Hydrostratigraphic framework and hydrogeological behaviour of the Mancha Oriental System (SE Spain)

The Mancha Oriental System (MOS) has a surface area of 7,260 km², making it one of the largest carbonate aquifer systems in Spain. The system sustains about 1,000 km² of irrigated crops and supplies groundwater to 275,000 inhabitants. The economic transformation brought about by the development of extensive irrigated cropland has led to a water-balance disequilibrium of about 75 million m³/year. This input–output deficit has negative consequences in the quantity and quality of the available resources, in the river–aquifer relationship, and in the associated ecosystems as well. To understand the hydrogeological behaviour of the system, it is necessary to design a conceptual model. Further, the conceptualisation of a groundwater flow system is a requirement of the European Water Framework Directive for the characterisation of groundwater bodies. The robustness of the conceptual model depends heavily on the user capability of representing the real system. In this work, a multidisciplinary approach has been used to represent the three-dimensional geological framework and the groundwater flow conceptualisation of the MOS. Data management and three-dimensional visualisation have been carried out by means of geographical information system (GIS) tools and software for contouring and three-dimensional surface mapping.     

Application of time- and magnitude-predictable model for long-term earthquake prediction in Iran

The regional time- and magnitude-predictable model has been applied successfully in diverse regions of the world to describe the occurrence of main shocks. In the current study, the model has been calibrated against the historical and instrumental catalog of Iranian earthquakes. The Iranian plateau is divided into 15 seismogenic provinces; then, the interevent times for strong main shocks have been determined for each one. The empirical relations reported by Papazachos et al. (Tectonophysics 271:295–323, 1997a) for the Alpine–Himalayan belt (including Iran) were adopted except for the constant terms that were calculated separately for every seismotectonic area. By using the calibrated equations developed for the study area and taking into account the occurrence time and magnitude of the last main shocks in each seismogenic source, the time-dependent conditional probabilities of occurrence P(?t) of the next main shocks during next 10, 20, 30, 40 and 50 years as well as the magnitude of the expected main shocks (M _f) have been estimated. The immediate probability (within next 10 years) of a large main shock is estimated to be high and moderate (>35 %) in all regions except zones 9 (M _f = 5.8) and 15 (M _f = 6.1). However, it should be noted that the probabilities have been estimated for different M _f values in 15 regions. Comparing the model predictions with the actual earthquake occurrence rates shows the good performance of the model for Iranian plateau.     

Electrical and electromagnetic surveys to locate possible causes of water seepage to ground surface at a quarry open pit near Helwan city,Egypt

Water seepage to ground surface at a limestone quarry located at Wadi Garawy about 20 km south-east of Helwan city in Egypt posed a real threat to the mining activity at the quarry. The quarry area is known to be very dry for decades and away from water utilities and infrastructures that may cause water leaks to the quarry. Geophysical investigation including 1D Vertical Electrical Sounding (VES), 2D Electrical Resistivity Tomography (ERT) and 1D Transient Electromagnetic (TEM) surveys were conducted to characterize the rock sequence and locate what could be a possible source of water seepage to the quarry. The resistivity profiles generated from the VES and TEM surveys mapped the rock units in the area down to depths exceeded 100 m. The ERT profiles acquired from the quarrying zone close to the water seepage spot have imaged the top of groundwater level at few meters below the ground surface at the quarry open pit. The spot of groundwater seepage seemed to occur at an area of limestone dissolution that were filled by finer sediments. The finer sediments acted as a hydrological conduit that allowed an upward seepage of groundwater to ground surface under the capillary action effect.     

A ROSAT survey of Wolf–Rayet galaxies — II. The extended sample

We present results from an ongoing X-ray survey of Wolf–Rayet (WR) galaxies, a class of objects believed to be very young starbursts. This paper extends the first X-ray survey of WR galaxies by Stevens &38; Strickland by studying WR galaxies identified subsequent to the original WR galaxy catalogue of Conti.   Out of a sample of 40 new WR galaxies a total of 10 have been observed with the ROSAT PSPC, and of these seven have been detected (NGC 1365, NGC 1569, I Zw 18, NGC 3353, NGC 4449, NGC 5408 and a marginal detection of NGC 2366). Of these, all are dwarf starbursts except for NGC 1365, which is a barred spiral galaxy possibly with an active nucleus. We also report on observations of the related emission-line galaxy IRAS 0833+6517.   The X-ray properties of these galaxies are broadly in line with those found for the original sample; they are X-ray overluminous compared with their blue luminosity and have thermal spectra with typically kT  ∼ 0.4 − 1.0 keV. There are some oddities: NGC 5408 is very overluminous in X-rays, even compared with other WR galaxies; I Zw 18 has a harder X-ray spectrum; NGC 1365, although thought to contain an active nucleus, has X-ray properties that are broadly similar to other WR galaxies, and we suggest that the X-ray emission from NGC 1365 is due to starburst activity.   A good correlation between X-ray and blue luminosity is found for the WR galaxy sample as a whole. However, when just dwarf galaxies are considered there is little evidence of correlation. We discuss the implications of these results on our understanding of the X-ray emission from WR galaxies and suggest that the best explanation for the X-ray activity is starburst activity from a young starburst region.     

Soft X-ray spectroscopic studies of the reaction of fractured pyrite surfaces with Cr(VI)-containing aqueous solutions

We have used synchrotron-based soft X-ray core-level photoemission and adsorption spectroscopies to study the reaction of aqueous sodium chromate solutions with freshly fractured pyrite surfaces. Pyrite surfaces were reacted with 50 μM sodium chromate solution at pH 7 for reaction times between 1 min and 37 hr. Additional experiments were performed at pH 2 and pH 4 with 50 μM sodium chromate solutions and at pH 7 with 5 mM solutions. At chromate concentrations of 50 μM, all chromium present on the pyrite surface was in the form of Cr(III), while at 5 mM, both Cr(III) and Cr(VI) were present at the pyrite surface. Minor quantities of oxidized sulfur species (sulfate, sulfite, and zero-valent sulfur) were identified as reaction products on the pyrite surface. The amount of oxidized sulfur species observed on the surface was greater when pyrite was reacted with 5 mM Cr(VI) solutions because the rate of chromium deposition exceeded the rate of dissolution of pyrite oxidation products, effectively trapping Cr(VI) and oxidized sulfur species in an overlayer of iron(III)-containing Cr(III)-hydroxide. This work shows that pyrite, an extremely cheap and readily available waste material, may be suitable for the removal of hexavalent chromium from acidic to circumneutral waste streams. The reduced chromium ultimately forms a coating on the pyrite surface, which passivates the pyrite surface towards further oxidation.     

Toxic chemicals in Canadian fish-eating birds

Cross-country comparison of DDE and PCB residue levels in cormorant, gull and tern eggs in Canada reveal that bird populations at the Great Lakes are most contaminated with those pollutants. DDE levels have been correlated with reproductive failure in Double-crested Cormorants in the Great Lakes with eggshell thinning as a major factor. Low reproductive success in Herring Gull colonies at Lake Ontario is associated with high chlorinated hydrocarbon levels in eggs. Fish-eating birds in the Wabigoon River system, northwestern Ontario, are among the most known mercury contaminated birds. It is suggested that the effects of mercury on the reproduction of fish-eating birds should be further examined there.Fish-eating birds occupy the highest levels of the food web and magnification of toxic chemicals through prey organisms in this web makes those birds vulnerable to the effects of environmental contaminants. Since fish-eating birds are present everywhere in Canada's freshwater and marine habitats and occupy various niches there, they may serve as pollution indicators in various food chains of our aquatic environment. Colonial birds are especially valuable indicators as pollution effects on total bird populations can be studied. Baseline information on fish-eating bird populations should now be collected everywhere in Canada for measuring present and future effects of environmental pollutants, as well as other man-made disturbances on their populations.     

A mechanism for the production of planetary nebulae

C¹² stars in the range 1.04–1.55M are evolved to simulate the core evolution of the possible precursors of planetary nebulae. The nuclear shell burning in stars above 1.2M advances to within about 0.2M of the surface, where the intense radiation interacts with the surface matter and causes mass loss. Comparison between our theoretical results and observations suggests that this may be a mechanism by which planetary nebulae are formed.Presented at the Trieste Colloquium on Mass Loss from Stars, September 12–16, 1968.     

Stellar polarization and the structure of the magnetic field of our galaxy

The stellar polarization data have been examined using a new catalogue containing accurate stellar distances. On the assumption of a magnetic alignment hypothesis, correlations on the larger distance scale indicate the existence of a dominant regular magnetic field, although its characteristics are difficult to determine. Within 500 pc its direction is towardsl45° and beyond this towardsl60°, though it is clear that such a longitudinal model is too simple. There is also some evidence for an inclination of this field to the galactic plane. The distribution of the polarization vectors away from the galactic plane has been examined and it is proposed that the two largest loop structures, previously identified as Supernova remnants, are linked by the regular field. Incremental polarization maps have been produced but they show little correlation with the spiral structure. The polarization appears to be saturated at about 1 kpc from the Sun, which is explained as the result of an observational selection effect. On the smaller distance scales an autocorrelation analysis in different directions has revealed no obvious coherence in the irregular component on scales greater than 50 pc.