Temperatures of serpentinization of ultramafic rocks based on O18/O16 fractionation between coexisting serpentine and magnetite

Five lizardite-chrysotile type serpentinites from California, Guatemala and the Dominican Republic show oxygen isotope fractionations of 15.1 to 12.9 per mil between coexisting serpentine and magnetite (O¹⁸ magnetite=–7.6 to –4.6 per mil relative to SMOW). Nine antigorites (mainly from Vermont and S. E. Pennsylvania) show distinctly smaller fractionations of 8.7 to 4.8 per mil (O¹⁸ magnetite=–2.6 to +1.7 per mil). Two lizardite and chrysotile serpentinites dredged from the Mid-Atlantic Ridge exhibit fractionations of 10.0 and 12.4 per mil (O¹⁸ magnetite=–6.8 and –7.9 per mil, respectively), whereas an oceanic antigorite shows a value of 8.2 per mil (O¹⁸ magnetite=–6.2). These data all clearly indicate that the antigorites formed at higher temperatures than the chrysotilelizardites. Electron microprobe analyses of magnetites from the above samples show that they are chemically homogeneous and essentially pure Fe₃O₂. However, some magnetites from certain other samples that show a wide variation of Cr content also give very erratic oxygen isotopic results, suggesting non-equilibrium. An approximate serpentine-magnetite geothermometer curve was constructed by (1) extrapolation of observed O¹⁸ fractionations between coexisting chlorites and Fe-Ti oxides in low-grade pelitic schists whose isotopic temperatures are known from the quartz-muscovite O¹⁸ geothermometer, and (2) estimates of the O¹⁸ fractionation factor between chlorite and serpentine (assumed to be equal to unity). This serpentine-magnetite geothermometer suggests approximate equilibrium temperatures as follows: continental lizardite-chrysotile, 85° to 115° C; oceanic lizardite and chrysotile, 130° C and 185° C, respectively; oceanic antigorite, 235° C; and continental antigorites, 220° to 460° C.Contribution No. 2029 of the Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91109.     

Theory of the electromagnetic transient response of the ionosphere for plane wave excitation

Summary The reflection and transmission of a transient plane wave by an ionosphere with a linear electron density profile and constant collision frequency are calculated. The exact frequency domain solution is inverted numerically, and the resultant reflected and transmitted waveforms are found to satisfy causality. A linearly varying, nondispersive dielectric half-space is also considered, but the nonphysical nature of the model causes the reflected waveform to be noncausal. Using convolution the waveforms for a step modulated sinusoid excitation are also obtained from the impulse response of the ionosphere. The results provide insight into the physical mechanism involved in the ionospheric propagation of HF electromagnetic pulsed signals.     

The Broken Hill ore body,Australia

The paper reviews recent works on the Broken Hill ore body to see what data is available on the origin and history of the ore. A high grade metamorphism is recognizable (the Willyama Metamorphism) and this was followed by a number of retrograde metamorphic events. The characteristics of these events is described and this is followed by an analysis of the hypothesis that there is a stratigraphic control of Broken Hill type mineralization. It is concluded that any control that does exist is of a regional nature and that the evidence is equally as good for a restriction of mineralization to areas of high grade metamorphism. Many of the isotopic and geochronological results for Broken Hill are not diagnostic as far as ore genesis is concerned. They do present an internally consistent set of data that records three major events, the Willyama Metamorphism and introduction of the Broken Hill type mineralization at 1700 m. y., the intrusion of the Mundi Mundi Granite and cross cutting pegmatites at 1560 m. y., and retrograde metamorphism and introduction of the Thackaringa Mineralization at or prior to 500 m.y. The sulphides have been deformed in the retrograde schist zones and the ore therefore predates this event. But there is no evidence at the moment that unambiguously establishes that the sulphides were present prior to the Willyama Metamorphism. If it was present prior to or during the Willyama Metamorphism and there is no period of deformation prior to the first recognizable folds at Broken Hill, then the sulphide mass was initially grossly discordant with bedding.

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Zusammenfassung Die Arbeit bringt Ergebnisse der neuesten Untersuchungen über die Broken-Hill-Lagerstätte anschließend an einen Überblick früherer Arbeiten. Der intensiven Willyama-Metamorphose folgen verschiedene retrograde Vorgänge, über die Einzelheiten mitgeteilt werden. Ferner wird die Hypothese einer stratigraphischen Kontrolle der Vererzung einer Prüfung unterzogen und festgestellt, daß die maßgeblichen Frakturen regionaler Natur sein müssen und daß die Beobachtungen somit eine Annahme der Vererzung der hochmetamorphen Gebiete ebenso stark stützt. Viele Resultate von Isotopenzusammensetzungen und geochronologischen Untersuchungen sind für Broken Hill nicht diagnostisch, wenigstens was die Erzgenese betrifft. Sie belegen 3 Hauptereignisse: die Willyama-Metamorphose und den Beginn der Vererzung um 1700.10⁶a, die Intrusion des Mundi Mundi Granits und querschlägiger Pegmatite um 1560.10⁶a und eine retrograde Metamorphose und den Eintritt der Thackaringa-Vererzung um oder vor 500.10⁶a. Die Sulfide sind in der Zone der retrograden Schiefer deformiert worden, was beweist, daß die Vererzung älter ist als dieses Ereignis. Es gibt aber z. Z. keinen Beweis, daß die Sulfide vor der Willyama Metamorphose vorhanden gewesen sind. Wenn sie vor oder während dieses Ereignisses vorhanden gewesen sind und wenn vor der Zeit der ersten deutlichen Falten in Broken Hill keine Deformation stattgefunden hat, dann war die Sulfidmasse ursprünglich in der Schichtung stark diskordant.

     

The surface wind over an upwelling area near Pisco,Peru

Harmonic analysis of longshore and onshore components of surface winds over an upwelling area off the coast of Peru shows regular, nearly sinusoidal, diurnal variations in both velocity components. Spectral analysis of wind speed also indicates strong diurnal variations in kinetic energy. The data are compatible with a recent model of coastal winds proposed by Lettau and Lettau.     

Structure of the crust in the conterminous United States

On the basis of the newest interpretations of all sufficiently long seismic profiles, a contour map of the Mohorovi?i? discontinuity for the conterminous United States is compiled. Differences from earlier interpretations are discussed.     

Zoning in garnets—Diffusion models

When reference frames and diffusing components are properly selected, the flux equations for diffusion of the major components in natural garnets may often be approximated by: J DC. In such cases it is shown that, for reasonable diffusion coefficients and boundary conditions, observed zoning profiles in natural garnets may be explained with pure diffusion models. These models allow for original inhomogeneities in the host rock and may be used to explain why single hand specimens may show such a variety of zoning profiles within a single mineral species.     

Mechanics of growth of some laccolithic intrusions in the Henry mountains, Utah, I: Field observations, Gilbert's model, physical properties and flow of the magma

The shapes of sills and laccolithic intrusions and associated host rock deformation were studied at several locations on the flanks of the Henry Mountains. Diorite sills range from 0.5 to 10 m in thickness, are less than 1 km² in areal extent, and have blunt terminations. The laccolithic intrusions range from 10 to 200 m in thickness, and from 1 to 3 km² in areal extent. The host rock, principally sandstone and shale, is deformed along closely spaced cataclastic shear planes. This deformation is concentrated at contacts, especially near sill terminations and over laccolith peripheries. The diorite contains plagioclase phenocrysts which are usually sheared in a thin zone adjacent to each contact. Field observations suggest that sills are the forerunners of laccolithic intrusions which form only after magma has spread far enough laterally (greater than about 1 km² in the Henry Mountains) to gain leverage to bend the overburden upward. Further injection of magma results in laccolithic peripheries or terminations with one of three distinct cross-sectional forms: (1) blunt termination of the diorite accompanied by bending and minor faulting of the host rock; (2) termination at a peripheral diorite dike cutting upward across the host rock; or (3) abrupt termination of the diorite against a nearly vertical fault zone.In order to study some of the processes of sill and laccolith intrusion, mechanical models for the driving pressure, physical properties, and flow behavior of the diorite magma are derived and discussed. A static driving pressure (equal to the difference between total magma pressure and lithostatic pressure) of up to 700 bar is estimated. The rheological behavior of the magma in the Henry Mountains is unknown. However, flow behavior is calculated assuming three of the more common models for fluids: Newtonian viscous, pseudoplastic, and Bingham. Suspended crystals probably contributed to the finite strength of the magma (estimated to be at least 10³ dyn/cm² for the Henry Mountains magma) which enables it to support dense zenoliths and also fixes maximum limits on the lengths of sills or dikes. Pressure in magma flowing along tabular intrusions of uniform thickness drops linearly in the flow direction for all three rheological materials. Thickening of tabular intrusions tends to make the pressure drop less rapidly, but pressure drops more rapidly in the tapered region near a termination. Pressure distributions under these and other conditions are derived in order to use them in the models of host rock deformation presented in Part II.     

High temperature mass spectrometric gas-release studies of Hawaiian volcanic glass: Pele's tears

The identification of gaseous molecular species and mechanisms of their release from glassy lava have been investigated with a high temperature mass spectrometer. Using Pele's tears as representative of quenched liquids of Hawaiian tholeiitic basalts, it was found that volatiles are released at low temperatures by a rate-limiting diffusion mechanism and, at temperatures in the softening range of the glass, by bursting of bubbles trapped near the vaporizing surface of the sphere-like particles.Gases released by bursting gave pressure surges and were found to be water vapor, CO₂ and CO. Those released principally by diffusion, and in some cases generated by thermal degradation and further reaction with the sample, include H₂, O₂, N₂, S₂, H₂S, SO₂, SO₃, COS, HCl, HF and NH₃. Average mole percent compositions of the volatiles H₂O, CO₂ and SO₂ relative to the total gas released were found to be 95 per cent, 3·5 per cent and 1 per cent, respectively. Minor concentrations of organic constituents, previously unobserved in volcanic gas analyses, were also found. Fragmentation patterns and gas release behavior suggest that these are derived from a mixture of low-molecular weight saturated and unsaturated acyclic hydrocarbons (C₁-C₄).