Modification of an acoustic pinger to transmit temperature data

An acoustic pinger can be modified to transmit two pings per second with the delay time between pings controlled by the temperature of an external thermistor. The precision of the temperature measurements is on the order of 0.1°C. This modification does not interfere with the normal depth indicating function of the pinger and is an inexpensive means of obtaining water temperature data.     

Water Self-Softening Processes at Waterfall Sites

Many rivers in tropical and subtropical karst regions are supersaturated with respect to CaCO3 and have high water hardness. After flowing through waterfall sites, river water is usually softened, accompanied by tufa formation, which is simply described as a result of water turbulence in fast-flowing water. In this paper, a series of laboratory experiments are designed to simulate the hydrological conditions at waterfall sites. The influences of air-water interface, water flow velocity, aeration and solid-water interface on water softening are compared and evaluated on a quantitative basis. The results show that the enhanced inorganic CO2 outgassing due to sudden hydrological changes occurring at waterfall sites is the principal cause of water softening at waterfall sites. Both air-water interface area and water flow velocity increase as a result of the "aeration effect", "low pressure effect" and "jet-flow effect" at waterfall sites, which greatly accelerates CO2 outgassing and therefore makes natural w     

Electronic structures of sulfide minerals — Theory and experiment

The sulfide minerals exhibit a rich diversity in sturctural chemistry and in electrical, magnetic and other physical properties. Models based on molecular orbital theory and incorporating some elements of band theory can be developed to describe the diverse valence electron behavior in these minerals. Qualitative models can be proposed on the basis of observed properties, and the models can be tested and refined using experimental data from X-ray emission and X-ray photoelectron spectroscopy and quantum mechanical calculations performed on cluster units which form the basic building blocks of the crystals. This approach to chemical bonding in sulfide minerals is illustrated for binary non-transition metal sulfides (ZnS, CdS, HgS, PbS), binary transition metal sulfides (FeS₂, CoS₂, NiS₂, CuS₂ ZnS₂) and more complex sulfides (CuFeS₂, Cu₂S, Ag₂S, CuS, Co₃S₄, CuCo₂S₄, Fe₃S₄). The relationship between qualitative and quantitative theories is reviewed with reference to the pyrite-marcasite-arsenopyrite-loellingite series of minerals. Application of the models to understanding structure-determining principles, relative stabilities, solid solution limits and properties such as color, reflectance and hardness are discussed.     

An assessment of the effect of chemical scavenging within submarine hydrothermal plumes upon ocean geochemistry

Profiles of ²¹⁰Pb over the Endeavour and North Cleft Segments of the Juan de Fuca Ridge are used to model a time scale for the scavenging, by hydrothermal plumes, of reactive elements in seawater. The hydrothermal plumes above these ridge segments are sites of intense scavenging removal of ²¹⁰Pb. At Endeavour, the total ²¹⁰Pb activities within the plume are as low as 8 dpm/100 l and dissolved activities are as low as 3 dpm/100 l. At the North Cleft, which is characterized by higher particulate Fe concentrations, the total ²¹⁰Pb activities are 4.5 dpm/100 l, the dissolved activities are 1–2 dpm/100 l and the ²¹⁰Pb activities are deficient with respect to the activity of the ²¹⁰Po daughter. These are perhaps the lowest ²¹⁰Pb activities ever measured in the deep sea. The large gradient of ²¹⁰Pb between the plume and surrounding deep water suggests that scavenging is focused into the plumes through horizontal transport. The implication, therefore, is that this process might impact the ocean on a scale larger than that local to the ridge crest. By coupling published measurements of particle flux from Endeavour with ²¹⁰Pb activities on particles trapped at that site, the total volume of seawater stripped of ²¹⁰Pb per year for that site was calculated to be 7.4 × 10¹² l/y. Globally, the extrapolated volume flux of seawater stripped of reactive constituents is 5.7 × 10¹⁵ l/y, such that the entire ocean is processed in this manner in 2.4×10⁵ y. The geochemical cycle of elements with ocean residence times much shorter than this (e.g., Pb and Th) will not be greatly affected by hydrothermal scavenging. On the other hand, this process holds significance for the geochemistry of other elements scavenged by hydrothermal plumes, such as P and V, whose ocean residence times are > 10⁴ y.     

Quantifying the seasonal variations in fluvial and eolian sources of terrigenous material to Cariaco Basin,Venezuela

The varved sediments that accumulate in the Cariaco Basin provide a detailed archive of the region’s climatic history, including a record of the quantity of fluvial and wind-transported material. In this study, we examine the sedimentological characteristics (clay mineralogy and grain size) of both surface sediments and sinking lithogenic material collected from sediment trap samples over a three-year period from 1997 to 2000. Data from biweekly sediment trap samples show a tri-modal particle size distribution, with prominent peaks at 2, 22 and 80 μm, indicating sediment contributions from both eolian and fluvial sources. The clay mineralogy of the water column samples collected from 1997 to 1999 also shows distinctive characteristics of eolian and fluvial material. An examination of surface sediment samples from the Cariaco Basin indicates that the Unare River is the main source of riverine sediments to the eastern sub-basin. By combining these sedimentological proxies, we estimate that ～10% of the terrigenous material delivered to the Cariaco Basin is eolian, while ～90% is fluvial. This represents an annual dust accumulation rate of ～0.59 mg/cm²/yr. Since aerosols are closely linked to climate variability, the ability to quantify paleo-dust fluxes using sedimentological characteristics will be a useful tool for future paleoclimate studies looking at sub-Saharan aridity and latitudinal migration of the Intertropical Convergence Zone.     

Multiple scattering of seismic waves in fractured media: Velocity and effective attenuation of the coherent components ofP waves andS waves

We show that the multiple scattering by small fractures of seismic waves with wavelengths long compared to the fracture size and fracture spacing is indistinguishable from multiple-scattering effects produced by regular porosity, except for an orientation factor due to fracture alignment. The fractures reduce theP-wave andS-wave velocities and produce an effective attenuation of the coherent component of the seismic waves. The attenuation corresponds to 1000/Q of about unity for a Gaussian spectrum of fractures, and it varies with frequencyf asf ³. For a Kolmogorov spectrum of fractures of spectral index the attenuation is an order of magnitude or so larger and varies with frequency asf ^3-v The precise degree of attenuation depends upon the matrix properties, the fracture porosity, the degree of fracture anisotropy, the type of fluid filling the fractures, and the incidence angle of the wave.For fracture porosities less than about 15% theP-wave andS-wave velocities are decreased by the order of 5–10% with a lesser dependence on the type of fluid filling the fractures (gas, oil, or brine) and with a dependence on both the degree of anisotropy and the incident angle made by the wave. The tendency of fractures to occur perpendicularly to bedding suggests that the best way to measure seismically fractured rock behavior in situ is by using the travel-time delay and reflection amplitude. As both the offset and the azimuth of receivers vary from a shot, the travel-time delay and reflection amplitude should both show an elliptical pattern of behavior—the travel-time delay in response to the varying seismic speed, and the reflection amplitude in response to angular variations in the multiple scattering. Observations of attenuation at several frequencies should permit (a) determination of the spectrum of fractures (Gaussian versus Kolmogorovian) and (b) determination of the contribution of viscous damping to the effective attenuation.     

Leveraging modern climatology to increase adaptive capacity across protected area networks

Human-driven changes in the global environment pose an increasingly urgent challenge for the management of ecosystems that is made all the more difficult by the uncertain future of both environmental conditions and ecological responses. Land managers need strategies to increase regional adaptive capacity, but relevant and rapid assessment approaches are lacking. To address this need, we developed a method to assess regional protected area networks across biophysically important climatic gradients often linked to biodiversity and ecosystem function. We plot the land of the southwestern United States across axes of historical climate space, and identify landscapes that may serve as strategic additions to current protected area portfolios. Considering climate space is straightforward, and it can be applied using a variety of relevant climate parameters across differing levels of land protection status. The resulting maps identify lands that are climatically distinct from existing protected areas, and may be utilized in combination with other ecological and socio-economic information essential to collaborative landscape-scale decision-making. Alongside other strategies intended to protect species of special concern, natural resources, and other ecosystem services, the methods presented herein provide another important hedging strategy intended to increase the adaptive capacity of protected area networks.     

Geothermal investigations in the Bohus granite area in southwestern Sweden

Heat generation and heat flow were determined for the Bohus granite massif in western Sweden. This is the start of a major program concerning geothermal energy in Sweden. Neutron activation analyses, temperature measurements, thermal conductivity measurements have been carried out. As was expected the result, 76 mW m⁻², shows that even old Precambrian shields locally exhibit much higher values than normal.