Use of Surface Waves in Statistical Correlations of Shear Wave Velocity and Penetration Resistance of Chennai Soils

Shear wave velocity (V _s) is one of the most important input parameter to represent the stiffness of the soil layers. It is preferable to measure V _s by in situ wave propagation tests, however it is often not economically feasible to perform the tests at all locations. Hence, a reliable correlation between V _s and standard penetration test blow counts (SPT-N) would be a considerable advantage. This paper presents the development of empirical correlations between V _s and SPT-N value for different categories of soil in Chennai city characterized by complex variation of soil conditions. The extensive shear wave velocity measurement was carried out using Multichannel Analysis of Surface Waves (MASW) technique at the sites where the SPT-N values are available. The bender element test is performed to compare the field MASW test results for clayey soils. The correlations between shear wave velocity and SPT-N with and without energy corrections were developed for three categories of soil: all soils, sand and clay. The proposed correlations between uncorrected and energy corrected SPT-N were compared with regression equations proposed by various other investigators and found that the developed correlations exhibit good prediction performance. The proposed uncorrected and energy corrected SPT-N relationships show a slight variation in the statistical analysis indicating that both the uncorrected and energy corrected correlations can predict shear wave velocity with equal accuracy. It is also found that the soil type has a little effect on these correlations below SPT-N value of about 10.     

Age,provenance and tectonic setting of the Canastra and Ibiá Groups (Brasília Belt,Brazil): Implications for the age of a Neoproterozoic glacial event in central Brazil

The Brasília Belt is one of the best preserved Neoproterozoic orogens in Brazil. It comprises a thick Meso–Neoproterozoic sedimentary/metasedimentary pile including the Canastra and Ibiá Groups, which are the object of this study. The Canastra Group constitutes a regressive sedimentary sequence made mainly of greenschist-facies metapelitic and metapsammitic rocks, including phyllite, sandy metarhythmite and quartzite, with minor intercalations of limestone, as well as carbonaceous and carbonatic phyllite. The Ibiá Group is formed of a basal diamictite followed upwards by phyllites and calc-schists. It rests on an erosional unconformity on top of the Canastra Group.A provenance study based on U–Pb zircon geochronology on a selection of seven samples helped to establish the various source areas and maximum depositional ages of the original sediments. In addition, seven new Sm–Nd analyses are presented and discussed together with previously published data.LAM-ICP-MS U–Pb dating of detrital zircon grains indicates a maximum depositional age of the Canastra and Ibiá Groups of ca. 1030 and 640 Ma, respectively. The provenance signature of the Canastra Group comprises a wide range of detrital zircon ages with a significant Paleoproterozoic component (～1.8 and ～2.1 Ga) and an important Mesoproterozoic source (1.1–1.2 Ga), especially for the Paracatu Formation, indicating the São Francisco–Congo Craton as main source. These provenance data, in particular the absence of Neoproterozoic zircon grains, typical of the active margin of the Brasília Belt, allied with the homogeneous Paleoproterozoic T_DM values are consistent with the previous interpretation that the Canastra Group represents a sedimentary sequence deposited on a passive margin setting.Zircon grains from the diamictite of the Ibiá Group yielded ages ranging from 936 to 2500 Ma. In contrast, the overlying calc-phyllite of the Rio Verde Formation reveals a dominant Neoproterozoic provenance pattern with important peaks at 665, 740 and 850 Ma. The São Francisco-Congo Craton and Goiás Magmatic Arc are, most probably, the two main source regions for the Ibiá Group which may represent, therefore, a former fore- or back-arc sedimentary sequence. Tectonically, therefore, the Ibiá Group is equivalent to the Araxá Group exposed in central Goiás and both represent syn-orogenic sedimentary sequences formed with important detrital contributions derived from the Neoproterozoic Goiás Arc.The provenance data presented here indicate that the Cubatão Formation is most possibly representative of a Marinoan or younger glacial event.     

Sea-level, sediment supply and coastal changes: Examples from the coast of Ireland

Sediment supply and pre-existing shoreline morphology are crucial factors in controlling coastal changes due to sea-level rise. Using examples from both southeast and northeast Ireland, it can be shown that sea-level change may trigger a sequence of events which leads to both static and dynamic shoreline equilibrium. Cliff erosion and longshore sediment movement in east Co. Wexford has led to injection of sediment onto the shelf, and the growth, under both wave and tide regimes, of linear offshore shoals. These shoals now control the pattern of shoreline erosion and provide a template for possible stepwise evolution of the coast under any future sea-level rise. In contrast, the nearby coast of south Co. Wexford comprises a series of coarse clastic barriers moving monotonously onshore, via overwash processes. Here the behavior of the barrier is conditioned by the antecedent morphology of both the beach face and stream outlet bedforms. Finally, the rock platform coast of Co. Antrim presents a far more resistant shoreline to incident marine processes, yet even here there is strong evidence of present process control over so-called ‘raised’ platforms and embayments. It is concluded that coastal sediment supply and dynamics, together with coastal morphology and its interaction with waves, present a far more complex variety of sea-level indicators than is normally acknowledged.     

Correlated Nd,Sr and Pb isotope variation in Walvis Ridge basalts and implications for the evolution of their mantle source

Basement intersected in DSDP holes 525A, 528 and 527 on the Walvis Ridge consists of submarine basalt flows and pillows with minor intercalated sediments. These holes are situated on the crest and mid and lower northwest flank of a NNW-SSE-trending ridge block which would have closely paralleled the paleo mid-ocean ridge [13, 14]. The basalts were erupted approximately 70 m.y. ago, an age equivalent to that of immediately adjacent oceanic crust in the Angola Basin and consistent with formation at the paleo mid-ocean ridge [14]. The basalt types vary from aphyric quartz tholeiites on the ridge crest to highly plagioclase phyric olivine tholeiites on the ridge flank. These show systematic differences in incompatible trace element and isotopic composition. Many element and isotope ratio pairs form systematic trends with the ridge crest basalts at one end and the highly phyric ridge flank basalts at the other.The low ¹⁴³Nd/¹⁴⁴Nd (0.51238), ²⁰⁶Pb/²⁰⁴Pb (17.54), ²⁰⁸Pb/²⁰⁴Pb (15.47), ²⁰⁸Pb/²⁰⁴Pb (38.14) and high⁸⁷Sr/⁸⁶Sr (0.70512) ratios of the ridge crest basalts suggest derivation from an old Nd/Sm-, Rb/Sr- and Pb/U-enriched mantle source. This isotopic signature is similar to that of alkaline basalts on Tristan de Cunha but offset to significantly lower Nd and Pb isotopic ratios. The isotopic ratio trends may be extrapolated beyond the ridge flank basalts with higher¹⁴³Nd/¹⁴⁴Nd (0.51270), ²⁰⁶Pb/²⁰⁴Pb (18.32), ²⁰⁷Pb/²⁰⁴Pb (15.52), ²⁰⁸Pb/²⁰⁴Pb (38.77) and lower ⁸⁷Sr/⁸⁶Sr (0.70417) ratios in the direction of increasingly Nd/Sm-, Rb/Sr- and Pb/U-depleted source compositions. These isotopic correlations are equally consistent with mixing od depleted and enriched end member melts or partial melting of an inhomogenous, variably enriched mantle source. However, observe ZrBaNbY interelement relationships are inconsistent with any simple two-component model of magma mixing, as might result from the rise of a lower mantle plume through the upper mantle. Incompatible element and Pb isotopic systematics also preclude extensive involvement of depleted (N-type) MORB material or its mantle sources. In our preferred petrogenetic model the Walvis Ridge basalts were derived by partial melting of mantle similar to an enriched (E-type) MORB source which had become heterogeneous on a small scale due to the introduction of small-volume melts and metasomatic fluids.     

Anreicherung von Metallionen durch Membranfiltration von Polyelektrolytkomplexen

The separation of heavy metals by complexation with macromolecular water-soluble agents and subsequent ultrafiltration is described. The method can be expected to join common techniques of metal separation like liquid-liquid extraction, adsorption, redox reaction or liquid membrane permeation. Reactions between metal ions and polymer phases are characterized as pH-dependent distribution equilibria illustrated at a propene-maleic acid copolymer as an example. The complexation behaviour of the substance under study is governed by isotherms of the saturation type. Attempts proved to be successful to calculate break-through constants as well as saturation capacities from batch-type studies and dynamic measurements by transferring the laws of adsorption and ion exchange, respectively, to the ultrafiltration process. The quantities of fixed metals amounting to about 2.5 mmol/g were found to be in the range of moderate adsorbents. A solution consisting of 3 solutes has been tested to get more detailed information on mixture behaviour as compared to single component systems. In the long run, the proposed method should provide an additional variant for the extraction and concentration of metal ions from diluted aqueous solutions.     

Formation of atoll garnets in the UHP eclogites of the Tso Morari Complex,Ladakh, Himalaya

The eclogites of the Tso Morari Complex, Ladakh, NW Himalayas preserve both garnets with spectacular atoll textures, as well as whole porphyroblastic garnets. Whole garnets are euhedral, idiomorphic and enclose inclusions of amphibole, phengite and zoisite within the cores, and omphacite and quartz/coesite towards the rims. Detailed electron microprobe analyses and back-scattered electron images show well-preserved prograde zoning in the whole garnets with an increase in Mg and decrease in Ca and Mn contents from the core to the rim. The atoll garnets commonly consist of euhedral ring over island/peninsular core containing inclusions of phengite, omphacite and rarely amphibole between the core and ring. Compositional profiles across the studied atoll grains show elemental variations with higher concentrations of Ca and Mn with low Mg at the peninsula/island cores; contrary to this low Ca, Mn and high Mg is observed at the outer rings. Temperature estimates yield higher values at the Mg-rich atoll garnet outer rings compared to the atoll cores. Atoll garnet formation was favoured by infiltration of fluid formed due to breakdown of hydrous phases, and/or the release of structurally bounded OH from nominally anhydrous minerals at the onset of exhumation. Infiltration of fluids along pre-existing fracture pathways and along mineral inclusion boundaries triggered breakdown of the original garnet cores and released elements which were subsequently incorporated into the newly-grown garnet rings. This breakdown of garnet cores and inward re-growth at the outer ring produced the atoll structure. Calibrated geo-thermobarometers and mineral equilibria reflect that the Tso Morari eclogites attain peak pressures prior to peak temperatures representing a clockwise path of evolution.     

Rates of aerodynamic entrainment in a developing boundary layer

Despite its significance for inception of grain transport by wind, the initial dislodgement of grains from a static surface by aerodynamic forces of drag and lift in the absence of grain collision has received little attention. This paper describes a series of wind-tunnel experiments in which the erosion of narrow strips of loose grains from the roughened surface of a flat plate exposed to a range of wind speeds was examined. The progressive downwind development of the boundary layer over the plate provided a range of airflow conditions which permitted systematic evaluation of grain entrainment rates arising from purely aerodynamic forces. Use of closely graded size fractions in flat, single grain layers resting on identical, fixed grain support eliminated the effects of surface irregularities and impacts from saltation. Results show that erosion of strips of loose grains develops with time according to an inverse exponential function in which the entrainment rate time constant relates to Shields dimensionless shear stress function. An empirical expression defining aerodynamic entrainment rate in terms of rate of strip erosion is derived and comparisons are made between present and published data. The need for additional data to resolve several questions raised by the present investigation is stressed. In addition, a simple, objective technique for accurate determination of the aerodynamic entrainment threshold of any loose, granular sediment is proposed.     

Typochemical features of the rare-earth component of monazites from the Ilmen’ reserve

By means of X-ray fluorescence with synchroton radiation (XRF-SR), the contents of all 14 rare-earth elements (REEs) and that of Y were determined in 12 monazite samples from different veins in the Ilmen’ Reserve (South Urals). It was found that, in anphibole-micaceous-carbonate mineralized zones within metabasites, monazites were pronouncedly depleted in middle and, especially, in heavy rare-earth elements (HREEs) (from 0.25% and below for Sm, 0.08% or below for Gd, 0.03% for Dy, 0.01% for Er and Tm, below 0.005% for Yb, trace amounts of other odd HREEs, at a Y content of 0.1% or below). Monazites from the veins of granitic pegmatites were characterized by vastly decreased La contents (4–8 compared to 11–13% for the group above), at high values for Pr (to 3%), Nd (to 8%), Sm (to 1.3%), Gd (to 1.1%), Dy (to 0.9%), Er (to 0.2%), Yb (to 0.05%), and Y (from 0.2 to 1.7%). Here, the values for odd REEs are also quite high compared to the group above (to 0.2% for Tb, to 0.08% for Ho, and to 0.1% for Tm).

     

Time relationship between regional deformation and fabric development in the Peralimala pluton,South India — Inferences from magnetic fabric

Anisotropy of magnetic susceptibility (AMS) is investigated in samples of Peralimala (PM) pluton (ca. 550 Ma) and adjacent gneiss, gabbro, mylonite and amphibolite from the Moyar Shear Zone (MSZ), Southern Granulite Terrane (SGT) with an aim to decipher the time-relationship between fabric development in the pluton and regional tectonics. Magnetic foliation recorded in the PM pluton is sub-parallel to the WNW-ESE striking MSZ. Magnetic foliation and lineation trajectories are sigmoidal and curve into the shear zone. A dextral sense of shear is deciphered from the trajectories, which is similar to that reported within the MSZ in some earlier studies. It is inferred that the PM pluton has developed post-emplacement deformation-fabric related to reactivation of the MSZ during Pan-African age. Based on the data and existing information about regional tectonics of the area, the possibility of the (a) PM pluton being a Deformed Alkali Rock and Carbonatite (DARC) and (b) MSZ marking an ancient suture zone, is discussed.