Comparison of fast elimination of Cr(VI) by alumina nanofiber and alumina nanoporous

The goal of this study is examination of the mixture between adsorption and permeation process for removing chromium (VI) from the water. Two types of supported membranes are developed: The first one which was made by sol–gel method is called nanoporous and the second one which was made by electrospinning is called nanofiber. The sorption capacity of nanoporous and nanofiber is examined in single batch experiments at various pH values, and it is found that maximum chromium removal is observed for both nanoporous and nanofiber at pH 3.5. Adsorption studies illustrated that the Cr(VI) adsorption onto alumina nanoporous and nanofiber is affected by changes in pH, contact time, dosage of adsorbent, concentration of chromium and solution volume. Langmuir and Freundlich isotherms can be used to explain the adsorption equilibria of Cr(VI) onto alumina nanoporous and nanofiber. It was found that balance adsorption data adequate Langmuir isotherm more than Freundlich model. Adsorption kinetics was found to be fitted to pseudo-second order and Weber and Morris model. The output of multiple linear regressions was run for the second-order response surface model implied that the linear agents of pH, sorbent dosage and Cr(VI) concentration are more significant factors. Manufacturing electrospun alumina nanofiber and sol–gel nanoporous with these cheap materials, renewable and fast methods are so important although the removal percentage is significant.     

Total Sulfur Concentration in Geological Reference Materials by Elemental Infrared Analyser

Total sulfur is an analyte for which there are few determinations published, despite the fact that it is a very important element (e.g., a major element in most ores, an important gas constituent in global warming, an active participant in acid drainage). Most geological reference materials have very poor quality sulfur results, that is with relative standard deviations (RSD) in the range of 30–50%, even for concentrations over 100 μg g⁻¹ S, which compromises their use as calibrators. In order to provide modern results with low RSD, sulfur was determined in twenty-nine geological reference materials with a state-of-the-art elemental S/C analyser using metal chips (certified reference materials with a traceability link) and analytical grade sulfur for high concentration samples. Analytical parameters (sample mass, crucible degassing, calibration strategy, etc.) were optimised by testing. Our results agreed with reference material values provided by issuing bodies. Results for CCRMP SY-2 (129 ± 13 μg g⁻¹ S), which has been proposed as a sulfur reference material, were in agreement with the proposed modern value of 122 ± 3.7 μg g⁻¹ S.     

Cooling of neutron stars with strong toroidal magnetic fields

We present models of temperature distribution in the crust of a neutron star in the presence of a strong toroidal component superposed to the poloidal component of the magnetic field. The presence of such a toroidal field hinders heat flow toward the surface in a large part of the crust. As a result, the neutron star surface presents two warm regions surrounded by extended cold regions and has a thermal luminosity much lower than in the case the magnetic field is purely poloidal. We apply these models to calculate the thermal evolution of such neutron stars and show that the lowered photon luminosity naturally extends their life-time as detectable thermal X-ray sources. Work partially supported by UNAM-DGAPA grant #IN119306.     

A scenario based analysis of land competition between food and bioenergy production in the US

Greenhouse gas abatement policies will increase the demand for renewable sources of energy, including bioenergy. In combination with a global growing demand for food, this could lead to a food-fuel competition for bio-productive land. Proponents of bioenergy have suggested that energy crop plantations may be established on less productive land as a way of avoiding this potential food-fuel competition. However, many of these suggestions have been made without any underlying economic analysis. In this paper, we develop a long-term economic optimization model (LUCEA) of the U.S. agricultural and energy system to analyze this possible competition for land and to examine the link between carbon prices, the energy system dynamics and the effect of the land competition on food prices. Our results indicate that bioenergy plantations will be competitive on cropland already at carbon taxes about US $20/ton C. As the carbon tax increases, food prices more than double compared to the reference scenario in which there is no climate policy. Further, bioenergy plantations appropriate significant areas of both cropland and grazing land. In model runs where we have limited the amount of grazing land that can be used for bioenergy to what many analysts consider the upper limit, most of the bioenergy plantations are established on cropland. Under the assumption that more grazing land can be used, large areas of bioenergy plantations are established on grazing land, despite the fact that yields are assumed to be much lower (less than half) than on crop land. It should be noted that this allocation on grazing land takes place as a result of a competition between food and bioenergy production and not because of lack of it. The estimated increase in food prices is largely unaffected by how much grazing land can be used for bioenergy production.     

Palynological Analysis of Amber-Bearing Clay from the Lower Cretaceous of Central Lebanon

An amber-bearing lignitic layer of sandy clay from the Lower Cretaceous of Central Lebanon (Mderej-Hammana)yielded a well-preserved,moderately variegated palynoflora,which origin is mixed between land plants and marine microflora.Its detailed analysis led to fulfill its inventory,to propose a paleoenvironmental reconstruction,and to draw the paleoclimate which prevailed over the region:an estuarian area under a rather humid,temperate climate;a variety of ferns grew near the shore-side and in the inward l...     

Spatial and temporal variations in the incidence of dust events over Iran

Large near-field tsunamis pose a significant threat to the Canadian West Coast due to its proximity to the circum-Pacific belt where a significant tsunami-inducing earthquake event from the Cascadia subduction zone is expected. This study investigated the risks associated with such an event in terms of pedestrian evacuation needs and plans for the Town of Tofino, a small community located on the West Coast of Vancouver Island. The population-at-risk within the hazard zone and its ability to evacuate to safety is evaluated using anisotropic path-distance modelling. Mitigation measures, such as vertical evacuation buildings, are quantitatively evaluated. Site-specific inundation modelling was not performed as part of this study; tsunami hazard and safe zones were computed using a range of run-ups varying between 3 and 25 m. It was established that up to 80% of the population is within the maximum hazard zone considered. This evacuation modelling exercise indicates that a maximum of 13% of the population would have insufficient time to reach safety when using a mobility-impaired ambulatory speed. The use of three vertical evacuation buildings can reduce the risk of losing population in this category by 99%. Although some conservative assumptions were used (vertical datum at higher high water, reductions in safe zones by generalization process and mobility-impaired evacuation speeds), the evacuation potential is likely overestimated due to the coarseness of the topographic data used in the evacuation modelling and from an overestimated first wave arrival time. This is the first Canadian study which used anisotropic evacuation modelling to evaluate the vulnerability of a Canadian community to tsunami inundation.

     

Selenium and sulfur concentrations in the Bushveld Complex of South Africa and implications for formation of the platinum-group element deposits

We have determined the S, Se, Cu and La contents through a complete stratigraphic section of the Bushveld Complex. The principle aim was to determine which phases controlled these elements. S, Se and Cu show positive correlations, but these elements do not correlate with La. In most cases, the concentration of S, Se and Cu in rocks containing greater than 800 ppm S can be modeled by segregation of a Fe–Ni–Cu sulfide liquid from a fractionating magma. As the magma evolved, Se and Cu were depleted by the continual segregation of sulfide liquid and the S/Se and S/Cu of the rocks increased. The Se/Cu ratio is higher in the more evolved rocks, which suggests that Se has a slightly lower partition coefficient than Cu into sulfide liquid (1,200 versus 1,700). The Lower and lower Critical Zone of the complex contains on average only 99 ppm S. The low S content of these rocks has led some authors to suggest that these rocks do not contain cumulate sulfides, despite the fact that they are moderately enriched in PGE. These samples fall along the same trend as the S-rich samples on the S-versus-Se plot and the S/La and Se/La ratios are greater than the initial magmas suggesting that despite the low S contents cumulate sulfides are present. Three models may be suggested in order to explain the low S content in the Lower and Critical Zone rocks: (a) the sulfides that were present have migrated away from the cumulate pile into the footwall or center of the intrusion; (b) the magma was saturated in sulfides at depth and during transport some sulfides lagged in embayments; (c) the rocks have lost both S and Se at high temperature. The first two models have important implications for exploration.     

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