Non-uniqueness and interpretation of the seawater Sr/Sr curve

Variations in the seawater ⁸⁷Sr/⁸⁶Sr curve through time can be caused by fluctuations in the strontium flux or variations in the isotopic ratio from at least six different sources and sinks. Thus, 12 or more parameters control each single measurement although widely accepted assumptions allow this to be reduced to typically six unknowns. Interpreting the causes of time-variation in the seawater ⁸⁷Sr/⁸⁶Sr curve is therefore hampered by inherent non-uniqueness. However, this problem is under-constrained rather than unconstrained. As a result, whilst there are an infinite number of possible interpretations, these all come from a few families of very similar solutions. Using this insight, it is possible to find solutions having the smallest possible variations in source flux or source ⁸⁷Sr/⁸⁶Sr ratio. Thus, lower-bounds can be placed upon the source variations responsible for the observed fluctuations in the seawater ⁸⁷Sr/⁸⁶Sr curve. When applied to the evolution of the Early Jurassic ⁸⁷Sr/⁸⁶Sr seawater curve, this approach demonstrates that a short-lived Toarcian event is genuine since it is present in all models, regardless of the values chosen for the unknown source fluxes and unknown source isotope ratios. However, the variations in strontium flux or isotopic ratio necessary to explain the Toarcian event may be significantly smaller than would be predicted assuming modern values for the unknown parameters.     

Groundwater-supported evapotranspiration within glaciated watersheds under conditions of climate change

This paper analyzes the effects of geology and geomorphology on surface-water/-groundwater interactions, evapotranspiration, and recharge under conditions of long-term climatic change. Our analysis uses hydrologic data from the glaciated Crow Wing watershed in central Minnesota, USA, combined with a hydrologic model of transient coupled unsaturated/saturated flow (HYDRAT2D). Analysis of historical water-table (1970–1993) and lake-level (1924–2002) records indicates that larger amplitude and longer period fluctuations occur within the upland portions of watersheds due to the response of the aquifer system to relatively short-term climatic fluctuations. Under drought conditions, lake and water-table levels fell by as much as 2–4 m in the uplands but by 1 m in the lowlands. The same pattern can be seen on millennial time scales. Analysis of Holocene lake-core records indicates that Moody Lake, located near the outlet of the Crow Wing watershed, fell by as much as 4 m between about 4400 and 7000 yr BP. During the same time, water levels in Lake Mina, located near the upland watershed divide, fell by about 15 m. Reconstructed Holocene climate as represented by HYDRAT2D gives somewhat larger drops (6 and 24 m for Moody Lake and Lake Mina, respectively). The discrepancy is probably due to the effect of three-dimensional flow. A sensitivity analysis was also carried out to study how aquifer hydraulic conductivity and land-surface topography can influence water-table fluctuations, wetlands formation, and evapotranspiration. The models were run by recycling a wet year (1985, 87 cm annual precipitation) over a 10-year period followed by 20 years of drier and warmer climate (1976, 38 cm precipitation). Model results indicated that groundwater-supported evapotranspiration accounted for as much as 12% (10 cm) of evapotranspiration. The aquifers of highest hydraulic conductivity had the least amount of groundwater-supported evapotranspiration owing to a deep water table. Recharge was even more sensitive to aquifer hydraulic conductivity, especially in the lowland regions. These findings have important implications for paleoclimatic studies, because the hydrologic response of a surface-water body will vary across the watershed to a given climate signal.     

Mercury mobilization by oxidative dissolution of cinnabar (α-HgS) and metacinnabar (β-HgS)

Cinnabar (α-HgS) and metacinnabar (β-HgS) dissolved at environmentally significant rates in oxygenated slurry experiments simulating a low-flow fluvial system. Based on SO₄²⁻ production, cinnabar dissolution rates were 2.64 to 6.16 μmol (SO₄²⁻) m^− 2 day^− 1, and metacinnabar dissolution rates were 1.20 to 1.90 μmol (SO₄²⁻) m^− 2 day^− 1. Monodentate-bound thiosulfate (S₂O₃²⁻) was identified as an oxidation product on the HgS surface by ATR-IR spectroscopy based on strong infrared absorption bands in the 1140–1145 cm^− 1 and 1006–1014 cm^− 1 regions. The presence of sulfide oxidation intermediates on the HgS surface indicates that SO₄²⁻ concentration underestimates α-HgS and β-HgS dissolution in this setting. Mercury release rates during dissolution were more than two orders of magnitude less than SO₄²⁻ production, but were significant: 0.47 mg (Hg) m^− 2 y^− 1 from cinnabar [6.45 nmol (Hg) m^− 2 day^− 1], and 0.17 mg (Hg) m^− 2 y^− 1 from metacinnabar [2.29 nmol (Hg) m^− 2 day^− 1]. The Hg mobilized during α-HgS and β-HgS dissolution is sufficient to form natural Au–Hg amalgam in downstream placer settings. The proportion of mercury that is not remobilized during α-HgS and β-HgS dissolution likely adsorbs to the dissolving mercuric sulfide. Adsorption of Hg²⁺ to cinnabar was detected in situ by anodic stripping voltammetry using a cinnabar-modified carbon paste electrode following accumulation of Hg²⁺ on the electrode at open circuit potential.     

Karrat Fjord (Greenland) tsunamigenic landslide of 17 June 2017: initial 3D observations

On 17 June 2017, a landslide-generated tsunami reached the village of Nuugaatsiaq, Greenland, leaving four persons missing and presumed dead. Here, we present a preliminary high-resolution analysis of the tsunamigenic landslide scar based on three-dimensional (3D) reconstructions of oblique aerial photographs taken during a post-failure reconnaissance helicopter overflight. Through a 3D quantitative comparison with pre-failure topography, we estimate that approximately 58 million m³ of rock and colluvium (talus) was mobilized during the landslide, 45 million m³ of which reached the fjord, resulting in a destructive tsunami. We classify this event as a “tsunamigenic extremely rapid rock avalanche,” which likely released along a pre-existing metamorphic fabric, bounded laterally by slope-scale faults. Further analysis is required to properly characterize this landslide and adjacent unstable slopes, and to better understand the tsunami generation.     

贵州西部的岩溶地貌

安顺、水城地区位于贵州高原西部,锥状岩溶非常显著,河流峡谷深切,从高原分水岭区的峰林盆地过渡到峰林谷地、峰丛谷地,再到干流峡谷区的封闭的峰丛洼地,表现出明显的分带现象。大多数洞穴为潜流成因,有继续发育的洞穴及高层老洞穴系统,后者显示了构造上升和地貌回春的较长发育史。沿深切三岔河的河流袭夺使地表、地下的岩溶地形特征有非常壮观的发育。锥状岩溶的形态分析揭示出锥峰坡度比较对称且较少受地质的控制。岩溶演化的关键性因素是构造上升速率。岩溶地形类型发育序列的模式与基面控制、地面剥蚀速度、侧方夷平作用及构造抬升有密切关系。而简单的地貌动力平衡模式不能充分说明贵州岩溶地貌复杂的变化。      

Rapidly oscillating M giant stars?

The Hipparcos mission discovered a few dozen M giant stars with periods P shorter than 10 d. Similar stars may be found in other large data bases of new variables (e.g., OGLE). The three possible sources of the magnitude variations – pulsation, starspots and ellipsoidal deformation – are discussed in general terms. The parallaxes and V − I colour indices are used to calculate radii and temperatures for all M giant variables with P <100 d. Masses are estimated from the positions of the stars in a Hertzsprung–Russell (HR) diagram, using evolutionary tracks. Using these data, it is shown that starspots can be ruled out as a variability mechanism in almost all cases, and ellipsoidal variations in about half of the stars. Pulsation in very high-overtone modes appears to be the only viable explanation for the stars with P <10 d. Many of the stars may be multiperiodic. IRAS data are used to deduce information about reddening and circumstellar dust. The apparently low level of mass-loss, as well as the kinematics and the spatial distribution of the stars, indicates that they are from a relatively young (i.e., thin disc) giant star population.     

Enhancing the effectiveness of policy-relevant integrative research in rural areas

There has been much debate about the importance of policy-relevant research in geography over the last decade. There has also been an increasing recognition by policymakers of the importance of integrative (interdisciplinary and transdisciplinary) approaches to policy-relevant research. However, geographers have been more reluctant than their colleagues in other social and natural sciences to embrace integrative research collaborations. For integrative research to achieve its full potential and to encourage greater participation from the geographical research community, we need to increase our understanding of its potential value, but also some of the challenges that it poses, and how these can be overcome. In this paper, we consider the processes involved in conducting successful integrative research from the perspective of researchers involved in these projects. We base our analysis on the results of a questionnaire survey of international integrative research programmes on environmental issues in rural areas, combined with our own experiences of working in integrative research. We conclude that effective integrative research depends on the establishment of a clear conceptual framework, the use of appropriate temporal and spatial scales in the research, effective language and communication, time and commitment, and trust and respect. We also highlight the value of stakeholder involvement in integrative research to ensure the policy relevance of the work and provide a mechanism to assist with effective knowledge transfer of the results.     

Characteristics of intense rainfall over Gujarat State (India) based on percentile criteria

The study focuses on the spatial and temporal variations of intense/extreme rainfall events over Gujarat State (India) during the period 1970–2014. Average monsoon rainfall for the state shows a significant increasing trend, with an increase of 48 mm/decade. Some of the stations in the Saurashtra region show a statistically significant increasing trend but none of the stations in the state show a decreasing trend. The increasing trend in monsoon rainfall is very significant for the past three decades, with an increase of 167 mm/decade. Instead of fixed absolute threshold values, relative threshold values of rainfall corresponding to the 95th, 98th, 99th and 99.5th percentiles for each station have been proposed to represent heavy, very heavy, intense and extreme rainfall, which varied between 70–120, 105–160, 130–210 and 165–280 mm, respectively. Significant increasing trends are observed for the frequency of heavy and very heavy rainfall events over the state.     

The ruby mines of Mogok

The world's finest rubies all come from the metamorphic rocks of Mogok, in Myanmar. Traditional methods of mining, with little mechanization, are still used; they work best in digging the gemstones out of narrow calcite veins and thin beds of buried placer gravel.