Persistence of 10-year old Exxon Valdez oil on Gulf of Alaska beaches: the importance of boulder-armoring

Oil stranded as a result of the 1989 Exxon Valdez spill has persisted for >10 years at study sites on Gulf of Alaska shores distant from the spill's origin. These sites were contaminated by "oil mousse", which persists in these settings due to armoring of underlying sediments and their included oil beneath boulders. The boulder-armored beaches that we resampled in 1999 showed continued contamination by subsurface oil, despite their exposure to moderate to high wave energies. Significant declines in surface oil cover occurred at all study sites. In contrast, mousse has persisted under boulders in amounts similar to what was present in 1994 and probably in 1989. Especially striking is the general lack of weathering of this subsurface oil over the last decade. Oil at five of the six armored-beach sites 10 years after the spill is compositionally similar to 11-day old Exxon Valdez oil. Analysis of movements in the boulder-armor that covers the study beaches reveals that only minor shifts have occurred since 1994, suggesting that over the last five, and probably over the last 10 years, boulder-armors have remained largely unmoved at the study sites. These findings emphasize the importance of particular geomorphic parameters in determining stranded oil persistence. Surface armoring, combined with stranding of oil mousse, results in the unexpectedly lengthy persistence of only lightly to moderately weathered oil within otherwise high-energy wave environments.     

How natural hazards impact the social environment for vulnerable groups: an empirical investigation in Japan

Natural Hazards - Much research has demonstrated that vulnerable people fare more poorly than non-vulnerable ones in disasters and crises across a variety of outcomes—including mental and...     

Determination of Reference Values for NIST SRM 610–617 Glasses Following ISO Guidelines

We present new reference values for the NIST SRM 610–617 glasses following ISO guidelines and the International Association of Geoanalysts’ protocol. Uncertainties at the 95% confidence level (CL) have been determined for bulk‐ and micro‐analytical purposes. In contrast to former compilation procedures, this approach delivers data that consider present‐day requirements of data quality. New analytical data and the nearly complete data set of the GeoReM database were used for this study. Data quality was checked by the application of the Horwitz function and by a careful investigation of analytical procedures. We have determined quantitatively possible element inhomogeneities using different test portion masses of 1, 0.1 and 0.02 μg. Although avoiding the rim region of the glass wafers, we found moderate inhomogeneities of several chalcophile/siderophile elements and gross inhomogeneities of Ni, Se, Pd and Pt at small test portion masses. The extent of inhomogeneity was included in the determination of uncertainties. While the new reference values agree with the NIST certified values with the one exception of Mn in SRM 610, they typically differ by as much as 10% from the Pearce et al. (1997) values in current use. In a few cases (P, S, Cl, Ta, Re) the discrepancies are even higher.     

Controls on herbaceous litter decomposition in the estuarine ecotones of the Florida Everglades

The effects of nutrient availability and litter quality on litter decomposition were measured in two oligotrophic phosphorus (P)-limited Florida Everglades esturies, United States. The two estuaries differ, in that one (Shark River estuary) is directly connected to the Gulf of Mexico and receives marine P, while the other (Taylor Slough estuary) does not receive marine P because Florida Bay separates it from the Gulf of Mexico. Decomposition of three macrophytes.Cladium jamaicense, Eleochaaris spp., andJuncus roemerianus, was studied using a litter bag technique over 18 mo. Litter was exposed to three treatments: soil surface+macroinvertebrates (=macro), soil surface without macroinvertebrates (=wet), and above the soil and water (=aerial). The third treatment replicated the decomposition of standing dead leaves. Decomposition rates showed that litter exposed to the wet and macro treatments decomposed significantly faster than the aerial treatment, where atmospheric deposition was the only source of nutrients. Macroinvertebrates had no influence on litter decompostion rates.C. jamaicense decomposed faster at sites, with higher P, andEleocharis spp. decomposed significantly faster at sites with higher nitrogen (N). Initial tissue C:N and C:P molar ratios revealed that the nutrient quality of litter of bothEleocharis spp. andJ. roemerianus was higher thanC. jamaicense, but onlyEleocharis spp. decomposed faster thanC. jamaicense. C. jamaicense litter tended to immobilize P, whileEleocharis spp. litter showed net remineralization of N and P. A comparison with other estuarine and wetland systems revealed the dependence of litter decomposition on nutrient availability and litter quality. The results from this experiment suggest that Everglades restoration may have an important effect on key ecosystem processes in the estuarine ecotone of this landscape.     

Floods in the Southern Alps of New Zealand: the importance of atmospheric rivers

Extremely high precipitation occurs in the Southern Alps of New Zealand, associated with both orographic enhancement and synoptic‐scale weather processes. In this study, we test the hypothesis that atmospheric rivers (ARs) are a key driver of floods in the Southern Alps of New Zealand. Vertically integrated water vapour and horizontal water vapour transport, and atmospheric circulation, are investigated concurrently with major floods on the Waitaki River (a major South Island river). Analysis of the largest eight winter maximum floods between 1979 and 2012 indicates that all are associated with ARs. Geopotential height fields reveal that these ARs are located in slow eastward moving extratropical cyclones, with high pressure to the northeast of New Zealand. The confirmation of ARs as a contributor to Waitaki flooding indicates the need for their further exploration to better understand South Island hydrometeorological extremes. Copyright © 2016 John Wiley & Sons, Ltd.     

Quantifying the Morphological Print of Bedload Transport

Bedload and river morphology interact in a strong feedback manner. Bedload conditions the development of river morphology along different space and time scales; however, by concentrating the flow in preferential paths, a given morphology controls bedload for a given discharge. As bedload is a non‐linear response of shear stress, local morphology is likely to have a strong impact on bedload prediction when the shear stress is averaged over the section, as is usually done. This was investigated by comparing bedload measured in different bed morphologies (step‐pool, plane bed, riffle‐pool, braiding, and sand beds), with bedload measured in narrow flumes in the absence of any bed form, used here as a reference. The initial methodology consisted of fitting a bedload equation to the flume data. Secondly, the morphological signature of each river was studied as the distance to this referent equation. It was concluded that each morphology affects bedload in a different way. For a given average grain shear stress, the larger the river, the larger the deviation from the flume transport. Narrow streams are those morphologies that behave more like flumes; this is particularly true with flat beds, whereas results deviate from flumes to a greater extent in step‐pools. The riffle‐pool's morphology impacts bedload at different levels depending on the degree of bar development, considered here through the ratio D₈₄/D₅₀ which is used as a proxy for the local bed patchiness and morphology. In braiding rivers morphological effects are important but difficult to assess because width is dependent on transport rate. Bed morphology was found to have negligible effects in sand bed rivers where the Shields stress is usually sufficiently high to minimize the non‐linearity effects when hydraulics is averaged over the section. Copyright © 2015 John Wiley & Sons, Ltd.     

Selective organic carbon losses from soils by sheet erosion and main controls

Although the impact of sheet erosion on the selective transportation of mineral soil particles has been widely investigated, little is yet known about the specific mechanisms of organic carbon (OC) erosion, which constitutes an important link in the global carbon cycle. The present study was conducted to quantify the impact of sheet erosion on OC losses from soils. Erosion plots with the lengths of 1‐ and 5‐m were installed at different topographic positions along a hillslope in a mountainous South African region. A total of 32 rainfall events from a three years period (November 2010 up to February 2013), were studied and evaluated for runoff (R), particulate and dissolved organic carbon (POC_L and DOC_L). In comparison to the 0–0·05 m bulk soil, the sediments from the 1‐m plots were enriched in OC by a factor 2·6 and those from the 5‐m long plots by a factor of 2·2, respectively. These findings suggest a preferential erosion of OC. In addition, total organic carbon losses (TOC_L) were incurred mainly in particulate form (~94%) and the increase in TOC_L from 14·09 ± 0·68 g C m^?1 yr^?1 on 1‐m plots to 50·03 ± 2·89 g C m^?1 yr^?1 on 5‐m plots illustrated an increase in sheet erosion efficiency with increasing slope length. Both TOC_L and sediment enrichment in OC correspondingly increased with a decrease in soil basal grass cover. The characteristics of rainstorms had no significant impact on the selectivity of OC erosion. The results accrued in this study investigating the links between sheet erosion and OC losses, are expected to be of future value in the generation of carbon specific erosion models, which can further help to inform and improve climate change mitigation measures. Copyright © 2016 John Wiley & Sons, Ltd.     

Hydrothermal Alteration, Fluid Inclusion and Stable Isotope Studies of the North Roby Zone, Lac des Iles PGE Mine, Ontario, Canada

The Archean mafic–ultramafic complex of Lac des Iles, Ontario, Canada, hosts economic platinum group elements (PGE)-Au-Cu-Ni mineralization in the Roby Zone. All lithologies in the North Roby Zone have been affected by hydrothermal alteration. The alteration products include talc (the most dominant mineral), anthophyllite, serpentine, actinolite, tremolite, chlorite, hornblende, zoisite, clinozoisite, epidote and sericite. In the altered rocks, light rare earth elements (La, Ce, Nd, Sm), Pb, Rb, Ba, Cs, S and possibly Y have been added by hydrothermal solution whereas Eu and heavy rare earth elements (Yb, Gd, Dy, Er) remained immobile. There are five types of fluid inclusions in the pegmatitic plagioclase with homogenization temperature and salinity ranging from 240°C to 445°C and 15.37 to 48.52 wt% equivalent NaCl, respectively. The δ¹⁸O and δD of talc range form 6.2‰ to 6.9‰ and −28‰ to −48‰, respectively. δ¹⁸O and δD water in equilibrium with talc during the hydrothermal alteration suggest a modified source for the hydrothermal solution. Microthermometry and stable isotope studies suggest that high temperature–high salinity fluid was diluted by, and mixed with, low temperature–low salinity meteoric solution. This mechanism precipitated the hydrothermal assemblage and redistributed trace elements during and after pegmatite formation in the North Ruby Zone.     

The Rožná uranium deposit (Bohemian Massif, Czech Republic): shear zone-hosted, late Variscan and post-Variscan hydrothermal mineralization

Three major mineralization events are recorded at the Rožná uranium deposit (total mine production of 23,000 t U, average grade of 0.24% U): (1) pre-uranium quartz-sulfide and carbonate-sulfide mineralization, (2) uranium, and (3) post-uranium quartz-carbonate-sulfide mineralization. (1) K–Ar ages for white mica from wall rock alteration of the pre-uranium mineralization style range from 304.5 ± 5.8 to 307.6 ± 6.0 Ma coinciding with the post-orogenic exhumation of the Moldanubian orogenic root and retrograde-metamorphic equilibration of the high-grade metamorphic host rocks. The fluid inclusion record consists of low-salinity aqueous inclusions, together with H₂O-CO₂-CH₄, CO₂-CH₄, and pure CH₄ inclusions. The fluid inclusion, paragenetic, and isotope data suggest that the pre-uranium mineralization formed from a reduced low-salinity aqueous fluid at temperatures close to 300°C. (2) The uraniferous hydrothermal event is subdivided into the pre-ore, ore, and post-ore substages. K–Ar ages of pre-ore authigenic K-feldspar range from 296.3 ± 7.5 to 281.0 ± 5.4 Ma and coincide with the transcurrent reorganization of crustal blocks of the Bohemian Massif and with Late Stephanian to Early Permian rifting. Massive hematitization, albitization, and desilicification of the pre-ore altered rocks indicate an influx of oxidized basinal fluids to the crystalline rocks of the Moldanubian domain. The wide range of salinities of fluid inclusions is interpreted as a result of the large-scale mixing of basinal brines with meteoric water. The cationic composition of these fluids indicates extensive interaction with crystalline rocks. Chlorite thermometry yielded temperatures of 260°C to 310°C. During this substage, uranium was probably leached from the Moldanubian crystalline rocks. The hydrothermal alteration of the ore substage followed, or partly overlapped in time, the pre-ore substage alteration. K–Ar ages of illite from ore substage alteration range from 277.2 ± 5.5 to 264.0 ± 4.3 Ma and roughly correspond with the results of chemical U–Pb dating of authigenic monazite (268 ± 50 Ma). The uranium ore deposition was accompanied by large-scale decomposition of biotite and pre-ore chlorite to Fe-rich illite and iron hydrooxides. Therefore, it is proposed that the deposition of uranium ore was mostly in response to the reduction of the ore-bearing fluid by interaction with ferrous iron-bearing silicates (biotite and pre-ore chlorite). The Th data on primary, mostly aqueous, inclusions trapped in carbonates of the ore substage range between 152°C and 174°C and total salinity ranges over a relatively wide interval of 3.1 to 23.1 wt% NaCl eq. Gradual reduction of the fluid system during the post-ore substage is manifested by the appearance of a new generation of authigenic chlorite and pyrite. Chlorite thermometry yielded temperatures of 150°C to 170°C. Solid bitumens that post-date uranium mineralization indicate radiolytic polymerization of gaseous and liquid hydrocarbons and their derivatives. The origin of the organic compounds can be related to the diagenetic and catagenetic transformation of organic matter in Upper Stephanian and Permian sediments. (3) K–Ar ages on illite from post-uranium quartz-carbonate-sulfide mineralization range from 233.7 ± 4.7 to 227.5 ± 4.6 Ma and are consistent with the early Tethys-Central Atlantic rifting and tectonic reactivation of the Variscan structures of the Bohemian Massif. A minor part of the late Variscan uranium mineralization was remobilized during this hydrothermal event.     

A high-resolution Holocene record on the Southern Brazilian shelf: Paleoenvironmental implications

A high-resolution, multi-proxy record has been used to determine the environmental changes during the Holocene on the southern Brazilian shelf. Present oceanographic conditions reveal wind and freshwater input as the determinants of short-term productivity changes in the study area. Magnetic susceptibility and grain-size variations, together with proxies of productivity (organic carbon, carbon accumulation rate, Ba, Sr, and Ca content, Ba/Al, Ba/Ti, and Al/Ti ratios) were analyzed and compared with proxies of redox condition (V/Ti ratio), terrigenous input (Fe/Ca and Ti/Ca ratios), as well as other Element/Ti ratios, to evaluate the paleoceanographic and paleoclimatic changes over the period.The core covers a time interval of about 7650 years, with sedimentation rates varying from 0.025 to 0.250 cm a⁻¹, which represent time intervals of between 8 and 80 a per sample. There is a clear change in the sedimentation rate at about 2800 B.P.All grain-size and elemental results indicate the occurrence of conspicuous changes between 5200 and 5000 cal. B.P., as well as between 3000 and 2800 cal. B.P. A comparison of the results with the palynological information available from the adjacent continental areas suggests that the sedimentary changes in this last interval may be correlated with the onset of modern climatic conditions in South America, and especially, with the onset of the Plata Plume Water, a water mass that carries cold, less saline waters towards the north. However, minor changes are observed at ca. 1500 B.P. and are correlated with an increase in the atmospheric humidity. Furthermore, a time-series analysis undertaken using several proxies indicated the occurrence of Sub-Milankovitch cycles, which may be compared with those reported worldwide.