Modified passive capillary samplers for collecting samples of snowmelt infiltration for stable isotope analysis in remote,seasonally inaccessible watersheds 1: laboratory evaluation

Snowmelt is the most significant source of runoff generation and recharge in many of the mountainous watersheds worldwide and this is especially true in the southwestern United States. Yet, the isotopic and geochemical composition of the soil–meltwater endmember remains poorly constrained. Using the isotopic compositions of snow and snowmelt runoff samples taken from the landscape surface as proxies for soil–meltwater endmembers is problematic since they are typically not representative of the actual composition of soil meltwater. Furthermore, the applicability of current methodologies to collect the isotopic composition of meltwater is limited because of the remote and often seasonally inaccessible nature of the terrain where snowpacks develop. Therefore, a robust methodology requiring little maintenance or monitoring is desirable. A lab experiment was conducted to determine the suitability of using a modified passive capillary sampler (M‐PCAPS) design to collect snowmelt infiltration for isotopic analysis. Passive capillary samplers are constructed from fiberglass wicks that can be installed in the soil to sample vadose‐zone waters under a wide range of matric potentials and require little maintenance. Results from this lab experiment indicate that the wicking process associated with M‐PCAPS does not fractionate water but certain precautions are necessary to prevent exchange between the wick and the atmosphere. In this experiment, M‐PCAPS effectively tracked the changing isotopic composition of a soil reservoir undergoing evaporation. Therefore, M‐PCAPS provide a robust methodology to sample the isotopic composition of snowmelt infiltration in remote watersheds and similar applications. Copyright © 2009 John Wiley & Sons, Ltd.     

Uptake and metabolism of arsenate by anexic cultures of the microalgae Dunaliella tertiolecta and Phaeodactylum tricornutum

Axenic cultures of the microalgae species, Dunaliella tertiolecta and Phaeodactylum tricornutum were grown at arsenic (As) concentrations typically found in uncontaminated marine environments ( 2 µg L^− 1) under different phosphorus concentrations. D. tertiolecta accumulated higher arsenic concentrations (mean: 13.7 ± 0.7 µg g^− 1 dry mass) than P. tricornutum (mean: 1.9 ± 0.2 µg g−1 dry mass). Media phosphorus concentrations (0.6–3 mg/L) had little influence on microalgae growth rates or arsenic accumulation. Arsenic was present as lipid bound (29–38%; 4.2–9.5%), water-soluble (20–29%; 26–34%) and residue bound (41–45%; 57–69%) arsenic species in D. tertiolecta and P. tricornutum respectively. Hydrolysed lipids contained mostly glycerol arsenoribose (OH- ribose), dimethylarsinate (DMA) and inorganic arsenic (As(V)) moieties. Water-soluble species of microalgae were very different. D. tertiolecta contained inorganic arsenic (54–86%) with variable amounts of DMA (7.4–20%), arsenoriboses (5–25%) and traces of methylarsonate (MA) ( 1%). P. tricornutum contained mostly DMA (32–56%) and phosphate arsenoribose (PO₄-ribose, 23–49%) and small amounts of OH-ribose (3.8–6.5%) and As(V) (9–16%). Both microalgae contained an unknown cationic arsenic species. The residue fractions of both microalgae contained predominately inorganic arsenic (99–100%). These results show that at natural seawater arsenic concentrations, both algae take up substantial amounts of inorganic arsenic that is complexed with structural elements or sequestered in vacuoles as stable complexes. A significant portion is also incorporated into lipids. Arsenic is metabolised to simple methylated species and arsenoriboses.     

青藏高原北缘中生代伸展构造^40Ar／^39Ar测年和MDD模拟

沿着青藏高原北缘的阿尔金山脉东段 ,发育了长度大于 30 0km、EW走向的拉配泉断裂。中美合作阿尔金课题组的地质填图结果表明 ,该断层实际上是一条南倾的正断层 ,局部倾角可以低至 30°以下。沉积学和热年代学研究控制了拉配泉断裂的活动时代 :早—中侏罗统地层可以解释为断裂上盘的伸展盆地沉积 ;下盘岩石中钾长石40 Ar/ 3 9Ar测年和MDD模拟给出 2个阶段的冷却事件 ,早期事件出现在约 2 2 0～ 187Ma之间 ,晚期事件出现在早白垩世晚期 (约 10 0Ma)。早期事件代表了拉配泉断裂正断作     

The optical performance of the PILOT instrument from ground end-to-end tests

The Polarized Instrument for Long-wavelength Observation of the Tenuous interstellar medium (PILOT) is a balloon-borne astronomy experiment designed to study the linear polarization of thermal dust emission in two photometric bands centred at wavelengths 240 μm (1.2 THz) and 550 μm (545 GHz), with an angular resolution of a few arcminutes. Several end-to-end tests of the instrument were performed on the ground between 2012 and 2014, in order to prepare for the first scientific flight of the experiment that took place in September 2015 from Timmins, Ontario, Canada. This paper presents the results of those tests, focussing on an evaluation of the instrument’s optical performance. We quantify image quality across the extent of the focal plane, and describe the tests that we conducted to determine the focal plane geometry, the optimal focus position, and sources of internal straylight. We present estimates of the detector response, obtained using an internal calibration source, and estimates of the background intensity and background polarization.     

Using 3D Printing to Create a Robust and Compact Peristaltic Field Pump: An Update to the Montana Drill Pump

The collection of water samples from springs, streams, and wells is a critical component of field hydrogeological studies. Fieldwork, especially in mountainous terrain, often involves hiking to remote springs and streams. It is logistically and physically difficult to carry bulky, heavy sampling equipment such as large peristaltic pumps with built‐in batteries in these areas. To address this problem, researchers at the University of Montana designed the Montana Drill Pump (MDP) roughly 30 years ago to provide a compact, low‐cost and portable option for sampling with a peristaltic pump in the backcountry (Woessner 2007 ). Although the MDP is popular, with the advent of 3D printing techniques, a more robust and precise fitting pump design can be inexpensively created that can be quickly assembled in the lab or field. This new pump design was tested on multiple backpacking sampling campaigns in the Panamint Mountains of southern California, Mount Hood in Oregon, and Glacier National Park in northern Montana during the summer of 2017. The design was proven to be easy to use and durable in the field and offers a rugged, updated, more precisely fitting option to the MDP.     

Origin and significance of cosmogenic signatures in vesicles of lunar basalt 15016

Lunar basalt 15016 (~3.3 Ga) is among the most vesicular (50% by volume) basalts recovered by the Apollo missions. We investigated the possible occurrence of indigenous lunar nitrogen and noble gases trapped in vesicles within basalt 15016, by crushing several cm-sized chips. Matrix/mineral gases were also extracted from crush residues by fusion with a CO₂ laser. No magmatic/primordial component could be identified; all isotope compositions, including those of vesicles, pointed to a cosmogenic origin. We found that vesicles contained ~0.2%, ~0.02%, ~0.002%, and ~0.02% of the total amount of cosmogenic ²¹Ne, ³⁸Ar, ⁸³Kr, and ¹²⁶Xe, respectively, produced over the basalt's 300 Myr of exposure. Diffusion/recoil of cosmogenic isotopes from the basaltic matrix/minerals to intergrain joints and vesicles is discussed. The enhanced proportion of cosmogenic Xe isotopes relative to Kr detected in vesicles could be the result of kinetic fractionation, through which preferential retention of Xe isotopes over Kr within vesicles might have occurred during diffusion from the vesicle volume to the outer space through microleaks. This study suggests that cosmogenic loss, known to be significant for ³He and ²¹Ne, and to a lesser extent for ³⁶Ar (Signer et al. 1977 ), also occurs to a negligible extent for the heaviest noble gases Kr and Xe.     

Erosion of rocky shore platforms by block detachment from layered stratigraphy

The majority of shore platforms form in rocks that are characterised by layered stratigraphy and pervasive jointing. Plucking of weathered, joint and bed bounded blocks is an important erosion process that existing models of platform development do not represent. Globally, measuring platform erosion rates have focused on microscale (< 1 mm) surface lowering rather than mesoscale (0.1-1 m) block detachment, yet the latter appears to dominate the morphological development of discontinuity rich platforms. Given the sporadic nature of block detachment on platforms, observations of erosion from storm event to multi-decadal timescales (and beyond) are required to quantify shore platform erosion rates. To this end, we collected aerial photography using an unmanned aerial vehicle to produce structure-from-motion-derived digital elevation models and orthophotos. These were combined with historical aerial photographs to characterise and quantify the erosion of two actively eroding stratigraphic layers on a shore platform in Glamorgan, south Wales, UK, over 78-years. We find that volumetric erosion rates vary over two orders of magnitude (0.1-10 m³ yr^-1) and do not scale with the length of the record. Average rates over the full 78-year record are 2-5 m³ yr^-1. These rates are equivalent to 1.2-5.3 mm yr^-1 surface lowering rates, an order of magnitude faster than previously published, both at our site and around the world in similar rock types. We show that meso-scale platform erosion via block detachment processes is a dominant erosion process on shore platforms across seasonal to multi-decadal timescales that have been hitherto under-investigated. © 2019 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd     

Carbonaceous cherts of the Barberton Greenstone Belt, South Africa: Isotopic, chemical and structural characteristics of individual microstructures

Carbonaceous matter occurring in chert deposits of the 3.4-3.2 Ga old Barberton Greenstone Belt (BGB), South Africa, has experienced low grade regional metamorphism and variable degrees of local hydrothermal alteration. Here a detailed study is presented of in situ analysis of carbonaceous particles by LRS (laser Raman spectroscopy) and SIMS (secondary ion mass spectrometry), reporting degree of structural disorder, carbon isotope ratio and nitrogen-to-carbon ratio. This combination of in situ analytical tools is used to interpret the δ¹³C values of only the best preserved carbonaceous remains, enabling the rejection of non-indigenous (unmetamorphosed) material as well as the exclusion of strongly hydrothermally altered carbonaceous particles. Raman spectroscopy confirmed that all carbonaceous cherts studied here have experienced a regional sub- to lower-greenschist facies metamorphic event. Although this identifies these organics as indigenous to the cherts, it is inferred from petrographic observations that hydrothermal alteration has caused small scale migration and re-deposition of organics. This suggest that morphological interpretation of these carbonaceous particles, and in general of putative microfossils or microlaminae in hydrothermally altered early Archean cherts, should be made with caution. A chert in the Hooggenoeg Formation, which is older than and has been hydrothermally altered by a volcanic event 3445 Ma ago, contains strongly altered carbonaceous particles with a uniform N/C-ratio of 0.001 and a range of δ¹³C that is shifted from its original value. Cherts of the Kromberg Formation post-date this volcanic event, and contain carbonaceous particles with a N/C-ratio between 0.002 and 0.006. Both the Buck Reef Chert and the Footbridge Chert of the Kromberg Formation have retained fairly well-preserved δ¹³C values, with ranges from −34‰ to −24‰ and −40‰ to −32 ‰, respectively. Abiologic reactions associated with hydrothermal serpentinization of ultramafic crust (such as Fischer-Tropsch synthesis) were an unlikely source for carbonaceous material in these cherts. The carbonaceous matter in these cherts has all the characteristics of metamorphosed biologic material.