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171.
Cornel E. J. de Ronde Gary J. Massoth David A. Butterfield Bruce W. Christenson Junichiro Ishibashi Robert G. Ditchburn Mark D. Hannington Robert L. Brathwaite John E. Lupton Vadim S. Kamenetsky Ian J. Graham Georg F. Zellmer Robert P. Dziak Robert W. Embley Vesselin M. Dekov Frank Munnik Janine Lahr Leigh J. Evans Ken Takai 《Mineralium Deposita》2011,46(5-6):541-584
Brothers volcano, of the Kermadec intraoceanic arc, is host to a hydrothermal system unique among seafloor hydrothermal systems known anywhere in the world. It has two distinct vent fields, known as the NW Caldera and Cone sites, whose geology, permeability, vent fluid compositions, mineralogy, and ore-forming conditions are in stark contrast to each other. The NW Caldera site strikes for ??600?m in a SW?CNE direction with chimneys occurring over a ??145-m depth interval, between ??1,690 and 1,545?m. At least 100 dead and active sulfide chimney spires occur in this field and are typically 2?C3?m in height, with some reaching 6?C7?m. Their ages (at time of sampling) fall broadly into three groups: <4, 23, and 35?years old. The chimneys typically occur near the base of individual fault-controlled benches on the caldera wall, striking in lines orthogonal to the slopes. Rarer are massive sulfide crusts 2?C3?m thick. Two main types of chimney predominate: Cu-rich (up to 28.5?wt.% Cu) and, more commonly, Zn-rich (up to 43.8?wt.% Zn). Geochemical results show that Mo, Bi, Co, Se, Sn, and Au (up to 91?ppm) are correlated with the Cu mineralization, whereas Cd, Hg, Sb, Ag, and As are associated with the dominant Zn-rich mineralization. The Cone site comprises the Upper Cone site atop the summit of the recent (main) dacite cone and the Lower Cone site that straddles the summit of an older, smaller, more degraded dacite cone on the NE flank of the main cone. Huge volumes of diffuse venting are seen at the Lower Cone site, in contrast to venting at both the Upper Cone and NW Caldera sites. Individual vents are marked by low-relief (??0.5?m) mounds comprising predominately native sulfur with bacterial mats. Vent fluids of the NW Caldera field are focused, hot (??300°C), acidic (pH????2.8), metal-rich, and gas-poor. Calculated end-member fluids from NW Caldera vents indicate that phase separation has occurred, with Cl values ranging from 93% to 137% of seawater values. By contrast, vent fluids at the Cone site are diffuse, noticeably cooler (??122°C), more acidic (pH?1.9), metal-poor, and gas-rich. Higher-than-seawater values of SO4 and Mg in the Cone vent fluids show that these ions are being added to the hydrothermal fluid and are not being depleted via normal water/rock interactions. Iron oxide crusts 3?years in age cover the main cone summit and appear to have formed from Fe-rich brines. Evidence for magmatic contributions to the hydrothermal system at Brothers includes: high concentrations of dissolved CO2 (e.g., 206?mM/kg at the Cone site); high CO2/3He; negative ??D and ??18OH2O for vent fluids; negative ??34S for sulfides (to ?4.6??), sulfur (to ?10.2??), and ??15N2 (to ?3.5??); vent fluid pH values to 1.9; and mineral assemblages common to high-sulfidation systems. Changing physicochemical conditions at the Brothers hydrothermal system, and especially the Cone site, occur over periods of months to hundreds of years, as shown by interlayered Cu?+?Au- and Zn-rich zones in chimneys, variable fluid and isotopic compositions, similar shifts in 3He/4He values for both Cone and NW Caldera sites, and overprinting of ??magmatic?? mineral assemblages by water/rock-dominated assemblages. Metals, especially Cu and possibly Au, may be entering the hydrothermal system via the dissolution of metal-rich glasses. They are then transported rapidly up into the system via magmatic volatiles utilizing vertical (??2.5?km long), narrow (??300-m diameter) ??pipes,?? consistent with evidence of vent fluids forming at relatively shallow depths. The NW Caldera and Cone sites are considered to represent stages along a continuum between water/rock- and magmatic/hydrothermal-dominated end-members. 相似文献
172.
David L. Huston Jorge M. R. S. Relvas J. Bruce Gemmell Susan Drieberg 《Mineralium Deposita》2011,46(5-6):473-507
Assessment of geological, geochemical and isotopic data indicates that a significant subgroup of volcanic-hosted massive sulphide (VHMS) deposits has a major or dominant magmatic?Chydrothermal source of ore fluids and metals. This group, which is typically characterised by high Cu and Au grades, includes deposits such as those in the Neoarchean Doyon-Bousquet-LaRonde and Cambrian Mount Lyell districts. These deposits are distinguished by aluminous advanced argillic alteration assemblages or metamorphosed equivalents intimately associated with ore zones. In many of these deposits, ??34Ssulphide is low, with a major population below ?3??; ??34Ssulphate differs from coexisting seawater and ??34Ssulphate?Csulphide????20?C30??. These characteristics are interpreted as the consequence of disproportionation of magmatic SO2 as magmatic?Chydrothermal fluids ascended and cooled and as a definitive evidence for a significant magmatic?Chydrothermal contribution. Other characteristics that we consider diagnostic of significant magmatic?Chydrothermal input into VHMS ore fluids include uniformly high (>3 times modern seawater values) salinities or very 18O-enriched (??18O?>?5??) ore fluids. We do not consider other criteria [e.g. variable salinity, moderately high ??18Ofluid (2?C5??), ??34Ssulphide near 0??, metal assemblages or a spatial association with porphyry Cu or other clearly magmatic-hydrothermal deposits] that have been used previously to advocate significant magmatic?Chydrothermal contributions to be diagnostic as they can be produced by non-magmatic processes known to occur in VHMS mineral systems. However, in general, a small magmatic?Chydrothermal contribution cannot be excluded in most VHMS systems considered. Conclusive data that imply minimal magmatic?Chydrothermal contributions are only available in the Paleoarchean Panorama district where coeval seawater-dominated and magmatic?Chydrothermal systems appear to have been physically separated. This district, which is characterised by chloritic and sericitic alteration assemblages and lacks aluminous advanced argillic alteration assemblages, is typical of many VHMS deposits around the world, suggesting that for ??garden variety?? VHMS deposits, a significant magmatic?Chydrothermal contribution is not required. Other than deposits associated with advanced argillic alteration assemblages, the only deposit for which we ascribe a major magmatic?Chydrothermal contribution is the Devonian Neves Corvo deposit. This deposit differs from other deposits in the Iberian Pyrite Belt and around the world in being extremely Sn-rich, with the Sn closely associated with Cu and in having formed from high 18O-rich fluids (??18Ofluid ??8.5??). We consider these characteristics, particularly the last, as diagnostic of a significant magmatic hydrothermal contribution. Our analysis indicates that two subgroups of VHMS deposits have a major magmatic?Chydrothermal contribution: Cu/Au-rich deposits with aluminous alteration assemblages and reduced, very Sn-rich deposits in which Sn was introduced in a high-temperature ore assemblage. Comparison with ??normal?? VHMS deposits suggests that these subgroups of VHMS deposits may form in specialised tectonic environments. The Cu/Au-rich deposits appear to form adjacent to magmatic arcs, an environment conducive to the generation of hydrous, oxidised melts by melting metasomatised mantle in the wedge above the subducting slab. This contrasts with the back-arc setting of ??normal?? VHMS deposits in which relatively dry granites (In this contribution, we use the term granite sensu latto) formed by decompression melting drive seawater-dominated hydrothermal circulation. The tectonic setting of highly Sn-rich VHMS deposits such as Neves Corvo is less clear; however, thick continental crust below the ore-hosting basin may be critical, as it is in other Sn deposits. 相似文献
173.
David L. Naftz Frank J. Millero Blair F. Jones W. Reed Green 《Aquatic Geochemistry》2011,17(6):809-820
Great Salt Lake (GSL) is one of the largest and most saline lakes in the world. In order to accurately model limnological
processes in GSL, hydrodynamic calculations require the precise estimation of water density (ρ) under a variety of environmental conditions. An equation of state was developed with water samples collected from GSL to
estimate density as a function of salinity and water temperature. The ρ of water samples from the south arm of GSL was measured as a function of temperature ranging from 278 to 323 degrees Kelvin
(oK) and conductivity salinities ranging from 23 to 182 g L−1 using an Anton Paar density meter. These results have been used to develop the following equation of state for GSL (σ = ± 0.32 kg m−3):
r- r0 = 184.0 10 6 2 + 1.0 4 70 8*\textS - 1. 2 10 6 1*\textT + 3. 1 4 7 2 1 \textE - 4*\textS 2 + 0.00 1 9 9 \textT 2 - 0.00 1 1 2*\textS*\textT, \rho - \rho^{0} = { 184}.0 10 6 2 { } + { 1}.0 4 70 8*{\text{S}} - 1. 2 10 6 1*{\text{T }} + { 3}. 1 4 7 2 1 {\text{E}} - 4*{\text{S}}^{ 2} + \, 0.00 1 9 9 {\text{T}}^{ 2} - 0.00 1 1 2*{\text{S}}*{\text{T}}, 相似文献
174.
Changing grading of soil: effect on critical states 总被引:3,自引:3,他引:3
Examples of situations are presented where the grading of a soil changes during its lifetime either by crushing of particles
leading to an increase of fine material or by slow transport of fine particles with seepage leading to a decrease of fine
material. Such grading changes influence the basic constitutive properties of the soil, in particular properties such as critical
states which are dependent on the available range of densities of packing. Discrete element modelling is used to show the
dependence of critical state conditions on grading and the way in which the particle assembly seeks out new critical state
conditions as the grading changes. 相似文献
175.
Recently, strong top-down (consumer) control of cordgrass (Spartina alterniflora) has been demonstrated. Here, we manipulated the densities of cordgrass consumers, acridid grasshoppers (Melanoplus bivittatus and Melanoplus femurrubrum), to examine their impact on cordgrass in the Plum Island Estuary (PIE), MA, USA. After 1 month, there was no detectable
effect of grasshopper density on S. alterniflora biomass and grasshoppers at the highest densities (34 individuals per square meter) consumed only ~14% of the standing stock
biomass. However, significant impacts of grasshopper density on grazing damage were seen. For example, plant damage and scarring
length increased by 160% and 6,156%, respectively, at the highest grasshopper densities relative to exclusion (zero grasshoppers)
densities. Plant height was significantly reduced with increasing grasshopper densities, although this may be a function of
leaf tip removal instead of reduced plant growth. No other strong consumers of cordgrass (e.g., Littoraria irrorata, Prokelisia marginata) were observed in PIE and we suggest that consumer regulation of cordgrass is weak in this system. 相似文献
176.
Effective livelihood adaptation to climate change disturbance: Scale dimensions of practice in Mozambique 总被引:2,自引:0,他引:2
Natural resource-dependent societies in developing countries are facing increased pressures linked to global climate change. While social-ecological systems evolve to accommodate variability, there is growing evidence that changes in drought, storm and flood extremes are increasing exposure of currently vulnerable populations. In many countries in Africa, these pressures are compounded by disruption to institutions and variability in livelihoods and income. The interactions of both rapid and slow onset livelihood disturbance contribute to enduring poverty and slow processes of rural livelihood renewal across a complex landscape. We explore cross-scale dynamics in coping and adaptation response, drawing on qualitative data from a case study in Mozambique. The research characterises the engagements across multiple institutional scales and the types of agents involved, providing insight into emergent conditions for adaptation to climate change in rural economies. The analysis explores local responses to climate shocks, food security and poverty reduction, through informal institutions, forms of livelihood diversification and collective land-use systems that allow reciprocity, flexibility and the ability to buffer shocks. However, the analysis shows that agricultural initiatives have helped to facilitate effective livelihood renewal, through the reorganisation of social institutions and opportunities for communication, innovation and micro-credit. Although there are challenges to mainstreaming adaptation at different scales, this research shows why it is critical to assess how policies can protect conditions for emergence of livelihood transformation. 相似文献
177.
Complexity theory has received considerable attention over the past decade from a wide variety of disciplines. Some who write on this topic suggest that complexity theory will lead to a unifying understanding of complex phenomena; others dismiss it as a passing and disruptive fad. We suggest that for the analysis of coupled natural/human systems, the truth emerges from the middle ground. As an approach focused as much on the connections among system elements as the elements themselves, we argue that complexity theory provides a useful conceptual framework for the study of coupled natural/human systems. It is, if nothing else, a framework that leads us to ask interesting questions about, for example, sustainability, resilience, threshold events, and predictability.In this paper we attempt to demystify the ongoing discussions on complexity theory by linking its evocative and overloaded terminology to real-world processes. We illustrate how a shift in focus from system elements to connections among elements can lead to meaningful insight into human-environment interactions that might otherwise be overlooked. We ground our discussion in ongoing interdisciplinary research surrounding Yellowstone National Park’s northern elk winter range; a tightly coupled natural/human system that has been the center of debate, conflict, and compromise for more than 135 years. 相似文献
178.
179.
Kenneth D. Adams Ted Goebel Kelly Graf Geoffrey M. Smith Anna J. Camp Richard W. Briggs David Rhode 《Geoarchaeology》2008,23(5):608-643
The Great Basin of the western U.S. contains a rich record of Late Pleistocene and Holocene lake‐level fluctuations as well as an extensive record of human occupation during the same time frame. We compare spatial‐temporal relationships between these records in the Lahontan basin to consider whether lake‐level fluctuations across the Pleistocene‐Holocene transition controlled distribution of archaeological sites. We use the reasonably well‐dated archaeological record from caves and rockshelters as well as results from new pedestrian surveys to investigate this problem. Although lake levels probably reached maximum elevations of about 1230–1235 m in the different subbasins of Lahontan during the Younger Dryas (YD) period, the duration that the lakes occupied the highest levels was brief. Paleoindian and Early Archaic archaeological sites are concentrated on somewhat lower and slightly younger shorelines (_1220–1225 m) that also date from the Younger Dryas period. This study suggests that Paleoindians often concentrated their activities adjacent to large lakes and wetland resources soon after they first entered the Great Basin. © 2008 Wiley Periodicals, Inc. 相似文献
180.
David Drolet Michael R. S. Coffin Myriam A. Barbeau Diana J. Hamilton 《Estuaries and Coasts》2013,36(5):940-950
Movement of animals on intertidal mudflats can have profound consequences for population and community dynamics. Such movement is often influenced by biotic interactions, but the abiotic environment can also be important, affecting the strength of species’ interactions and even changing their outcome. Here, we focused on two biotic interactions and examined their effect on movement of the burrow-dwelling amphipod Corophium volutator: intraspecific interactions (specifically, the effect of conspecific density) and interspecific interactions with a competitor–predator, the mud snail Ilyanassa obsoleta (=Nassarius obsoletus). We assessed the magnitude of the temporal variation and examined the influence of pertinent abiotic variables (lunar cycle, presence of tide pools). Despite substantial temporal variation in movement levels, density of conspecifics did not influence emigration or immigration rates of C. volutator. Mud snails negatively affected immigration of C. volutator, and this was consistent across all lunar phases. However, mud snails influenced mortality and emigration of C. volutator in a contrasting way relative to lunar phases; sometimes amphipods evaded snails and survived, but at other times did not emigrate and were killed. The presence of tide pools did not change the nature or strength of the snail–amphipod interaction. Our results further clarify the complex interactions between C. volutator and I. obsoleta and suggest that resources on the mudflat are sufficient to sustain high densities of amphipods in a density-independent manner. Further, they highlight the importance of considering multiple environmental variables when examining interspecific interactions. 相似文献
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