The mineralogic transformation of ferrihydrite induced by heterogeneous reaction with bioreduced anthraquinone disulfonate (AQDS) and the role of phosphate

Bioreduced anthraquinone-2,6-disulfonate (AH₂DS; dihydro-anthraquinone) was reacted with a 2-line, Si-substituted ferrihydrite under anoxic conditions at neutral pH in PIPES buffer. Phosphate (P) and bicarbonate (C); common adsorptive oxyanions and media/buffer components known to effect ferrihydrite mineralization; and Fe(II)_aq (as a catalytic mineralization agent) were used in comparative experiments. Heterogeneous AH₂DS oxidation coupled with Fe(III) reduction occurred within 0.13-1 day, with mineralogic transformation occurring thereafter. The product suite included lepidocrocite, goethite, and/or magnetite, with proportions varing with reductant:oxidant ratio (r:o) and the presence of P or C. Lepidocrocite was the primary product at low r:o in the absence of P or C, with evidence for multiple formation pathways. Phosphate inhibited reductive recrystallization, while C promoted goethite formation. Stoichiometric magnetite was the sole product at higher r:o in the absence and presence of P. Lepidocrocite was the primary mineralization product in the Fe(II)_aq system, with magnetite observed at near equal amounts when Fe(II) was high [Fe(II)/Fe(III)] = 0.5 and P was absent. P had a greater effect on reductive mineralization in the Fe(II)_aq system, while AQDS was more effective than Fe(II)_aq in promoting magnetite formation. The mineral products of the direct AH₂DS-driven reductive reaction are different from those observed in AH₂DS-ferrihydite systems with metal reducing bacteria, particularly in presence of P.     

The Tamayo transform fault in the mouth of the Gulf of California

The Tamayo transform fault is located at the north end of the East Pacific Rise where it enters the Gulf of California. This paper presents bathymetric, seismic reflection, magnetic, and gravity data from a detailed survey of the transform fault. The dominant feature of the offset region is a bathymetric ridge trending 120°, parallel to the predicted transform plate boundary. This transform ridge is associated with a large (600 ) positive magnetic anomaly, and a very small positive free-air gravity anomaly. Magnetic and gravity models indicate either a basalt or serpentinite composition for the ridge, but cannot distinguish between these possibilities. At its eastern end, the modern zone of strike-slip motion is in a narrow valley south of the transform ridge. The transform plate margin appears to pass through a saddle in the transform ridge and meet the western spreading center segment in the trough north of the transform ridge. On the basis of this survey and previous work, the history of the Tamayo from continental breakup to the present has been reconstructed. Initial rifting occurred along a trend of 130° at approximately 3.5 m.y.b.p. Once the transform fault was free of the constraints imposed by continent-continent and continent-oceanic lithospheric interaction, the trend of the transform fault rotated counter-clockwise. This rotation resulted in a leaky transform fault and intrusion of a large continuous transform ridge. Further adjustments in the spreading center/transform fault plate boundary configuration have given rise to an incipient zone of rifting cutting across the transform ridge and emplacement of diapiric structures.Contribution of the Scripps Institution of Oceanography, new series.     

Alma and E-merlin Data Transmission Systems: Lessons for Ska

ALMA, EVLA and e-MERLIN use high data rate optical fibre links based on commercially available 10 Gbps opto-electronics. This paper describes the systems designed by NRAO and JBO staff to be used in ALMA and e-MERLIN. ALMA has a requirement for a 120 Gbps data rate per telescope, requiring the use of 12 lasers in the 1550 nm telecommunication band, with maximum link lengths around 20 km. e-MERLIN has a lower bandwidth and requires 30 Gbps links per telescope and therefore three lasers per telescope; however, the link lengths reach up to around 400 km, and amplification, de-dispersion and regeneration are required. Dense wavelength division multiplexing is used to avoid fibre management problems and save fibre costs. The design criteria and experience gained in these projects is very relevant to SKA as the proposed configuration of the antenna elements maps well to the link lengths used here. The chosen data rate will be a major cost driver.     

Diamondiferous peridotitic microxenoliths from the Diavik Diamond Mine, NT

Twenty-five diamonds recovered from 21 diamondiferous peridotitic micro-xenoliths from the A154 South and North kimberlite pipes at Diavik (Slave Craton) match the general peridotitic diamond production at this mine with respect to colour, carbon isotopic composition, and nitrogen concentrations and aggregation states. Based on garnet compositions, the majority of the diamondiferous microxenoliths is lherzolitic (G9) in paragenesis, in stark contrast to a predominantly harzburgitic (G10) inclusion paragenesis for the general diamond production. For garnet inclusions in diamonds from A154 South, the lherzolitic paragenesis, compared to the harzburgitic paragenesis, is distinctly lower in Cr content. For microxenolith garnets, however, Cr contents for garnets of both the parageneses are similar and match those of the harzburgitic inclusion garnets. Assuming that the microxenolith diamonds reflect a sample of the general diamond population, the abundant Cr-rich lherzolitic garnets formed via metasomatic overprinting of original harzburgitic diamond sources subsequent to diamond formation, conversion of original harzburgitic diamond sources occurred in the course of metasomatic overprint re-fertilization. Metasomatic overprinting after diamond formation is supported by the finding of a highly magnesian olivine inclusion (Fo₉₅) in a microxenolith diamond that clearly formed in a much more depleted environment than indicated by the composition of its microxenolith host. Chondrite normalized REE patterns of microxenolith garnets are predominantly sinusoidal, similar to observations for inclusion garnets. Sinusoidal REE_N patterns are interpreted to indicate a relatively mild metasomatic overprint through a highly fractionated (very high LREE/HREE) fluid. The predominance of such patterns may explain why the proposed metasomatic conversion of harzburgite to lherzolite appears to have had no destructive effect on diamond content. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

RICE PRODUCER‐PROCESSOR NETWORKS IN CÔTE D'IVOIRE*

ABSTRACT. Pressured by structural adjustment loan conditions, Côte d'Ivoire reduced state support for rice production and processing during the 1990s. In this article we examine how various actors in the rice commodity chain adapted to the macroeconomic reforms. Following a brief history of the rice sector, we present the results of fieldwork based on interviews conducted in 2002 of farmers, millers, traders, and workers in the state extension service and nongovernmental organizations. We found that, in the absence of state supports for farmers, private millers became the focal point of regional producer‐processor rice networks. The four networks identified became the sole source of domestic commercial rice when the state removed subsidies for fertilizer and modern seeds, privatized extension, and liberalized prices and imports. To increase their role in the national rice supply, the rice networks may need support through microlending and a focus on niche markets.     

Beach Comfort Index – a new approach to evaluate the thermal conditions of beach holiday resorts using a South African example

The climatic conditions of seven beach holiday resorts in South Africa (Alexander Bay, Cape Town, George, Port Elizabeth, East London, Durban and Richard's Bay) have been examined with regard to the thermal perception of beach holiday makers. The evaluation of the thermal conditions is based on the human energy balance calculations which have been adapted to the requirements of beach goers. A model has been developed to calculate the missing radiation input data and parameters such as ‘beach day’ and ‘beach hour’ are introduced and defined. The average monthly number of beach days is calculated for every location showing the highest amounts in Durban and Richard's Bay and the highest annual variations in Cape Town. The Beach Comfort Index Map of South Africa shows the maximum, minimum and average number of beach days per month and the probability of beach days and thus providing understandable and interpretable information on the thermal conditions of the sites from the point of view of beach holiday makers. This revised version was published online in July 2006 with corrections to the Cover Date.     

A Database for Volatile Organic Compounds

The database for volatile organic compounds (VOC data base) was created with the aim of providing an overview of tropospheric hydrocarbon measurements. The data base contains 202 substances, for which atmospheric and useful kinetic data such as rate coefficients, photolysis frequencies, mixing ratios, emission data and ozone formation potentials are compiled from available literature. The database file can be downloaded without charge from http://www.physchem.uni-wuppertal.de/voc-database. Registered users will be informed about the appearance of updates.     

Interactive visualization of 3D mantle convection

The current availability of thousands of processors at many high performance computing centers has made it feasible to carry out, in near real time, interactive visualization of 3D mantle convection temperature fields, using grid configurations having 10–100 million unknowns. We will describe the technical details involved in carrying out this endeavor, using the facilities available at the Laboratory of Computational Science and Engineering (LCSE) at the University of Minnesota. These technical details involve the modification of a parallel mantle convection program, ACuTEMan; the usage of client–server socket based programs to transfer upwards of a terabyte of time series scientific model data using a local network; a rendering system containing multiple nodes; a high resolution PowerWall display, and the interactive visualization software, DSCVR. We have found that working in an interactive visualizastion mode allows for fast and efficient analysis of mantle convection results. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.