) carried out using the ECHAM6/MPIOM climate model. A wavelike pattern is found in the upper tropospheric levels (200 hPa) similar to the summer circumglobal wave train (CGT) extending from the North Pacific to the Eurasian region. The positive phase of the CGT is associated with upper level anomalous low (high) pressure over western (eastern) Europe. It is further associated with a dipole-like precipitation pattern over Europe entailing significantly enhanced (reduced) precipitation over the western (eastern) region. The anomalous circulation features and associated summer precipitation pattern over Europe inverts for the negative CGT phase. Accordingly, the global teleconnection pattern of a precipitation index summarizing summer precipitation over Western Europe entails an upper level signature which consists of a CGT-like wave pattern extending from the North Pacific to Eurasia. The imprint of the CGT on European summer precipitation is distinct from that of the summer North Atlantic Oscillation, despite the two modes of variability bear strong similarities in their upper level atmospheric pattern over Western Europe. The analysis of simulated CGT features and of its climatic implications for the European region substantiates the existence of the CGT-European summer precipitation connection. The summer CGT in the mid-latitude therefore adds to the list of the modes of large-scale atmospheric variability significantly influencing European summer precipitation variability.     

Discrimination between wave‐ravinement surfaces and bedset boundaries in Pliocene shallow‐marine deposits,Crotone Basin,southern Italy: An integrated sedimentological,micropalaeontological and mineralogical approach

The lower Pliocene Belvedere Formation, cropping out in the Crotone Basin, southern Italy, exhibits a metre‐scale to decametre‐scale shallow‐marine cyclicity that shares features of both high‐frequency sequences linked to shoreline shifts and controlled by minor relative sea‐level and/or sediment supply changes, and sedimentological cycles unrelated to shoreline shifts. In order to better understand the high‐frequency sequence stratigraphic framework of this succession, an integration of sedimentological, micropalaeontological (micro‐foraminifera assemblages) and mineralogical (heavy mineral abundance) data is used. From a sedimentological/stratigraphic point of view, wave‐ravinement surfaces bounding high‐frequency sequences, and associated substrate‐controlled ichnofacies, are prominent in outcrop and document environmental and water‐depth changes, whereas bedset boundaries separating sedimentological cycles have a more subtle field appearance and are only associated with changes of environmental energy. Moreover, condensed deposits are present only above wave‐ravinement surfaces, and the high‐frequency sequences bounded by these surfaces have a thickness that is an order of magnitude greater than that of the bedsets. Micro‐foraminifera assemblages may change, and the content of heavy minerals usually increases, across wave‐ravinement surfaces, whereas both parameters do not change significantly across bedset boundaries. The abundance of heavy minerals is systematically higher, with respect to the underlying and overlying deposits, in the condensed shell beds that overlie wave‐ravinement surfaces. An integrated sedimentological, micropalaeontological and mineralogical approach represents a powerful tool to discriminate between wave‐ravinement surfaces bounding high‐frequency sequences and bedset boundaries, and in general to investigate at the intra high‐frequency sequence scale. This integrated approach is expected to be very useful in the study of potentially all shallow‐marine successions composed of small‐scale cycles, in order to delineate a detailed sequence stratigraphic framework and understand the factors that controlled the cyclicity.